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Cacoxenite

A valid IMA mineral species - grandfathered
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ⓘHrbek Mine, Svatá Dobrotivá (St Benigna), Zaječov, Beroun District, Central Bohemian Region, Czech Republic
A secondary mineral found in oxidized zones of phosphatic magnetite deposits, in novaculites, in phosphate-rich pegmatites, and rarely in iron-rich sediments and soils.


Unique Identifiers

Classification of Cacoxenite

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and< 2:1
Dana 8th ed.:
42.13.5.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
13 : Miscellaneous
Hey's CIM Ref.:
19.14.27

19 : Phosphates
14 : Phosphates of Fe and other metals

Mineral Symbols
Transparency:
Translucent
Colour:
Yellow to brownish yellow, reddish orange, golden yellow, deep orange, green
Comment:
Yellow in transmitted light.
Hardness:
3 - 4 onMohs scale
Density:
2.2 - 2.6 g/cm3 (Measured)    2.217 g/cm3 (Calculated)

Optical Data of Cacoxenite
Surface Relief:
Moderate
Pleochroism:
Visible
Comments:
O = Pale yellow
E = Canary yellow to yellow orange

Chemistry of Cacoxenite
Common Impurities:
Al

Crystallography of Cacoxenite
Place of Conservation of Type Material:
No defined type material.

Synonyms of Cacoxenite

Other Language Names for Cacoxenite

Common AssociatesTric.1 :P18.DC.FerrivauxiteFe3+Al2(PO4)2(OH)3 · 5H2OTric.1 :P18.DC.IanbruceiteZn2(AsO4)(OH) · 3H2OMon. 2/m :P21/b8.DC.05NissoniteCu2Mg2(PO4)2(OH)2 · 5H2OMon. 2/m :B2/b8.DC.07EuchroiteCu2(AsO4)(OH) · 3H2OOrth. 222 :P2121218.DC.10LegranditeZn2(AsO4)(OH) · H2OMon. 2/m :P21/b8.DC.12StrashimiriteCu8(AsO4)4(OH)4 · 5H2OMon.8.DC.15EarlshannoniteMn2+Fe3+2(PO4)2(OH)2 · 4H2OMon. 2/m :P21/b8.DC.15KunatiteCuFe3+2(PO4)2(OH)2 · 4H2OMon. 2/m :P21/b8.DC.15UM2006-27-PO:FeHZnZnFe3+2(PO4)2(OH)2 · 4H2OMon.8.DC.15UKI-2006-(PO:AlCuFeH)Fe2+Al3+2(PO4)2(OH)2 · 4H2O8.DC.15CobaltarthuriteCoFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m :P21/b8.DC.15ArthuriteCuFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m :P21/b8.DC.15OjuelaiteZnFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m :P21/b8.DC.15WhitmoreiteFe2+Fe3+2(PO4)2(OH)2 · 4H2OMon. 2/m :P21/b8.DC.15BendadaiteFe2+Fe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m :P21/b8.DC.17KleemaniteZnAl2(PO4)2(OH)2 · 3H2OMon.8.DC.20MagnesiobermaniteMgMn3+2(PO4)2(OH)2 · 4H2OMon. 2 :P218.DC.20BermaniteMn2+Mn3+2(PO4)2(OH)2 · 4H2OMon. 2/m :P2/b8.DC.20CoralloiteMn2+Mn3+2(AsO4)2(OH)2 · 4H2OTric. 1 :P18.DC.22KovdorskiteMg2(PO4)(OH) · 3H2OMon. 2/m :P21/b8.DC.25ZincostrunziteZnFe3+2(PO4)2(OH)2 · 6.5H2OTric.1 :P18.DC.25MetavauxiteFe2+Al2(PO4)2(OH)2 · 8H2OMon. 2/m :P21/b8.DC.25MetavivianiteFe2+Fe3+2(PO4)2(OH)2 · 6H2OTric.1 :P18.DC.25FerristrunziteFe3+Fe3+2(PO4)2(OH)3 · 5H2OTric.8.DC.25StrunziteMn2+Fe3+2(PO4)2(OH)2 · 6H2OTric.1 :P18.DC.25FerrostrunziteFe2+Fe3+2(PO4)2(OH)2 · 6H2OTric.8.DC.27BerauniteFe3+6(PO4)4O(OH)4 · 6H2OMon.m :Bb8.DC.27TvrdýiteFe2+Fe3+2Al3(PO4)4(OH)5(H2O)4 · 2H2OMon. 2/m :B2/b8.DC.27ZincoberauniteZnFe3+5(PO4)4(OH)5 · 6H2OMon. 2/m :B2/b8.DC.30MaghrebiteMgAl2(AsO4)2(OH)2 · 8H2OTric.1 :P18.DC.30FerrolaueiteFe2+Fe3+2(PO4)2(OH)2 · 8H2OTric.1 :P18.DC.30UshkoviteMgFe3+2(PO4)2(OH)2 · 8H2OTric.1 :P18.DC.30LaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric.1 :P18.DC.30ParavauxiteFe2+Al2(PO4)2(OH)2 · 8H2OTric.1 :P18.DC.30SigloiteFe3+Al2(PO4)2(OH)3 · 7H2OTric.1 :P18.DC.30NordgauiteMnAl2(PO4)2(F,OH)2 · 5H2OTric.1 :P18.DC.30Kayrobertsonite[MnAl2(PO4)2(OH)2(H2O)4] · 2H2OTric.1 :P18.DC.30KummeriteMn2+Fe3+Al(PO4)2(OH)2 · 8H2OTric.1 :P18.DC.30MangangordoniteMn2+Al2(PO4)2(OH)2 · 8H2OTric.1 :P18.DC.30StewartiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric.1 :P18.DC.30GordoniteMgAl2(PO4)2(OH)2 · 8H2OTric. 1 :P18.DC.30Kastningite(Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2OTric.1 :P18.DC.30PseudolaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OMon. 2/m :P21/b8.DC.32KamarizaiteFe3+3(AsO4)2(OH)3 · 3H2OTric.1 :P18.DC.32TinticiteFe3+3(PO4)2(OH)3 · 3H2OTric.1 :P18.DC.35VauxiteFe2+Al2(PO4)2(OH)2 · 6H2OTric.1 :P18.DC.37VantasseliteAl4(PO4)3(OH)3 · 9H2OOrth.8.DC.45Souzalite(Mg,Fe2+)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2OTric.18.DC.45Gormanite(Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2OTric.8.DC.47KingiteAl3(PO4)2F2(OH) · 7H2OTric.8.DC.50AllanpringiteFe3+3(PO4)2(OH)3 · 5H2OMon. 2/m :P21/m8.DC.50FluorwavelliteAl3(PO4)2(OH)2F · 5H2OOrth.mmm(2/m2/m2/m)8.DC.50WavelliteAl3(PO4)2(OH)3 · 5H2OOrth.mmm(2/m2/m2/m)8.DC.52KribergiteAl5(PO4)3(SO4)(OH)4 · 4H2OTric.1 :P18.DC.55MapimiteZn2Fe3+3(AsO4)3(OH)4 · 10H2OMon.m :Bm8.DC.57OgdensburgiteCa2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2OOrth.mmm(2/m2/m2/m) :Cmmm8.DC.60CloncurryiteCu0.5(VO)0.5Al2(PO4)2F2 · 5H2OMon. 2/m :P21/b8.DC.60Nevadaite(Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2OOrth.mmm(2/m2/m2/m)8.DC.62KenngottiteMn2+3Fe3+4(PO4)4(OH)6(H2O)2Mon. 2/m :P2/b8.DC.67MolinelloiteCu(H2O)(OH)V4+O(V5+O4)Tric.1 :P18.DC.70WhitecapsiteH16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2OHex. 6/m :P63/m8.DC.75HeimitePbCu2(AsO4)(OH)3 · 2H2OMon. 2/m8.DC.80LedneviteCu[PO3(OH)] · H2OMon. 2/m :P21/b

Other Information
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    • References for CacoxeniteⓘRanquel PegmatiteOyarzábal et al. (2016)
    Australia
     
    Dieter Mylius collectionCendón et al. (2004)Bottrill (2018)Sielecki (1988)Sielecki (1988)Harrowfield et al. (1981)Beyer et al. (1996)Pilkington et al. (1982)+1 other referenceSorrell (n.d.)+1 other referenceFrancis et al. (2012)Birch et al. (1993)Museum Victoria Mineralogy CollectionSorrell (n.d.)
    Austria
     
    Strasser (1992)+1 other referenceKolitsch (2009)Aufschluss 1972 (SB)Exel (1993)Meixner (1958)Aufschluss 1972 (SB)Michael Reicht collectionM.Reicht collectionBernhard (1996)+1 other reference
    Belgium
     
    Van Tassel (1966)+7 other referencesVan Tassel (1959)+2 other referencesperso.infonie.be (2004)Michel Blondieau.+1 other referenceFouassin et al. (1975)+2 other referencesFransolet (1987)Hatert et al. (2002)Hatert et al. (2002)Hatert et al. (2002)Blondieau (2005)Dillen et al. (1990)+1 other referenceBlondieau et al. (2012)
    Brazil
     
    various photographsCassedanne et al. (1999)Sergio Varvello collection
    Bulgaria
     
    Kunov (1996)+2 other referencesKunov et al. (1997)
    Burundi
     
    www.trademarksa.org (n.d.)
    Cameroon
     
    F. Pillard : "Contribution à l'étude de l'altération de la vivianite : cas de la vivianite d'Anloua (Cameroun)
    Canada
     
    Boyle (1972)Johnston (1915)Ontario Ministry of Northern ...+1 other referencePersonal Collection - Bill MorgensternBill Morgenstern
    Czech Republic
     
    Palache et al. (1951)Pauliš+4 other referencesVrtiška L. et al. (2018)Černý P. et al. (2015)Palache et al. (1951)+1 other referencePovondra et al. (eds.)+1 other referenceČerný P (1)Sejkora et al. (2006)Sejkora et al. (2006)JirásekJanouš+4 other referencesPalache et al. (1951)Houzar S.: Přehled minerálů z ...Vrtiška et al. (2017)Staněk (1970)+1 other referenceStaněk (1997)
    DR Congo
     
    De Bondt (n.d.)
    Europe
     
    Berbain et al. (2012)
    France
     
    Chollet Pascal collection - Self ...Yannick Vessely collection+1 other referencePierre Le Roch & Jean-Marc Johannet ...Cuchet et al. (2000)Coueille (1988)Germain C. (1995)Pierre Le Roch CollectionQueneau (n.d.)Le Roc'h P. ()Palache et al. (1951)Bernard Barrière collectionQueneau (n.d.)M. Arliguie collection+1 other referenceLièvre et al. (2002)Lièvre et al. (2002)Lièvre et al. (2002)perso.wanadoo.fr (2004)Boisson (1988)Alain Hanson Collection (gift from Michel Arliguie 9/2010)Patureau (2008)Boisson (1988)+1 other referenceAlain Hanson collectionQueneau P. (2001)+1 other referencePalache et al. (1951)Pascale & Daniel JournetLaurent Gayraud collectionLheur (2023)Laurent Gayraud collectionJean-Marie LAURENT collectionBerbain et al. (2012)Berbain et al. (2012)Izaac da Silva Leite collectionGAYRAUD (2010)+1 other referenceLièvre J.-M. & Pouit D. (2004)
    Germany
     
    Ko Jansen collectionWalenta (1992)Walenta (1992)in the collection of Christof SchäferPalache et al. (1951)+2 other referencesObermüller et al. (1993)Lorenz (2003)58.+1 other referenceDana 7:II:772Geipel (1982)von Voith (1836)Fehr et al. (1985)Dill et al. (2009)Dill et al. (2012)Dill et al. (2008)+1 other referencewww.mineralienatlas.de (n.d.)+2 other referencesWeiß (1990)web.archive.org (2001)Kastning et al. (1996)+2 other referencesPöllmann et al. (2005)Weiß (1990)DILL et al. (2009)Weber (2013)Wittern (2001)Kirnbauer (1984)Palache et al. (1951)+1 other referenceWeiß (1990)in the collection of Christof SchäferPalache et al. (1951)+1 other referenceBlaß (2002)Weiß (1990)Blaß et al. (1998)+1 other referenceWittern (2001)Stieglitz et al. (1987)+1 other referenceEmser Hefte 1988 (4)Wittern (2001)+1 other referencewww.mineralienatlas.de (2016)Gröbner et al. (2011)Witzke (1992)Wittern (2001)Martin (1994)Lapis 30 (7/8)Witzke et al. (1997)Witzke et al. (2013)Pestel et al. (2012)Martin (1994)www.mineralienatlas.de (2016)Witzke et al. (1998)Wittern (2001)Witzke et al. (2001)
    Greece
     
    Frenzel (1895)
    Hungary
     
    NAGY et al. (2000)Szakáll: Minerals of RudabányaZajzon N et al. (20014)GEODASzakáll et al. (1996)
    Ireland
     
    Ryback et al. (1988)
    Italy
     
    Castellaro-KampfMarco Ciriotti 2010Gianluca Armellino et al. (2024)+1 other referenceMattioli (1979)+1 other referenceOlmi F.Bortolozzi (n.d.)Luigi Chiappino data+1 other referenceI. Campostrini personal comunication
    Japan
     
    Yamada (2004)S. Matsubara (2000)Yamada (2004)SHIMOBAYASHI et al. (2012)Kitahara (1949)Takashi Yamada et al. (1999)Esaka collection+1 other reference
    Mali
     
    Gineste (2012)
    Mexico
     
    Michael Shannon specimens
    Morocco
     
    Favreau (2012)
    Namibia
     
    Keller et al. (1989)
    New Zealand
     
    Stott (pers. notes)
    Poland
     
    Lis et al. (1986)
    Portugal
     
    luigi chiappino specimenAlves (n.d.)Martins da Pedra collection+1 other referenceArtur Neves' collection - August 2014Rui Nunes visit 18 July 2015Nunes (n.d.)Alves (n.d.)Pedro Alves collection. Characterized ...Schnorrer-Köhler et al. (1991)Alves (n.d.)Self-collected by Pedro Alves.Alves (n.d.)Alves (n.d.)Mineralien AtlasRui Nunes 2011Identified in Rebentão Mineself-find
    Romania
     
    minerals-of-the-carpathians.eu (2008)+1 other reference
    Rwanda
     
    Bertossa (1968)+1 other reference
    Slovakia
     
    Martin Števko & Dušan ...
    South Africa
     
    Atanasova et al. (2016)Woolf (2023)SAMS (South African Micromount Society)
    Spain
     
    Christian Rewitzer collection - SEM-EDS ...mti-minas-andalucia.blogspot.com (n.d.)Sáinz de Baranda et al. (2004)www.foro-minerales.com (2022)+1 other referenceBareche (2005)www.foro-minerales.com (n.d.)www.foro-minerales.com (n.d.)www.foro-minerales.com (n.d.)Cesar Menor SalvanNunes (n.d.)+1 other referenceViñals et al. (2011)Miguel Calvo Rebollar (2015)Miguel Calvo Rebollar (2015)NÚÑEZ-GARCÍA et al. (2012)+1 other referenceVérez et al. (2024)Calvo Rebollar (2015)Calvo et al. (2003)
    Sweden
     
    Palache et al. (1951)Bjällerud (1989)+1 other reference
    Switzerland
     
    EDXS analyses
    UK
     
    George Eric Stanley Curtis collectionLapis 11 (2)+1 other referenceGolley et al. (1995)Golley et al. (1995)Richard Bell personal collectionRyback et al. (1988)+1 other referenceGolley et al. (1995)+3 other referencesHartley (1984)+2 other referencesStanley et al. (1991)Steve Rust collectionAlysson Rowan collection
    Uruguay
     
    Fabre (n.d.)
    USA
     
    Barwood et al. (1978)+1 other referenceRocks & Min.: 58:57-62.+1 other referenceHenry BarwoodRocks & Min.: 64:203.+1 other referenceCook et al. (1982)Simkev Micromounts CollectionDean (1995)Dean (1995)Dean (1995)Rocks & Minerals: 70 (5)chris bryant+1 other referenceCook et al. (1982)Dean (1995)U. S. Geological Survey Open-File ...Anthony et al. (1995)Anthony et al. (1995)Arthur E. Smith (2008)R&M 70:3 pp 154-170Howard+1 other referenceR&M 70:3 pp 154-170Henry Barwood - unpublished (2010)Rocks & min.: 64:297.Rocks & Min.: 63:109.Rocks & Min.: 63: 113.+2 other referencesHoward (2007)Rocks & Min.:63:118.Smith (1988)Smith (1988)Rocks & Min.: 63:120.Rocks & Min.:64:297-298.Am Min 51:1811-1814Smith (1988)Smith (1988)Pemberton (1983)+2 other referencesCarnein et al. (2005)Blanchard et al. (1968)Min News 21:8 pp 1+1 other referenceMarc V. Hurst (2012)Kelley CollectionAm Min 53:2096-2101Rocks & Min.: 64:185.Cook (1978)Jason Smith & M.E. Ciriotti (2005)Barwood (1999)+1 other referenceCook (1978)Rocks & Min.: 21:347+1 other referenceRocks & Minerals 54:4 pp161-165Kampf et al. (2013)Ostrander et al. (1940)Paul P.Hearn et al. (1988)Bernstein (1976)Dana 6:1083.Jensen et al. (1995)Jensen et al. (1995)Castor et al. (2004)Castor et al. (2004)Silver Coin Mine. Compact Disc. Paul ...Collected by and in the collection of ...Collected by Dick Thomssen.Castor et al. (2004)Castor et al. (2004)Jeremy ZolanCastor et al. (2004)Collection of Kelly Starnes 1990Castor et al. (2004)Castor et al. (2004)Wilson et al. (2008)Moore (1973)Smith (2005)Henderson (1980)Locality description: "[...] all the ...C.G.Segeler (personal communication)See specimen ...D.Court collection+1 other referenceWalstrom (n.d.)Palache et al. (1951)Rocks & Min.: 60:84.+1 other referenceRocks & Minerals: 60 (2)+1 other referenceKenny Gay personal messagewww.mindat.org/mesg-11-168140.htmlPalache et al. (1951)+1 other referenceLapham et al. (1965)Lapham et al. (1965)Dana 6: 1069+1 other referenceSloto (2019)Palache et al. (1951)Henderson (1980)Min. Col. PA+2 other referencesK. Cabaniss & L.E. Kearns (2011)Steve Stuart specimenRocks & Minerals 54:4 pp173-175Seaman (1976)Loomis (2011)Rocks & Minerals: 67 (6)Paris (2011)Dietrich (1990)Rocks & Min.:64:42-45 (also see Rocks & Min.:57:20-22 & 60:168)+1 other referenceDietrich (1990)Rocks & Min.: 57:20-22+1 other referenceDietrich (1990)Klemic et al. (1972)+1 other reference
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