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Hedyphane

A valid IMA mineral species - grandfathered
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First described fromLångban, Sweden and named in 1830 by Johann Friedrich August Breithaupt from the Greek ηδύς for "sweet" or "beautiful" and φαίνεσθαι, "to appear", in allusion to the typical appearance and luster of specimens. Redefined in 1926 by William Foshag and Robert Gage and then redefined by Roland C. Rouse, Pete J. Dunn, and Donald R. Peacor (1984).
Type Locality:
ⓘLångban Mine, Långban Ore District, Filipstad, Värmland County, Sweden
Isostructural with:
Phosphohedyphane
A relatively rare mineral of theApatite Supergroup found in metamorphosed manganese deposits. The Pb3Ca2 analogue ofTurneaureite andMimetite. The arsenate analogue ofPhosphohedyphane. Also the chlorine analogue ofhydroxylhedyphane.

Pb and Ca atoms are ordered on two different cation sites (M1 and M2) in the crystal structure.
Formerly thought to be a Ca-bearing variety ofmimetite.

08336730017366892243061.jpg
Flat, tabular habit
09038520017366898029839.jpg
Semispherulitic aggregates
01089350017366894961422.jpg
Prismatic, needlelike habit
02819140017366908859161.jpg
Massive
04177430017366892595473.jpg
In MW UV light: pale yellow
08336730017366892243061.jpg
Flat, tabular habit
09038520017366898029839.jpg
Semispherulitic aggregates
08141080017366894944579.jpg
Prismatic, needlelike habit
06717290017366908832226.jpg
Massive
04177430017366892595473.jpg
In MW UV light: pale yellow
03664710017366914766831.jpg
Flat, tabular habit
06453400017366914769683.jpg
Semispherulitic aggregates
01130920017366914778247.jpg
Prismatic, needlelike habit
04964010017366914776386.jpg
Massive
00625230017366914785216.jpg
In MW UV light: pale yellow



Unique Identifiers
First published:
1830
Type description reference:
Breithaupt, [J.F.] August (1830) Bestimmung neuer mineral-specien, hedyphan.Journal für Chemie und Physik, 308-316

Classification of Hedyphane

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
N : With only large cations, (OH, etc.):RO4 = 0.33:1
Dana 8th ed.:
41.8.2.1

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
8 : A5(XO4)3Zq
Hey's CIM Ref.:
22.2.17

22 : Phosphates, Arsenates or Vanadates with other Anions
2 : Phosphates, arsenates or vanadates with chloride

Mineral Symbols
Comment:
Bright lustre
Colour:
White, yellowish white, buff, bluish; colourless in transmitted light.
Hardness:
4 - 5 onMohs scale
Tenacity:
Brittle
Fracture:
Sub-Conchoidal
Density:
5.82 g/cm3 (Measured)    

Optical Data of Hedyphane
Surface Relief:
Moderate

Chemistry of Hedyphane

Crystallography of Hedyphane
General Appearance of Type Material:
As finger thick fission filling in garnet-pyroxene matrix.
Geological Setting of Type Material:
Metamorphosed manganese deposit.
Reference:
Breithaupt, [J.F.] August (1830) Bestimmung neuer mineral-specien, hedyphan.Journal für Chemie und Physik, 308-316

Synonyms of Hedyphane

Other Language Names for Hedyphane

Varieties of Hedyphane

Relationship of Hedyphane to other Species
Other Members of Hedyphane Group:
AiolositeNa4Bi(SO4)3ClHex. 6/m :P63/m
CaracoliteNa3Pb2(SO4)3ClMon. 2/m :P21/m
CesaniteNa3Ca2(SO4)3(OH)Hex.6 :P6
FluorphosphohedyphaneCa2Pb3(PO4)3FHex. 6/m :P63/m
FluorsigaiiteCa2Sr3(PO4)3FHex. 6/m :P63/m
HydroxylhedyphaneCa2Pb3(AsO4)3(OH)Trig.3 :P3
Miyahisaite(Sr,Ca)2Ba3(PO4)3FHex. 6/m :P63/m
MorelanditeCa2Ba3(AsO4)3ClHex.
ParafiniukiteCa2Mn3(PO4)3ClHex. 6/m :P63/m
PhosphohedyphaneCa2Pb3(PO4)3ClHex. 6/m :P63/m
UM2002-53-PO:CaHPbCa2Pb3(PO4)3(OH,Cl,F)
Forms a series with:
MimetiteHedyphane-Mimetite Series

Common AssociatesHex. 6/m :P6/m8.BN.AraditeBaCa6[(SiO4)(VO4)](VO4)2FTrig. 3m :R3m8.BN.MagganasiteCuFe3+3O(AsO4)3Tric.1 :P18.BN.FluorpyromorphitePb5(PO4)3FHex. 6/m :P63/m8.BN.FluorsigaiiteCa2Sr3(PO4)3FHex. 6/m :P63/m8.BN.05PieczkaiteMn5(PO4)3ClHex. 6/m :P63/m8.BN.05FluorapatiteCa5(PO4)3FHex. 6/m :P63/m8.BN.05FluorcaphiteSrCaCa3(PO4)3FHex. 6/m :P63/m8.BN.05VanadinitePb5(VO4)3ClHex. 6/m :P63/m8.BN.05HydroxylhedyphaneCa2Pb3(AsO4)3(OH)Trig.3 :P38.BN.05Mimetite-MPb5(AsO4)3ClMon. 2/m :P21/b8.BN.05JohnbaumiteCa5(AsO4)3(OH)Hex. 6/m :P63/m8.BN.05PliniusiteCa5(VO4)3FHex. 6/m :P63/m8.BN.05Hydroxylapatite-MCa5(PO4)3OHMon. 2/m :P21/b8.BN.05HydroxylpyromorphitePb5(PO4)3(OH)Hex. 6/mmm(6/m2/m2/m) :P63/mcm8.BN.05Miyahisaite(Sr,Ca)2Ba3(PO4)3FHex. 6/m :P63/m8.BN.05Carlgieseckeite-(Nd)NaNdCa3(PO4)3FTrig.3 :P38.BN.05Belovite-(Ce)NaCeSr3(PO4)3FTrig.3 :P38.BN.05Kuannersuite-(Ce)NaCeBa3(PO4)3F0.5Cl0.5Trig.3 :P38.BN.05AlforsiteBa5(PO4)3ClHex. 6/m :P63/m8.BN.05Unnamed (OH-analogue of Mimetite)Pb5(AsO4)3(OH)Hex. 6/m :P63/m8.BN.05StronadelphiteSr5(PO4)3FHex. 6/m :P63/m8.BN.05ParafiniukiteCa2Mn3(PO4)3ClHex. 6/m :P63/m8.BN.05MimetitePb5(AsO4)3ClHex. 6/m :P63/m8.BN.05 vaGermanate-pyromorphitePb5(PO4)2GeO48.BN.05Belovite-(La)NaLaSr3(PO4)3FTrig.3 :P38.BN.05FluorphosphohedyphaneCa2Pb3(PO4)3FHex. 6/m :P63/m8.BN.05FluorstrophiteSrCaSr3(PO4)3FHex. 6/m :P63/m8.BN.05HydroxylapatiteCa5(PO4)3(OH)Hex. 6/m :P63/m8.BN.05Johnbaumite-MCa5(AsO4)3OHMon. 2/m :P21/m8.BN.05PhosphohedyphaneCa2Pb3(PO4)3ClHex. 6/m :P63/m8.BN.05TurneaureiteCa5(AsO4)3ClHex. 6/m :P63/m8.BN.05MorelanditeCa2Ba3(AsO4)3ClHex.8.BN.05OxypyromorphitePb10(PO4)6O8.BN.05Deloneite(Na0.5REE0.25Ca0.25)(Ca0.75REE0.25)Sr1.5(CaNa0.25REE0.25)(PO4)3F0.5(OH)0.5Trig. 3 :P38.BN.05ChlorapatiteCa5(PO4)3ClHex. 6/m :P63/m8.BN.05PyromorphitePb5(PO4)3ClHex. 6/m :P63/m8.BN.05VanackeritePb4Cd(AsO4)3ClTrig. 3 :P38.BN.05SvabiteCa5(AsO4)3FHex. 6/mmm(6/m2/m2/m) :P63/mmc8.BN.10ArctiteNa2Ca4(PO4)3FTrig.3m(32/m) :R3m8.BN.10KrügeriteBaCa6(SiO4)2[(P0.5S0.5)O4]2FTrig.3m(32/m) :R3m8.BN.15GoryainoviteCa2(PO4)ClOrth.mmm(2/m2/m2/m) :Pbcm

Fluorescence of Hedyphane

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    • References for HedyphaneⓘRío Agrio Mine ?Brodtkorb (2006)
    Australia
     
    Grubb (1971)+1 other referenceSARIG database - deposit No. 4310.Muller (1972)+2 other references
    Austria
     
    Kolitsch et al. (2021)
    Bulgaria
     
    Minceva-Stefanova (2001)
    Chile
     
    SEM-EDS by Joy Desor
    Czech Republic
     
    [Lapis 1995+1 other referenceC.Auer (2013)Duda
    Germany
     
    Gerstenberg et al. (2017)
    Greece
     
    Rieck et al. (2018)Rieck et al. (2020)Rieck et al. (2022)
    Ireland
     
    de Haller
    Italy
     
    Balestra et al. (2010)Piccoli et al. (2007)Onac (2025)Stara et al. (1995)Rivista Mineralogica Italiana 3/1992-"I minerali del giacimento di Monte Tamara (Nuxis)Conedera M. et al. (2016)A.Costantini (2015)Biagioni et al. (2013)Nannoni et al. (2008)Dini A. (2013)Senesi F. (1999)
    Japan
     
    Yamada et al. (2019)
    Mexico
     
    Betts (n.d.)Panczner (1987)+1 other referenceRocks & Min.: 56:247.Moore (2008)Parker (2010)
    Namibia
     
    Gebhard (1999)Dunn (1991)
    North Macedonia
     
    Bermanec et al. (1993)+1 other referenceBermanec et al+2 other referencesChukanov et al. (2015)Ermolaeva et al. (2019)
    Papua New Guinea
     
    Petersen et al. (2002)
    Spain
     
    Rewitzer et al. (2020)Calvo Rebollar et al. (2022)Rewitzer et al. (2018)Menor (2010)Menor (2010)Menor (2010)Menor (2009)Sainz de Baranda Graf et al. (2023)
    Sweden
     
    Moore (1972)Breithaupt (1830)+4 other referencesWiklund (2016)Adolfsson (1979)Gatedal (2003)Holtstam et al. (1999)Holtstam et al. (1999)Holtstam et al. (1999)Holtstam et al. (1993)+1 other referenceGatedal (2003)Holtstam et al. (1998)Palache et al. (1951)+1 other referenceNysten et al. (2016)+1 other referenceNysten et al. (2016)+1 other reference
    UK
     
    Cooper et al. (1990)+1 other referenceCooper et al. (1990)Turner et al. (2010)
    USA
     
    Joan Rosell - RosellMinerals.com (2014)J.D. MizerRaman ID 12-13-2007 on material ...Bulletin of the Mineralogical Society ...+1 other referenceHayes et al. (2008)Palache (1935)+1 other referenceMiyawaki et al. (2019)+1 other referenceCoolbaugh et al. (2020)SEM-EDS (Mount 12-03, TM#1, Mar.5, 2013)
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