Hydrotalcite supergroup. It has a layered double hydroxide-type structure, in which brucite-like layers [Fe3+6O4(OH)8]2+ are intercalated with CO32- anions and water molecules.
The fully oxidized analogue of
fougèrite and
trébeurdenite, related to them chemically by the exchange of (Fe3+O2−) with (Fe2+OH−).
Synchrotron X-ray data indicate that the natural material is a nanoscale intergrowth of 2T and 3T polytypes; the latter probably has the 3T7 stacking sequence.