Sphalerite Group.
Sphalerite, also known as blende or zinc blende, is the major ore of zinc. When pure (with little or no iron) it forms clear to white crystals (known as
cleiophane). Yellow to orange sphalerite is often called 'golden sphalerite'.
Red shades of sphalerite have been called 'ruby blende' or 'ruby jack' in the past.
As iron content increases, sphalerite forms dark, opaque submetallic crystals (known as
marmatite or, in the past, 'black jack').
Very rarely, green crystals owe their colour to trace amounts of cobalt (Henn & Hofmann, 1985; Rager et al., 1996).
Sphalerite may also contain considerable manganese, grading into
alabandite. Samples containing up to 0.36 apfu (atoms per formula unit) manganese (21.4 wt.% MnO) have been described by Hurai & Huraiová (2011). It can also be mercury-rich and form a series with
metacinnabar.
Sphalerite is an important source of rare metals like gallium (Ga) and indium (In), and the semi-metal germanium (Ge). Samples from the Restauradora vein of the Capillitas deposit, Argentina, bears a record, at 24.89 wt% In (and 13.49 wt% Cu) it is, astonishingly, still a sphalerite (Márquez-Zavalía et al. 2024).
See article on the
schalenblende variety, by Harjo Neutkens:
https://www.mindat.org/a/best_schalenblendeAccording to Haussühl and Müller (1963), there are numerous polytypes; the ones identified by them are 3R (=3C); 2H, 4H, 6H; and 9R, 12R, 15R and 21R. Note that this can be taken to infer that wurtzite (all the H polytypes) is merely a series of polytypes of sphalerite!
Compare
UM1993-16-S:CdInZn and
UM1993-15-S:CdInZn.