Movatterモバイル変換


[0]ホーム

URL:


Log InRegister
AboutSupport UsPhotosDiscussionsSearchLearnMore
Quick Links :The Mindat ManualThe Rock H. Currier Digital LibraryMindat Newsletter [Free Download]
Home PageAbout MindatThe Mindat ManualHistory of MindatCopyright StatusWho We AreContact UsAdvertise on Mindat
Donate to MindatCorporate SponsorshipSponsor a PageSponsored PagesMindat AdvertisersAdvertise on Mindat
Learning CenterWhat is a mineral?The most common minerals on earthInformation for EducatorsMindat ArticlesThe ElementsThe Rock H. Currier Digital LibraryGeologic Time
Minerals by PropertiesMinerals by ChemistryAdvanced Locality SearchRandom MineralRandom LocalitySearch by minIDLocalities Near MeSearch ArticlesSearch GlossaryMore Search Options
Search For:
Mineral Name:
Locality Name:
Keyword(s):
 
The Mindat ManualAdd a New PhotoRate PhotosLocality Edit ReportCoordinate Completion ReportAdd Glossary Item
Mining CompaniesStatisticsUsersMineral MuseumsClubs & OrganizationsMineral Shows & EventsThe Mindat DirectoryDevice SettingsThe Mineral Quiz
Photo SearchPhoto GalleriesSearch by ColorNew Photos TodayNew Photos YesterdayMembers' Photo GalleriesPast Photo of the Day GalleryPhotography

Katoite

A valid IMA mineral species
This page is currently not sponsored.Click here to sponsor this page.
Photos of Katoite (21)Discuss Katoite
Katoite GallerySearch Photos of Katoite
EditAdd SynonymEdit CIF structuresClear Cache
+ to each of the four adjacent oxygens (so 4H+ in total) per each one Si4+ lost. This progressive exchange can also be represented as Ca3Al2(SiO4)3-x(OH)4x. In end-member katoite, the replacement is complete (so x = 3).

Previously, the mineral "hibschite" (no longer an IMA-approved species) was considered an intermediate member of the grossular-katoite series, and was defined as Ca3Al2(SiO4)3-x(OH)4x, where x = 0.2-1.5; compositions where x < 0.2 were still considered grossular, whereas compositions where x > 1.5 were considered katoite. Now, based on the modern "50% rule", what was previously called "hibschite" would now be considered grossular (or perhaps more descriptively as "OH-bearing grossular"), although "hibschite", "hydrogrossular" and "hydrogarnet" are still all informally in common use.
Colour:
Colourless
Lustre:
Vitreous
Hardness:
5 - 6
Specific Gravity:
3.013 (Calculated)
Crystal System:
Isometric
Member of:
Name:
Named in 1984 by E. Passaglia and R. Rinaldi in honor of Akira Kato (加藤 昭) (b. 19 June 1931, Tokyo prefecture, Japan), Department of Geology, National Science Museum, Ueno, Tokyo, Japan. Former president of the International Mineralogical Association. In addition to his academic positions, Dr Kato was the founder of one of the most active Tokyo clubs for mineral collectors and amateur mineralogists and he was always willing to help amateurs with their studies.
Type Locality:
Grossular-Katoite Series. Compare also the tetragonal-pseudocubicHoltstamite.
Ungrouped member of theGarnet Supergroup.

For x = 3, i.e. the end member, the species is also known as C3AH6 ("Tricalcium aluminate hydrate") in hydrated cement.
See alsohydrogarnet.

Note that the "hydrogarnet" exchange is not limited to only grossular-rich garnets, and has also been observed involving andradite ("hydro-andradite") and sometimes uvarovite ("hydro-uvarovite") as well. A related exchange, where Si is also replaced by vacancies but the local charge balance is instead maintained by replacing the four adjacent oxygen by fluorine, is particularly notable in some igneous spessartine-rich garnets ("fluor-spessartine"), but occurs in other garnet varieties as well; mixed exchanges (e.g. "fluor-hydro-andradite") are also known.

Katoite from Tadano bears both hexa- and tetravalentsulfur (Banno et al., 2023).



Unique Identifiers
IMA Formula:
Ca3Al2(OH)12
Approval year:
1982

Classification of Katoite
51.4.3d.2

51 : NESOSILICATES Insular SiO4 Groups Only
4 : Insular SiO4 Groups Only with cations in [6] and >[6] coordination
16.9.17

16 : Silicates Containing Aluminum and other Metals
9 : Aluminosilicates of Ca

Mineral Symbols
Colour:
Colourless
Streak:
White
Density:
3.013(5) g/cm3 (Calculated)

Optical Data of Katoite+ to each of the four adjacent oxygens (so 4H+ in total) per each one Si4+ lost. This progressive exchange can also be represented as Ca3Al2(SiO4)3-x(OH)4x. In end-member katoite, the replacement is complete (so x = 3).

Previously, the mineral "hibschite" (no longer an IMA-approved species) was considered an intermediate member of the grossular-katoite series, and was defined as Ca3Al2(SiO4)3-x(OH)4x, where x = 0.2-1.5; compositions where x < 0.2 were still considered grossular, whereas compositions where x > 1.5 were considered katoite. Now, based on the modern "50% rule", what was previously called "hibschite" would now be considered grossular (or perhaps more descriptively as "OH-bearing grossular"), although "hibschite", "hydrogrossular" and "hydrogarnet" are still all informally in common use.
Common Impurities:
Mg,S

Chemical Analysis

Synonyms of Katoite

Other Language Names for Katoite

Varieties of Katoite

Relationship of Katoite to other Species
Other Members of Garnet Supergroup:
Berzeliite GroupX3Z2[TO4]3
Bitikleite GroupCa3Z2[TO4]3
CryolithioniteNa3Al2(LiF4)3Iso.m3m(4/m32/m) :Ia3d
Garnet GroupX3Z2(SiO4)3
Henritermierite GroupCa3Z2(SiO4)2[◻(OH)4]
MidbariteCa3Mg2(V2Si)O12Iso.m3m(4/m32/m)
MonteneveiteCa3Sb5+2(Fe3+2Fe2+)O12Iso.m3m(4/m32/m) :Ia3d
NikmelnikoviteCa12(Fe2+Fe3+3Al3◻)[SiO4]6[◻(OH)4]54Trig.3 :R3
Priscillagrewite-(Y)(Ca2Y)Zr2(AlO4)3Iso.
Schorlomite GroupCa3Z2[SiO4][TO4]2
UM1984-37-SiO:CrMnMn2+3Cr3+2(SiO4)3
XuiteCa3Fe3+2[(AlO3(OH)]3Iso.m3m(4/m32/m)
YafsoaniteCa3Te6+2(ZnO4)3Iso.m3m(4/m32/m) :Ia3d
Forms a series with:

Common AssociatesTet.42m :P421c

Other Information
Search Engines:
  • Look for Katoite on Google
  • Look for Katoite images on Google
  • Look for Katoite on Bing
  • Look for Katoite images on Bing
  • Look for Katoite on DuckDuckGo
  • Look for Katoite images on DuckDuckGo
  • Look for Katoite in the Rock H. Currier Digital Library
  • References for KatoiteKolesov, B. A. (2005) The vibrational spectrum of synthetic hydrogrossular (katoite) Ca3Al2(O4H4)3: A low-temperature IR and Raman spectroscopic study.American Mineralogist, 90 (8) 1335-1341doi:10.2138/am.2005.1622

    Localities for KatoiteMount ErebusKammerer (2011)
    Germany
     
    Wittern (2001)Blaß et al. (2004)Galuskin et al. (2016)
    Hungary
     
    Topographia Mineralogica Hungariae VI.+2 other references
    Israel
     
    Galuskin et al. (2015)Galuskin et al. (2016)Murashko et al. (2025)Galuskin+1 other reference
    Italy
     
    Carlini et al. (2018)Passaglia et al. (1982)
    Japan
     
    Banno et al. (2023)
    Middle East
     
    Gross (1977)
    Norway
     
    Jamtveit et al. (1997)
    Palestine
     
    Galuskina et al. (2019)Galuskin et al. (2015)
    Romania
     
    Marincea et al. (2015)
    Russia
     
    Galuskina et al. (2013)
    Slovakia
     
    Zajzon N. et al. (2021)
     
    and/or 
    Mindat.org is an outreach project of theHudson Institute of Mineralogy, a 501(c)(3) not-for-profit organization.
    Copyright © mindat.org and the Hudson Institute of Mineralogy 1993-2025, except where stated. Most political location boundaries are© OpenStreetMap contributors. Mindat.org relies on the contributions of thousands of members and supporters. Founded in 2000 byJolyon Ralph.
    Privacy Policy -Terms & Conditions -Contact Us / DMCA issues -Report a bug/vulnerabilityCurrent server date and time: April 16, 2025 22:01:16 Page updated: March 22, 2025 09:02:17