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Sphalerite

A valid IMA mineral species - grandfathered
This page kindly sponsored byMark Kucera
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Originally called blende in 1546 by Georgius Agricola (Georg Bauer). Known by a variety of chemical-based names subsequent to Agricola and before Glocker, including "zincum". Named Sphalerite in 1847 by Ernst Friedrich Glocker from the Greek σφαλεροζ "sphaleros" = treacherous, in allusion to the ease with which dark varieties were mistaken for galena, but yielded no lead.
Polymorph of:
Sphalerite Group.

Sphalerite, also known as blende or zinc blende, is the major ore of zinc. When pure (with little or no iron) it forms clear to white crystals (known ascleiophane). Yellow to orange sphalerite is often called 'golden sphalerite'.

Red shades of sphalerite have been called 'ruby blende' or 'ruby jack' in the past.

As iron content increases, sphalerite forms dark, opaque submetallic crystals (known asmarmatite or, in the past, 'black jack').

Very rarely, green crystals owe their colour to trace amounts of cobalt (Henn & Hofmann, 1985; Rager et al., 1996).

Sphalerite may also contain considerable manganese, grading intoalabandite. Samples containing up to 0.36 apfu (atoms per formula unit) manganese (21.4 wt.% MnO) have been described by Hurai & Huraiová (2011). It can also be mercury-rich and form a series withmetacinnabar.

Sphalerite is an important source of rare metals like gallium (Ga) and indium (In), and the semi-metal germanium (Ge). Samples from the Restauradora vein of the Capillitas deposit, Argentina, bears a record, at 24.89 wt% In (and 13.49 wt% Cu) it is, astonishingly, still a sphalerite (Márquez-Zavalía et al. 2024).

See article on theschalenblende variety, by Harjo Neutkens:https://www.mindat.org/a/best_schalenblende

According to Haussühl and Müller (1963), there are numerous polytypes; the ones identified by them are 3R (=3C); 2H, 4H, 6H; and 9R, 12R, 15R and 21R. Note that this can be taken to infer that wurtzite (all the H polytypes) is merely a series of polytypes of sphalerite!

CompareUM1993-16-S:CdInZn andUM1993-15-S:CdInZn.




Unique Identifiers

Classification of Sphalerite

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
2.8.2.1

2 : SULFIDES
8 : AmXp, with m:p = 1:1
3.4.4

3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
4 : Sulphides etc. of Group II metals other than Hg (Mg, Ca, Zn, Cd)

Mineral Symbols
Transparency:
Transparent, Translucent
Colour:
Yellow, light to dark brown, black, red-brown, colourless, light blue, rarely green
Comment:
Coloration of sphalerites from the Binntal, CH - varying from yellow to black for nearly identical iron contents - seems to be strongly influenced by the manganese content (Graeser, 1969).
Streak:
Pale yellow to brown.
Hardness:
VHN100=208 - 224 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
Perfect
Perfect {011}
Fracture:
Conchoidal
Density:
3.9 - 4.1 g/cm3 (Measured)    4.096 g/cm3 (Calculated)

Optical Data of Sphalerite
Common Impurities:
Fe,Mn,Cd,Hg,In,Tl,Ga,Ge,Sb,Sn,Pb,Ag,Co

Age distribution
Click on an icon to view
Sphalerite no.1 - Goldschmidt (1913-1926)
Sphalerite no.3 - Goldschmidt (1913-1926)
Sphalerite no.9 - Goldschmidt (1913-1926)
Sphalerite no.13 - Goldschmidt (1913-1926)
Sphalerite no.33 - Goldschmidt (1913-1926)
Sphalerite no.46 - Goldschmidt (1913-1926)
Sphalerite no.53 - Goldschmidt (1913-1926)
Sphalerite no.162 - Goldschmidt (1913-1926)
3d models and HTML5 code kindly provided bywww.smorf.nl.

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Edge Lines |Miller Indices |Axes

Transparency
Opaque |Translucent |Transparent

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Crystal StructureHilltop mine, Paradise, Cochise County, Arizona, USA 376
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
3.123 Å(100)
2.705 Å(10)
1.912 Å(51)
1.633 Å(30)
1.561 Å(2)
1.351 Å(6)
1.240 Å(9)
1.209 Å(2)
1.1034 Å(9)
1.0403 Å(5)
0.9557 Å(3)
0.9138 Å(5)
0.8548 Å(3)
0.8244 Å(2)

Geological Environment

Other Language Names for Sphalerite

Varieties of SphaleriteCleiophaneCleiophane is colorless to white or green sphalerite due to low contents of Fe2+ and Mn2+. Yellow gemmy sphalerite is called "golden sphalerite."

First reported from Franklin, Franklin Mining District, Sussex Co., New Jersey, USA.Gallium-bearing SphaleriteEnrichment in Ga (and other rare elements like, especially, Cd) is quite typical for many sphalerites, and sphalerite may act as an important source of Ga.Gem BlendeA ruby-red translucent variety of "blende" (= sphalerite).
The translucency increases with decreasing iron content.HonigblendeGerman name for honey-coloured sphalerite.Indium-bearing SphaleriteAn In-bearing variety of sphalerite. It is usually also Cu-rich (coupled substitution of Cu+ + In3+ <-> 2Zn2+).

In contents close to 22 wt.% are reported by Márquez-Zavalía et al. (2020).MarmatiteA macroscopically opaque and black, iron-rich variety of sphalerite, with up to 25 wt% Fe, or 40 mol% FeS, usually also Mn-rich, formed at relatively high temperatures.Mercury-bearing SphaleriteA mercury-bearing variety of sphalerite.

See alsoPolhemusite.MátraiteA densely twinned columnar variety of sphalerite. Discredited as 2006-C.
Nitta et al. (2008) showed that the sphalerite is twinned on {111}.

Originally reported from Gyöngyösoroszi, Mátra Mts., Heves Co., Hungary.Pyrophoric sphaleriteA variety of sphalerite that gives off sparks or glows when abraded. Some pieces are so sensitive that the effect is obtained by scratching them with a fingernail (definitions furnished by Frank L. Hess, Mining Engineer, U.S. Bureau of Mines, Collee Park,...

Relationship of Sphalerite to other Species
Other Members of Sphalerite Group:
BrowneiteMnSIso.43m :F43m
ColoradoiteHgTeIso.43m :F43m
HawleyiteCdSIso.43m :F43m
Ishiharaite(Cu,Ga,Fe,In,Zn)SIso.43m :F43m
MetacinnabarHgSIso.43m :F43m
Rudashevskyite(Fe,Zn)SIso.43m :F43m
StilleiteZnSeIso.43m :F43m
TiemanniteHgSeIso.43m :F43m

Common AssociatesTet.42m :I42m2.CB.OkruginiteCu2SnSe3Mon.m :Bb2.CB.HanswilkeiteKFeS2Mon. 2/m :B2/b2.CB.AuroselenideAuSeMon. 2/m :B2/m2.CB.Ruizhongite(Ag2◻)Pb3Ge2S8Iso.43m :I43d2.CB.AgmantiniteAg2MnSnS4Orth.2.CB.TolstykhiteAu3S4Te6Tric.1 :P12.CB.GachingiteAu(Te1-xSex)Orth.mmm(2/m2/m2/m)2.CB.05aHawleyiteCdSIso.43m :F43m2.CB.05UM1998-15-S:CuFeZnCu2Fe3Zn5S102.CB.05aColoradoiteHgTeIso.43m :F43m2.CB.05aMetacinnabarHgSIso.43m :F43m2.CB.05aTiemanniteHgSeIso.43m :F43m2.CB.05bSakuraiite(Cu,Zn,Fe)3(In,Sn)S4Iso.2.CB.05cPolhemusite(Zn,Hg)STet.2.CB.05aRudashevskyite(Fe,Zn)SIso.43m :F43m2.CB.05aStilleiteZnSeIso.43m :F43m2.CB.05aIshiharaite(Cu,Ga,Fe,In,Zn)SIso.43m :F43m2.CB.07aUnnamed (Cu-Mn-Sn Sulphide)Cu2MnSnS42.CB.07aShenzhuangiteNiFeS2Tet.42m :I42d2.CB.10bTalnakhiteCu9(Fe,Ni)8S16Iso.43m :I43m2.CB.10bHaycockiteCu4Fe5S8Orth. 2222.CB.10aLenaiteAgFeS2Tet.42m :I42d2.CB.10aGalliteCuGaS2Tet.42m :I42d2.CB.10aRoquesiteCuInS2Tet.42m :I42d2.CB.10aEskeborniteCuFeSe2Tet.42m :P42c2.CB.10aUM1984-30-S:CuFeSnCu2Fe2Sn3S72.CB.10cOmariniiteCu8Fe2ZnGe2S12Orth. 222 :I2222.CB.10aChalcopyriteCuFeS2Tet.42m :I42d2.CB.10aUnnamed (Cu-Zn-In Sulphide)CuZn2InS42.CB.10bMooihoekiteCu9Fe9S16Tet.42m :P42m2.CB.10aLaforêtiteAgInS2Tet.42m :I42d2.CB.10bPutoraniteCu1.1Fe1.2S2Iso.m3m(4/m32/m) :Pn3m2.CB.15aVelikiteCu2HgSnS4Tet.4 :I42.CB.15cUM2006-11-S:CuFeGeZnCu8(Fe,Zn)3Ge2S12 (?)2.CB.15aHocartiteAg2(Fe2+,Zn)SnS4Tet.42m :I42m2.CB.15aKësteriteCu2ZnSnS4Tet.4 :I42.CB.15aPirquitasiteAg2ZnSnS4Tet.4 :I42.CB.15aStanniteCu2FeSnS4Tet.42m :I42m2.CB.15cStannoiditeCu+6Cu2+2(Fe2+,Zn)3Sn2S12Orth. 222 :I2222.CB.15bMohiteCu2SnS3Mon.2.CB.15aČernýiteCu2CdSnS4Tet.42m :I42m2.CB.15aIdaiteCu5FeS6Hex.2.CB.15aFerrokësteriteCu2FeSnS4Tet.4 :I42.CB.15aKuramiteCu3SnS4Tet.42m :I42m2.CB.17a vArsenic-bearing RenieriteCu11GeAsFe4S162.CB.20MawsoniteCu6Fe2SnS8Tet.42m :P4m22.CB.20ChatkaliteCu6FeSn2S8Tet.42m :P4m22.CB.30FrieseiteAg2Fe5S8 (?)2.CB.30NekrasoviteCu26V2(Sn,As,Sb)6S32Iso.43m :P43n2.CB.30Argyropyritenear Ag2Fe7S112.CB.30MaikainiteCu20(Fe,Cu)6Mo2Ge6S32Iso.m3m(4/m32/m)2.CB.30ColusiteCu13VAs3S16Iso.43m :P43n2.CB.30GermaniteCu13Fe2Ge2S16Iso.43m :P43n2.CB.30GermanocolusiteCu26V2(Ge,As)6S32Iso.43m :P43m2.CB.30StibiocolusiteCu13V(Sb,Sn,As)3S16Iso.43m :P43m2.CB.30Ovamboite Cu20(Fe,Cu,Zn)6W2Ge6S32Iso.43m :P43n2.CB.35aMorozeviczite(Pb,Fe)3Ge1-xS4Iso.2.CB.35aRenierite(Cu1+,Zn)11Fe4(Ge4+,As5+)2S16Tet.42m :P42c2.CB.35aHemusiteCu6SnMoS8Iso.2.CB.35bCatamarcaiteCu6GeWS8Hex. 6mm :P63mc2.CB.35aVincienniteCu+7Cu2+3Fe2+2Fe3+2Sn(As,Sb)S16Tet.2.CB.35aKiddcreekiteCu6SnWS8Iso.43m :F43m2.CB.35aPolkovicite(Fe,Pb)3(Ge,Fe)1-xS4Iso.2.CB.40LautiteCuAsSOrth.mmm(2/m2/m2/m) :Pnma2.CB.42LingbaoiteAgTe3Trig. 3m :R3m2.CB.45CadmoseliteCdSeHex. 6mm :P63mc2.CB.45RambergiteMnSHex. 6mm :P63mc2.CB.45Buseckite(Fe,Zn,Mn)SHex. 6mm :P63mc2.CB.45MaletoyvayamiteAu3Se4Te6Tric.1 :P12.CB.45GreenockiteCdSHex. 6mm :P63mc2.CB.45Wurtzite(Zn,Fe)SHex. 6mm :P63mc2.CB.47MurchisiteCr5S6Trig.3m(32/m) :P31c2.CB.50ZincselenideZnSe2.CB.50WassoniteTiSTrig.3m(32/m) :R3m2.CB.52DzhezkazganiteReMoCu2PbS6 ?Trig. 3m :R3m2.CB.55bIsocubaniteCuFe2S3Iso.m3m(4/m32/m) :Fm3m2.CB.55aCubaniteCuFe2S3Orth.mmm(2/m2/m2/m)2.CB.60RaguiniteTlFeS2Orth.2.CB.60PicotpauliteTlFe2S3Orth.mmm(2/m2/m2/m) :Cmcm2.CB.65ArgentopyriteAgFe2S3Mon. 2/m2.CB.65SternbergiteAgFe2S3Orth.mmm(2/m2/m2/m)2.CB.70SulvaniteCu3VS4Iso.43m :P43m2.CB.75VulcaniteCuTeOrth.mmm(2/m2/m2/m)2.CB.80EmpressiteAgTeOrth.mmm(2/m2/m2/m)2.CB.85MuthmanniteAuAgTe2Mon. 2/m :P2/m

Fluorescence of Sphalerite

Other Information
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  • References for SphaleritePring, Allan, Wade, Benjamin, McFadden, Aoife, Lenehan, Claire E., Cook, Nigel J. (2020) Coupled Substitutions of Minor and Trace Elements in Co-Existing Sphalerite and Wurtzite.Minerals, 10 (2) 147doi:10.3390/min10020147

    Significant localities for SphaleriteMax MineNiedermayr et al. (1995)
    Canada
     
    Mielke (n.d.)+1 other reference
    France
     
    Belot (1978)Mines+1 other referenceJ F Carpenter specimen
    Germany
     
    Kirill VlasovLapis 2005 (30)
    Ireland
     
    Flannery (n.d.)+2 other referencesFlannery (n.d.)+1 other referenceFlannery (n.d.)+2 other referencesMoreton (1999)
    Italy
     
    Cioffi M. (Alpi Apuane)+1 other referenceBiagioni et al. (2008)Benvenuti et al. (2000)Dini (1995)Orlandi et al. (2004)
    Kazakhstan
     
    RWMW specimen+2 other references
    Kosovo
     
    Féraud J. (1979)+3 other references
    Norway
     
    Neumann (1944)Torkelsen (1993)
    Peru
     
    - (1997)+2 other referencesImai et al. (1985)+2 other references- (1997)+1 other reference- (1997)Burkart-Baumann+2 other references
    Poland
     
    Andrzejewski K. (1993)
    Romania
     
    Mârza+10 other references
    Russia
     
    Dobovol'skaya et al. (1990)+3 other references
    South Africa
     
    Wilson (2001)
    Spain
     
    Calvo et al. (1993)+1 other referenceGómez Fernández et al. (2006)[var: Marmatite]Calvo (2003)
    Switzerland
     
    Graeser et al. (1987)
    UK
     
    Dunham K CDavid Baldwin
    USA
     
    Januzzi (1994)+1 other referenceFluorite: The Collector's Choice. Extra ...+7 other referencesJ. Zolan+2 other referencesJ. WingardSherwood et al. (1998)[var: Cleiophane]Kyle (1976)+2 other referencesRocks & Min.+2 other references
     
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