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Oxyphlogopite

A valid IMA mineral species
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Named in 2010 by N. V. Chukanov, A. A. Mukhanova, R. K. Rastsvetaeva, D.I. Belakovskiy, S. Möckel, O. V. Karimova, S. N. Britvin, and S. V. Krivovichev for its chemical relationship to phlogopite.
Type Locality:
ⓘRothenberg Quarry, Bell, Mendig, Mayen-Koblenz, Rhineland-Palatinate, Germany
It forms coarse dark brown to black vitreous prismatic (up to 1.5 mm) or platy (up to 4×4×0.2 mm) crystals in cavities of alkaline basalt.


Unique Identifiers
Approval year:
2009

Classification of Oxyphlogopite

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets

Mineral Symbols
Colour:
Dark brown to almost black
Streak:
Brown
Hardness:
3 onMohs scale
Tenacity:
Flexible
Cleavage:
Perfect
on {001}
Density:
3.06(1) g/cm3 (Measured)    3.086 g/cm3 (Calculated)

Optical Data of Oxyphlogopite
Surface Relief:
Moderate
Dispersion:
r < v, strong
Pleochroism:
Visible
Comments:
Brown to dark brown

Chemistry of Oxyphlogopite
Common Impurities:
Fe,Na

Crystallography of Oxyphlogopite
General Appearance of Type Material:
Imperfect prismatic and thin lamellar crystals.
Place of Conservation of Type Material:
Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia: registration nos. 3884/1 (cotype) and 3884/2 (holotype).
Geological Setting of Type Material:
Oxyphlogopite is pneumatolitic in origin. It occurs as crystals lining the walls of cavities in cavernous alkali basalt and growing into the rock near the caverns.
Associated Minerals at Type Locality:
Albite-Anorthite SeriesAugiteDiopsideMagnetiteNepheline
Sanidine

Synonyms of Oxyphlogopite

Other Language Names for Oxyphlogopite

Relationship of Oxyphlogopite to other Species
Other Members of Biotite:
AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m :B2/m
EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
FluoranniteKFe2+3(Si3Al)O10F2Mon. 2/m :B2/m
FluorophlogopiteKMg3(Si3Al)O10F2Mon. 2/m :B2/m
FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m :B2/m
PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m :B2/m
SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
TetraferrianniteKFe2+3(Si3Fe3+)O10(OH)2Mon. 2/m :B2/m
TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2Mon. 2/m :B2/m
Forms a series with:
PhlogopiteOxyphlogopite-phlogopite Series

Common AssociatesTric.1 :P19.EC.BalestraiteKLi2V5+Si4O12Mon. 2 :B29.EC.05TalcMg3Si4O10(OH)2Tric.1 :P19.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric.1 :P19.EC.05WillemseiteNi3Si4O10(OH)2Mon.9.EC.9.EC.VoloshiniteRb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2Mon. 2/m :B2/b9.EC.10FluorluanshiweiiteKLiAl1.5(Si3.5Al0.5)O10F2Mon. 2/m :B2/m9.EC.10GarmiteCsLiMg2(Si4O10)F2Mon.9.EC.10GorbunoviteCsLi2(Ti,Fe)Si4O10(F,OH,O)2Mon.9.EC.10FerripyrophylliteFe3+Si2O5(OH)Mon. 2/m9.EC.10ManganiceladoniteK(MgMn3+◻)(Si4O10)(OH)2Mon.9.EC.10LuanshiweiiteKLiAl1.5(Si3.5Al0.5)O10(OH)2Mon. 2/m :B2/b9.EC.10PyrophylliteAl2Si4O10(OH)2Tric.19.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.9.EC.15FerroaluminoceladoniteK(Fe2+Al◻)(Si4O10)(OH)2Mon. 2/m :B2/m9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon. 2/m :B2/b9.EC.15FerroceladoniteK(Fe2+Fe3+◻)(Si4O10)(OH)2Mon. 2/m :B2/m9.EC.15Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2Mon. 2/m :B2/b9.EC.15KreiteriteCsLi2Fe3+(Si4O10)F2Mon.9.EC.15RoscoeliteKV3+2(AlSi3O10)(OH)2Mon. 2/m :B2/b9.EC.15AluminoceladoniteK(MgAl◻)(Si4O10)(OH)2Mon. 2/m :B2/m9.EC.15Tobelite(NH4)Al2(AlSi3O10)(OH)2Mon. 2/m :B2/m9.EC.15TainioliteKLiMg2(Si4O10)F2Mon. 2/m :B2/m9.EC.15CeladoniteK(MgFe3+◻)(Si4O10)(OH)2Mon. 2/m :B2/m9.EC.15ChromceladoniteK(MgCr◻)(Si4O10)(OH)2Mon. 2 :B29.EC.15MontdoriteKFe2+1.5Mn2+0.5Mg0.5Si4O10(F,OH)2Mon. 2/m :B2/m9.EC.15ChromphylliteKCr2(AlSi3O10)(OH)2Mon. 2/m :B2/b9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon. 2/m9.EC.15UM1988-22-SiO:AlCaFFeHKLiMgKLiMgAl2Si3O10F2Mon.9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m :B2/b9.EC.20MasutomiliteK(LiAlMn2+)[AlSi3O10]F2Mon. 2 :B29.EC.20Chloroferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)29.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m :B2/m9.EC.20TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2Mon. 2/m :B2/m9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon. 2/m :B2/m9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m :B2/m9.EC.20Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m :B2/m9.EC.20EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric. 1 :P19.EC.20NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m :B2/m9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m :B2/m9.EC.20YangzhumingiteKMg2.5(Si4O10)F2Mon. 2/m :B2/m9.EC.20OrloviteKLi2Ti(Si4O10)OFMon. 2 :B29.EC.20TetraferrianniteKFe2+3(Si3Fe3+)O10(OH)2Mon. 2/m :B2/m9.EC.20ShirokshiniteK(NaMg2)(Si4O10)F2Mon. 2/m :B2/m9.EC.20TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2Mon. 2/m :B2/b9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m :B2/b9.EC.20ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m :B2/m9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon. 2/m :B2/b9.EC.20FluorophlogopiteKMg3(Si3Al)O10F2Mon. 2/m :B2/m9.EC.20Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4Mon. 2/m :B2/m9.EC.20UM2004-49-SiO:AlCsFHKLi(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)29.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m :B2/m9.EC.20AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m :B2/m9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.9.EC.22PimeliteNi3Si4O10(OH)2 · 4H2OHex.9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2Mon. 2/m :B2/b9.EC.30Chlorophaeite(Ca,Mg,Fe)2Fe2Si4O13 · 10H2O9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2Mon. 2/m :B2/m9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2Mon. 2/m :B2/m9.EC.35ClintoniteCaAlMg2(SiAl3O10)(OH)2Mon. 2/m :B2/m9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2Mon. 2/m :B2/m9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2Mon. 2/m :B2/m9.EC.35BityiteCaLiAl2(AlBeSi2O10)(OH)2Mon. 2/m :B2/b9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2Mon. 2/m :B2/b9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m :B2/m9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m :B2/m9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2OMon.9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m :B2/m9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?)Orth.9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.9.EC.45SwineforditeLi(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2OMon. 2/m :B2/m9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon. 2/m :B2/m9.EC.45ZincsiliteZn3Si4O10(OH)2 · 4H2O (?)Mon.9.EC.45HanjiangiteBa2CaV3+Al(H2AlSi3O12)(CO3)2FMon. 2 :B29.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2OMon.9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2OMon. 2/m9.EC.52Tarasovitenear NaKAl11Si13O40(OH)9 · 3H2O9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m :B2/m9.EC.55Borocookeite(LiAl4◻)[BSi3O10](OH)8Mon.m :Bb9.EC.55FranklinfurnaceiteCa2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8Mon. 2 :B29.EC.55PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.9.EC.55VakhrushevaiteMg5Cr(AlSi3O10)(OH)8Tric.19.EC.55Nimite(Ni,Mg,Al)6((Si,Al)4O10)(OH)8Mon. 2/m :B2/m9.EC.55Cookeite(LiAl4◻)[AlSi3O10](OH)8Mon. 2/m9.EC.55Gonyerite(Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8Orth.9.EC.55Chamosite(Fe2+,Mg,Al,Fe3+)6(Si,Al)4O10(OH,O)8Mon. 2/m :B2/m9.EC.55Orthochamosite(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)89.EC.55Baileychlore(Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8Tric.19.EC.55SudoiteMg2Al3(Si3Al)O10)(OH)8Mon. 2/m :B2/m9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 :P19.EC.55DonbassiteAl4.33(Si3Al)O10(OH)8Mon. 2 :B29.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12Mon.9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2OMon.9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2OOrth.9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2OMon.9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10Mon.9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2OMon. 2 :B29.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2OMon. 2/m :B2/m9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon. 2/m :B2/m9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10Mon.9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2OMon.9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2Mon.9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig.3m(32/m) :P31m9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2OMon.9.EC.75Ferrisurite(Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2OMon.9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2Mon. 2 :P219.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.

Radioactivityshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

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    • References for OxyphlogopiteⓘChassigny Martian meteoriteFleet (2003)
    Germany
     
    Freudenberg (1919)Personally collected by Günter FrenzChukanov N.V. et al.: Oxyphlogopite (Mg,Ti,Fe)Marko Burkhardt Collectionin the collection of Christof SchäferBlaß (2020)Blaß (2020)
    USA
     
    Färber (n.d.)
    Quick NavTopAbout OxyphlogopiteUnique IdentifiersIMA ClassificationClassificationMineral SymbolsPhysical PropertiesOptical DataChemistryCrystallographyX-Ray Powder DiffractionGeological EnvironmentType OccurrenceSynonymsOther LanguagesRelationshipsCommon AssociatesStrunz-MindatRadioactivityOther InformationInternet LinksReferencesLocalitiesLocality List
     
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