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Fougèrite

A valid IMA mineral species
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Photos of Fougèrite (29)
Fougèrite GallerySearch Photos of Fougèrite
EditAdd SynonymEdit CIF structuresClear Cache
Fe2+4Fe3+2(OH)12[CO3] · 3H2O
Colour:
Bluish green, green, green-black, blackish
Lustre:
Earthy
Crystal System:
Trigonal
Member of:
Name:
Named for "a forest near Fougères, Brittany, France", where the type material was collected.
Type Locality:
The mineral formerly described as fougèrite has been found to be an intimate intergrowth of two phases with distinctFe2+:Fe3+ ratios. The phase withFe2+:Fe3+ = 2:1 retains the name fougèrite; that withFe2+:Fe3+ = 1:2 is defined as the new speciestrébeurdenite. Both belong to theFougèrite Group (Mills et al., 2012).

Fougèrite is unstable in air at normal conditions (Trolard et al., 2007); the green (or green-black, blackish), hexagonal, transparent platelets transform quickly into yellow-brown to brown, opaque, often poorly crystalline, brittle iron oxyhydroxides (limonite,goethite,lepidocrocite). Known previously as "Green Rust", mainly from iron-rich slags.

Varieties containing Zn retain their green colour and transparency (Blaß et al., 1997).

The characteristic blue-green colour (5BG6/1 in the Munsell system) of fougèrite has long been used as a universal criterion in soil classification to identify Gleysols (Trolard et al., 2007).

One of six minerals proposed to be essential for life emergence. Actually, one of two "vital" candidates due to "comprising precipitate membrane", the other one beingmackinawite (Russell & Pone, 2020).


Unique Identifiers
IMA Formula:
Fe2+4Fe3+2(OH)12(CO3) · 3H2O
Approval year:
2003
First published:
2007

Classification of Fougèrite
6.4.6.2

6 : HYDROXIDES AND OXIDES CONTAINING HYDROXYL
4 : Miscellaneous

Mineral Symbols
Transparency:
Opaque
Colour:
Bluish green, green, green-black, blackish
Comment:
Only when fresh; alters within hours and days

Chemistry of Fougèrite

Crystallography of Fougèrite
General Appearance of Type Material:
Small crystals (400-500 nm) in the form of hexagonal plates.
Place of Conservation of Type Material:
None.
Geological Setting of Type Material:
Subsurface horizon of a Gleysol soil. Partial oxidation and hydrolysis of aqueous Fe2+.
Associated Minerals at Type Locality:
Reference:
Trolard, F., Bourrié, G., Abdelmoula, M., Refait, Ph., Feder, F. (2007) Fougerite, a new mineral of the pyroaurite-iowaite group: description and crystal structure. Clays and Clay Minerals: 55: 323-334.

Synonyms of Fougèrite

Relationship of Fougèrite to other Species
Other Members of this group:
LiudongshengiteZn4Cr2(OH)12(CO3) · 3H2OTrig.3m(32/m) :R3m
MössbaueriteFe3+6O4(OH)8[CO3] · 3H2OTrig.3
TrébeurdeniteFe2+2Fe3+4O2(OH)10CO3 · 3H2OTrig.3m(32/m) :R3m

Common AssociatesTrig.3m(32/m) :R3m4.FL.Mariakrite[Ca4Al2(OH)12(H2O)4][Fe2S4]Tric.1 :P14.FL.05MuskoxiteMg7Fe4O13 · 10H2OTrig.3m(32/m)4.FL.05JamboriteNi2+1-xCo3+x(OH)2-x(SO4)x · nH2OTrig.3m(32/m) :R3m4.FL.05MössbaueriteFe3+6O4(OH)8[CO3] · 3H2OTrig.34.FL.05MeixneriteMg6Al2(OH)16(OH)2 · 4H2OTrig.3m(32/m) :R3m4.FL.05WoodalliteMg6Cr2(OH)16Cl2 · 4H2OTrig.3m(32/m) :R3m4.FL.05DritsiteLi2Al4(OH)12Cl2 · 3H2OHex. 6/mmm(6/m2/m2/m) :P63/mcm4.FL.05RotemiteCa4Cr2(OH)12Cl2 · 4H2OTrig.3m(32/m) :R3c4.FL.05IowaiteMg6Fe3+2(OH)16Cl2 · 4H2OTrig.3m(32/m) :R3m4.FL.10HydrocalumiteCa4Al2(OH)12(Cl,CO3,OH)2 · 4H2OMon. 2 :P214.FL.15KuzeliteCa4Al2(OH)12[SO4] · 6H2OTrig.4.FL.20Jianshuiite(Mg,Mn,Ca)Mn3O7 · 3H2OTrig.3 :R34.FL.20ErnienickeliteNiMn3O7 · 3H2OTrig. 3 :R34.FL.20AuroriteMn2+Mn4+3O7 · 3H2OTrig. 3 :R34.FL.20ChalcophaniteZnMn4+3O7 · 3H2OTrig.3 :R34.FL.25WoodruffiteZn2+x/2(Mn4+1-xMn3+x)O2 · yH2OMon. 2/m :B2/m4.FL.30Asbolane(Ni,Co)2-xMn4+(O,OH)4 · nH2OHex.4.FL.30 vaLampaditeCu, Mn, O, H4.FL.35BuseriteNa4Mn14O27 · 21H2O4.FL.40Takanelite(Mn,Ca)Mn4O9 · H2OHex.4.FL.40Ranciéite(Ca,Mn2+)0.2(Mn4+,Mn3+)O2 · 0.6H2OTrig.3 :P34.FL.45Birnessite(Na,Ca)0.5(Mn4+,Mn3+)2O4 · 1.5H2OMon. 2/m :B2/m4.FL.55CianciulliiteMn(Mg,Mn)2Zn2(OH)10 · 2-4H2OMon. 2/m :B2/m4.FL.60JenseniteCu3[TeO6] · 2H2OMon. 2/m :P21/m4.FL.65LeisingiteCu2MgTe6+O6 · 6H2OTrig. 3 :P34.FL.70AkdalaiteAl10O14(OH)2Hex.4.FL.75CafetiteCaTi2O5 · H2OMon. 2/m :P21/b4.FL.80MouriteUMo5O12(OH)10Mon.4.FL.85DeloryiteCu4(UO2)(MoO4)2(OH)6Mon. 2/m :B2/m4.FL.90LagalyiteCa2xMn1-xO2 · 1.5-2H2OMon.4.FL.95Tunnerite (of Cornu)4.FL.100CarbocalumiteCa4Al2(OH)12(CO3) · 6H2OTrig.3m(32/m) :R3c4.FL.100MampsisiteCa4Al2(CO3)(OH)12 · 5H2OTric.

Fluorescence of Fougèrite

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  • References for FougèriteMills, S. J., Christy, A. G., Génin, J.-M. R., Kameda, T., Colombo, F. (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides.Mineralogical Magazine, 76 (5) 1289-1336doi:10.1180/minmag.2012.076.5.10

    Localities for FougèriteSlag localitiesBlaß et al. (1997)C. Auer (2023)Schebesta (Autoren)+1 other referenceG. Branstetter coll.Neschen (n.d.)+1 other referenceNeschen (n.d.)
    Belgium
     
    Blaß et al. (1995)
    Canada
     
    Norman Wilson collection
    Denmark
     
    Genin et al. (2005)
    France
     
    Chollet et al. (2013)Symposium OS09 et al. (II)Paul PoulainChollet Pascal CollectionF. Trolard et al.: CRAS (Paris)+1 other reference
    Germany
     
    Bender et al. (1994)Neschen (n.d.)+1 other referenceBlaß et al. (1995)Blaß et al. (1995)Blaß et al. (1995)Thomas Kleser CollectionThomas Kleser Collection
    Greece
     
    Gelaude et al. (1996)
    Italy
     
    Gianandrea Ghirri collectionBonifazi (2020)
    Russia
     
    Pavel.M. Kartashov (n.d.)
    Spain
     
    Georges FAVREAU collection + EDS
    Switzerland
     
    Bonifazi Marco
    UK
     
    Norman Wilson collectionNorman Wilson personal collection
     
    and/or 
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