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Nihonium -113Nh: properties of free atoms

Nihonium atoms have 113 electrons and theshell structure is  2.8.18.32.32.18.3.

Theground state electron configuration of ground state gaseous neutral nihonium is  [Rn].5f14.6d10.7s2.7p1 (a guess based upon that of thallium) and theterm symbol is 2P1/2 (a guess based upon guessed electronic structure).

Kossel shell structure of nihonium
Schematic electronic configuration of nihonium.
Kossel shell structure of nihonium
The Kossel shell structure of nihonium.

Atomic spectrum

 

A representation of the atomic spectrum of nihonium.

Ionisation Energies and electron affinity

Theelectron affinity of nihonium is (no data) kJ mol‑1. Theionisation energies of nihonium are given below.

Ionisation energies of nihonium
Ionisation energy numberEnthalpy / kJ mol‑1
1st705
Ionisation energies of nihonium
Ionisation energies of nihonium.

Effective Nuclear Charges

The following are "Clementi-Raimondi" effective nuclear charges,Zeff. Follow the hyperlinks for more details and for graphs in various formats.

Effective nuclear charges for nihonium
1s(no data) 
2s(no data)2p(no data) 
3s(no data)3p(no data)3d(no data) 
4s(no data)4p(no data)4d(no data)4f(no data)
5s(no data)5p(no data)5d(no data) 
6s(no data)6p(no data) 
7s  

References

These effective nuclear charges,Zeff, are adapted from the following references:

  1. E. Clementi and D.L.Raimondi,J. Chem. Phys. 1963,38, 2686.
  2. E. Clementi, D.L.Raimondi, and W.P. Reinhardt,J. Chem. Phys. 1967,47, 1300.

Electron binding energies

Electron binding energies for nihonium. All values ofelectron binding energies are given in eV. The binding energies are quoted relative to the vacuum level for rare gases and H2, N2, O2, F2, and Cl2 molecules; relative to the Fermi level for metals; and relative to the top of the valence band for semiconductors.
LabelOrbitaleV [literature reference]

Notes

I am grateful toGwyn Williams (Jefferson Laboratory, Virginia, USA) who provided the electron binding energy data. The data are adapted from references 1-3. They are tabulated elsewhere on the WWW (reference 4) and in paper form (reference 5).

References

  1. J. A. Bearden and A. F. Burr, "Reevaluation of X-Ray Atomic Energy Levels,"Rev. Mod. Phys., 1967,39, 125.
  2. M. Cardona and L. Ley, Eds.,Photoemission in Solids I: General Principles (Springer-Verlag, Berlin) with additional corrections, 1978.
  3. Gwyn Williams WWW table of values
  4. D.R. Lide, (Ed.) inChemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.
  5. J. C. Fuggle and N. Mårtensson, "Core-Level Binding Energies in Metals,"J. Electron Spectrosc. Relat. Phenom., 1980,21, 275.

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