Grossular-Katoite Series. Compare also the tetragonal-pseudocubic
Holtstamite.
Ungrouped member of the
Garnet Supergroup.
For x = 3, i.e. the end member, the species is also known as C3AH6 ("Tricalcium aluminate hydrate") in hydrated cement.
See also
hydrogarnet.
Note that the "hydrogarnet" exchange is not limited to only grossular-rich garnets, and has also been observed involving andradite ("hydro-andradite") and sometimes uvarovite ("hydro-uvarovite") as well. A related exchange, where Si is also replaced by vacancies but the local charge balance is instead maintained by replacing the four adjacent oxygen by fluorine, is particularly notable in some igneous spessartine-rich garnets ("fluor-spessartine"), but occurs in other garnet varieties as well; mixed exchanges (e.g. "fluor-hydro-andradite") are also known.
Katoite from Tadano bears both hexa- and tetravalent
sulfur (Banno et al., 2023).