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Macedonite

A valid IMA mineral species
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PbTiO3
Colour:
Black with weak brownish tint; brownish yellow with greenish tint in thin section
Lustre:
Vitreous
Hardness:
5½ - 6
Specific Gravity:
7.82
Crystal System:
Tetragonal
Member of:
Perovskite Subgroup >Stoichiometric Perovskites Group >Perovskite Supergroup
Name:
Named by Radusinović and Markov (1971) after what was, at the time, the constituent country of Macedonia, Yugoslavia. The area is now the country of North Macedonia. The area includes the type locality of Crni Kamen.
Type Locality:
ⓘCrni Kamen, Alinci, Prilep Municipality, North Macedonia
A rare accessory mineral in microcline-quartz syenite pegmatite veins and as inclusions in oxide phases in a metamorphosed Fe-Mn ore body.

Macedonite is an oxide single perovskite with second order Jahn-Teller distortions. The Macedonite fromCrni Kamen is the only natural perovskite mineral known to contain significant amounts of Bi2O3 (2.2 wt.%) (Mitchellet al. 2016).


Unique Identifiers
First published:
1971
Type description reference:
Radusinovic, Dusan, Markov, Cvetko (1971) Macedonite - lead titanate: A new mineral.American Mineralogist, 56 (3-4). 387-394

Classification of Macedonite
Dana 8th ed.:
4.3.6.1

4 : SIMPLE OXIDES
3 : A2X3
Hey's CIM Ref.:
7.11.26

7 : Oxides and Hydroxides
11 : Oxides of Sn and Pb

Mineral Symbols
Transparency:
Opaque
Colour:
Black with weak brownish tint; brownish yellow with greenish tint in thin section
Hardness:
5½ - 6 onMohs scale
Tenacity:
Very brittle
Density:
7.82 g/cm3 (Measured)    8.09 g/cm3 (Calculated)

Optical Data of Macedonite

Crystallography of Macedonite
General Appearance of Type Material:
Small (< 0.2mm) crystals.
Place of Conservation of Type Material:
Institute for Nuclear Raw Materials, Belgrade, Serbia.
U.S. National Museum of Natural History, Washington, D.C., USA: #122391.
Geological Setting of Type Material:
Microcline-quartz syenite pegmatite veins cutting pyroxene amphibole schist.
Associated Minerals at Type Locality:
AegirineArfvedsoniteMicroclineQuartzRutile
Zircon
Reference:
Radusinović, D. and C. Markov (1971) Macedonite - lead titanate: a new mineral. American Mineralogist: 56: 387-394.
Download:
http://rruff.info/rruff_1.0/uploads/AM56_387.pdf

Synonyms of Macedonite

Other Language Names for Macedonite

Relationship of Macedonite to other Species
Other Members of this group:
BarioperovskiteBaTiO3Orth.mm2 :Amm2
GoldschmidtiteKNbO3Iso.m3m(4/m32/m) :Pm3m
Isolueshite(Na,La)NbO3Iso.m3m(4/m32/m) :Pm3m
LakargiiteCa(Zr,Sn,Ti)O3Orth.mmm(2/m2/m2/m) :Pnma
Loparite(Na,REE)2Ti2O6Iso.m3m(4/m32/m)
LueshiteNaNbO3Orth.mmm(2/m2/m2/m)
MegawiteCaSnO3Orth.mmm(2/m2/m2/m) :Pban
PerovskiteCaTiO3Orth.mmm(2/m2/m2/m) :Pnma
TausoniteSrTiO3Iso.43m

Common AssociatesIso.m3m(4/m32/m)4.CC.Yttriaite-(Y)Y2O3Iso.m3(2/m3)4.CC.AllendeiteSc4Zr3O12Trig.3 :R34.CC.ChlorkyuygeniteCa12Al14O32[(H2O)4Cl2]Iso.43m :I43d4.CC.BotuobinskiteSrFe2+Mg2(Cr3+6Ti4+12)[O36(OH)2]Trig.3 :R34.CC.MirnyiteSrZr4+Mg2(Cr3+6Ti4+12)O38Trig.3 :R34.CC.Haitaite-(La)LaU4+Fe3+2(Ti13Fe2+4Fe3+)O38Trig.3 :R34.CC.ShagamiteKFe11O17Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.BitikleiteCa3(Sb5+Sn4+)[AlO4]3Iso.m3m(4/m32/m) :Ia3d4.CC.Anzaite-(Ce)Ce3+ 4Fe2+Ti6O18 (OH)2Mon. 2/m :B2/m4.CC.Heamanite-(Ce)(K0.5Ce0.5)TiO3Iso.m3m(4/m32/m)4.CC.Priscillagrewite-(Y)(Ca2Y)Zr2(AlO4)3Iso.4.CC.SaranovskiteSrCaFe2+2(Cr4Ti2)Ti12O38Trig.3 :R34.CC.05ChrombismiteBi3+16Cr6+O27Iso.m3m(4/m32/m)4.CC.10FreudenbergiteNa2(Ti,Fe)8O16Mon.4.CC.10FluormayeniteCa12Al14O32F2Iso.43m :I43d4.CC.10FluorkyuygeniteCa12Al14O32[(H2O)4F2]Iso.43m :I43d4.CC.15GrossiteCaAl4O7Mon. 2/m :B2/b4.CC.17GoldschmidtiteKNbO3Iso.m3m(4/m32/m) :Pm3m4.CC.20Unnamed (HBU UK-4)NaFe2+Zn2(Ti,Fe3+,Nb)6Ti12O38Trig.3 :R34.CC.20ChlormayeniteCa12Al14O32[◻4Cl2]Iso.43m :I43d4.CC.20PaseroitePbMn2+(Mn2+,Fe3+)2(V5+,Ti,◻)18O38Trig.3 :R34.CC.20Mianningite(◻,Pb,Ce,Na)(U4+,Mn,U6+)Fe3+2 (Ti,Fe3+)18O38Trig.3 :R34.CC.20UM1987-03-O:FePbTiU~(U,Pb)(Ti,Fe3+,Fe2+,Mn)21O38Trig.3 :R34.CC.22GoreriteCaAlFe3+11O19Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.22KahlenbergiteKAl11O17Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.25NixoniteNa2Ti6O13Mon. 2/m :B2/m4.CC.25YafsoaniteCa3Te6+2(ZnO4)3Iso.m3m(4/m32/m) :Ia3d4.CC.30LatrappiteCa2NbFe3+O6Orth.mmm(2/m2/m2/m) :Pnma4.CC.30NatroniobiteNaNbO3Mon.4.CC.30PerovskiteCaTiO3Orth.mmm(2/m2/m2/m) :Pnma4.CC.30LueshiteNaNbO3Orth.mmm(2/m2/m2/m)4.CC.30BarioperovskiteBaTiO3Orth.mm2 :Amm24.CC.30MegawiteCaSnO3Orth.mmm(2/m2/m2/m) :Pban4.CC.30LakargiiteCa(Zr,Sn,Ti)O3Orth.mmm(2/m2/m2/m) :Pnma4.CC.32UsturiteCa3(Sb5+Zr)[Fe3+O4]3Iso.m3m(4/m32/m) :Ia3d4.CC.32ElbrusiteCa3(U6+0.5Zr1.5)[Fe3+O4]3Iso.m3m(4/m32/m) :Ia3d4.CC.32MonteneveiteCa3Sb5+2(Fe3+2Fe2+)O12Iso.m3m(4/m32/m) :Ia3d4.CC.32DzhuluiteCa3(Sb5+Sn4+)[Fe3+O4]3Iso.m3m(4/m32/m) :Ia3d4.CC.35TausoniteSrTiO3Iso.43m4.CC.35Loparite(Na,REE)2Ti2O6Iso.m3m(4/m32/m)4.CC.35Panguite(Ti,Al,Sc,Mg,Zr,Ca)1.8O3Orth.mmm(2/m2/m2/m) :Pbca4.CC.35Isolueshite(Na,La)NbO3Iso.m3m(4/m32/m) :Pm3m4.CC.37PauloabibiteNaNbO3Trig. 3 :R34.CC.40LandauiteNaMnZn2(Ti,Fe)6Ti12O38Trig.3 :R34.CC.40Mathiasite(Mg,Cr,Fe,Ca,K)2(Ti,Zr,Cr,Fe)5O12Trig.3 :R34.CC.40SenaitePb(Mn,Y,U)(Fe,Zn)2(Ti,Fe,Cr,V)18(O,OH)38Trig.3 :R34.CC.40Gramaccioliite-(Y)(Pb,Sr)(Y,Mn)Fe3+2(Ti,Fe3+)18O38Trig.3 :R34.CC.40Lindsleyite(Ba,Sr)(Zr,Ca)(Fe,Mg)2(Ti,Cr,Fe)18O38Trig.4.CC.40CrichtoniteSr(Mn,Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH)38Trig.3 :R34.CC.40Loveringite(Ca,Ce,La)(Zr,Fe)(Mg,Fe)2(Ti,Fe,Cr,Al)18O38Trig.3 :R34.CC.40Cleusonite(Pb,Sr)(U4+,U6+)(Fe2+,Zn)2(Ti,Fe2+,Fe3+)18(O,OH)38Trig. 3 :R34.CC.40Davidite-(Ce)Ce(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38Trig.3 :R34.CC.40Davidite-(La)La(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38Trig.3 :R34.CC.40Davidite-(Y)(La,Ce,Na,Ca,Pb)(Y,Fe2+,◻)(Fe2+,Mn2+)2(Ti,Fe3+,Nb,Zr)18O38 (hypothetical)Trig.4.CC.40UhligiteCa3(Ti,Al,Zr)9O20 ?Iso.4.CC.40Dessauite-(Y)(Sr,Pb)(Y,U)(Ti,Fe3+)20O38Trig.3 :R34.CC.45DiaoyudaoiteNaAl11O17Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.45YimengiteK(Cr,Ti,Fe,Mg)12O19Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.45NežilovitePbZn2Mn4+2Fe3+8O19Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.45HawthorneiteBaMgTi3Cr4Fe2+2Fe3+2O19Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.45Mizraite-(Ce)Ce(Al11Mg)O19Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.45HaggertyiteBaFe2+4Fe3+2Ti5MgO19Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.45LindqvistitePb2Mn2+Fe16O27Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.45HiboniteCaAl12O19Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.45Kangite(Sc,Ti,Al,Zr,Mg,Ca,◻)2O3Iso.m3(2/m3)4.CC.45ChihuahuaiteFeAl12O19Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.45BarioferriteBaFe3+12O19Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.45PlumboferritePb2(Fe3+,Mn2+,Mg)11O19Trig. 32 :P3124.CC.45BatiferriteBaTi2Fe3+8Fe2+2O19Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.45Magnetoplumbite(Pb,Mn)(Fe,Mn)12O19Hex. 6/mmm(6/m2/m2/m) :P63/mmc4.CC.50Jeppeite(K,Ba)2(Ti,Fe)6O13Mon. 2/m :B2/m4.CC.55ZenzénitePb3Fe3+4Mn4+3O15Hex. 6/mmm(6/m2/m2/m) :P63/mcm4.CC.60Mengxianminite (of Huang et al.)(Ca,Na)3(Fe,Mn)2Mg2(Sn,Zn)5Al8O29

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    • References for MacedoniteⓘCrni Kamen (TL)Radusinovic et al. (1971)+1 other reference
    Spain
     
    Calvo+1 other referenceDill et al. (2023)Dill et al. (2023)
    Sweden
     
    Burke et al. (1971)+2 other referencesDunn et al. (1985)+1 other referenceGatedal (n.d.)
    UK
     
    Turner et al. (2010)
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