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Dufrénite

A valid IMA mineral species - grandfathered
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Photos of Dufrénite (252)Discuss Dufrénite
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Ca0.5Fe2+Fe3+5(PO4)4(OH)6 · 2H2O
Colour:
Dark green, olive-green, olive-brown, black; olive-brown to reddish brown with oxidation; bluish green to reddish brown or yellow in transmitted light.
Lustre:
Sub-Vitreous, Resinous, Silky
Hardness:
3½ - 4½
Specific Gravity:
3.1 - 3.34
Crystal System:
Monoclinic
Member of:
Name:
Named in 1833 by Alexandre Brongniart in honor of Ours Pierre Armand Petit Dufrenoy [September 5, 1792 - March 20, 1857), Professor of Mineralogy in the École des Mines, Paris, France. (Because of many look-alike species in the environments where dufrénite occurred, species such as rockbridgeite, etc. were called by that name.)
The mineral dufrénoysite is also named in his honor.
Co-Type Localities:
Isostructural with:
A secondary mineral occurring with limonite in gossan of veins and in iron ore deposits.

See alsonatrodufrénite which is visually indistinguishable from dufrénite and appears to be much more common than presently thought (Henry Barwood, unpubl. results).
A (formally) vacancy- andMn2+-dominant member was reported by Sejkora et al. (2006).

Note: dufrénite is the correct spelling, not dufrenite (Burke, 2008).

There are some dufrenite-like species, e.g.,'UM1949-01-PO:Fe'.


Unique Identifiers
IMA Formula:
Ca0.5Fe2+Fe3+5(PO4)4(OH)6 · 2H2O

Classification of Dufrénite

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
K : With large and medium-sized cations, (OH, etc.):RO4 > 1:1 and< 2:1
42.9.1.2

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
9 : (AB)7(XO4)4Zq·xH2O
19.13.4

19 : Phosphates
13 : Phosphates of Fe alone

Mineral Symbols
Transparency:
Translucent, Opaque
Comment:
Silky in cross-section of botryoids
Colour:
Dark green, olive-green, olive-brown, black; olive-brown to reddish brown with oxidation; bluish green to reddish brown or yellow in transmitted light.
Streak:
Green
Tenacity:
Brittle
Cleavage:
Perfect
One perfect, a second cleavage good and both parallel to the fibre direction, with traces of a poor third cleavage at right angles to the other two.
Fracture:
Fibrous
Density:
3.1 - 3.34 g/cm3 (Measured)    3.41 g/cm3 (Calculated)

Optical Data of Dufrénite
Surface Relief:
Moderate
Dispersion:
rv relatively strong
Pleochroism:
Visible
Comments:
X = Deep blue, light brown, light yellow-brown or deep bluish green
Y = Buff, brown, light brown, light yellow-brown
Z = Deep red-brown, dark brown, red-brown, deep olive-brown
(from localities: Rock Run, AL; Siegen, Westphalia; Wheal Phoenix; and Hirs

Chemistry of Dufrénite

Crystallography of Dufrénite

Geological Environment
Place of Conservation of Type Material:
Muséum Nationale d’Histoire Naturelle, Paris, France, number42.47.
Geological Setting of Type Material:
Iron ore deposit
Associated Minerals at Type Locality:

Synonyms of Dufrénite

Other Language Names for Dufrénite

Relationship of Dufrénite to other Species
Other Members of Dufrénite Group:
BimbowrieiteNaMgFe3+5(PO4)4(OH)6 · 2H2OMon. 2/m :B2/b
BurangaiteNaFe2+Al5(PO4)4(OH)6 · 2H2OMon. 2/m :B2/b
GayiteNaMn2+Fe3+5(PO4)4(OH)6 · 2H2OMon. 2/m :B2/b
MatioliiteNaMgAl5(PO4)4(OH)6 · 2H2OMon. 2/m :B2/b
NatrodufréniteNaFe2+Fe3+5(PO4)4(OH)6 · 2H2OMon. 2/m :B2/b

Common AssociatesMon. 2/m :B2/m8.DK.BimbowrieiteNaMgFe3+5(PO4)4(OH)6 · 2H2OMon. 2/m :B2/b8.DK.PuttapaitePb2Mn2+2ZnCr3+4O2(AsO4)4(OH)6 · 12H2OMon. 2/m :B2/m8.DK.10ThalliumpharmacosideriteTlFe4[(AsO4)3(OH)4] · 4H2OIso.43m :F43m8.DK.10NatropharmacosideriteNaFe3+4(AsO4)3(OH)4 · 4H2OIso.43m :P43m8.DK.10PharmacosideriteKFe3+4(AsO4)3(OH)4 · 6-7H2OIso.43m :P43m8.DK.10PlumbopharmacosideritePb0.5Fe3+4(AsO4)3(OH)4 · 5H2OIso.43m :P43m8.DK.10StrontiopharmacosideriteSr0.5Fe4[(AsO4)3(OH)4] · 4H2OTet.42m :P42m8.DK.10BariopharmacosideriteBa0.5Fe3+4(AsO4)3(OH)4 · 5H2OTet.42m :P42m8.DK.10Hydroniumpharmacosiderite(H3O)Fe4(AsO4)3(OH)4 · 4H2OIso.43m :P43m8.DK.12Hydroniumpharmacoalumite(H3O)Al4(AsO4)3(OH)4 · 4.5H2OIso.43m :P43m8.DK.12BariopharmacoalumiteBa0.5Al4(AsO4)3(OH)4 · 4H2OIso.43m :P43m8.DK.12PharmacoalumiteKAl4(AsO4)3(OH)4 · 6.5H2OIso.43m :P43m8.DK.12Calciopharmacoalumite Ca0.5Al4(AsO4)3(OH)4 · 5H2OIso.43m :P43m8.DK.12NatropharmacoalumiteNaAl4(AsO4)3(OH)4 · 4H2OIso.43m :P43m8.DK.15MatioliiteNaMgAl5(PO4)4(OH)6 · 2H2OMon. 2/m :B2/b8.DK.15BurangaiteNaFe2+Al5(PO4)4(OH)6 · 2H2OMon. 2/m :B2/b8.DK.15NatrodufréniteNaFe2+Fe3+5(PO4)4(OH)6 · 2H2OMon. 2/m :B2/b8.DK.15GayiteNaMn2+Fe3+5(PO4)4(OH)6 · 2H2OMon. 2/m :B2/b8.DK.20KidwelliteNaFe3+9+x(PO4)6(OH)11 · 3H2O, x = 0.33Mon. 2/m :P2/b8.DK.25Bleasdaleite(Ca,Fe3+)2Cu5(Bi,Cu)(PO4)4(H2O,OH,Cl)13Mon. 2/m :B2/m8.DK.30Matulaite(Fe3+,Al)Al7(PO4)4(PO3OH)2(OH)8(H2O)8 · 8H2OMon. 2/m8.DK.35KrasnoviteBa(Al,Mg)(PO4,CO3)(OH)2 · H2OOrth.mmm(2/m2/m2/m)

Fluorescence of Dufrénite

Other Information
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  • References for DufréniteCerro Blanco pegmatite districtDina (1993)Demartin et al. (1997)Gay et al. (1991)+1 other referenceOYARZABAL et al. (H2O)+2 other referencesRoda-Robles et al. (2012)
    Australia
     
    Birch et al. (1997)Birch et al. (1997)Day (1998)Johnson (1956)Stuart MillsDerrick+1 other referenceHarrowfield et al. (1981)Kolitsch et al. (1999)Francis (2010)Francis (2010)Frost et al. (2004)Sorrell (n.d.)+1 other referenceElliott et al. (2025)Francis (2010)Noble et al. (1983)Birch et al. (1993)Sue Koepke collectionCollection of NHMSimpson (1920)Peter DownesJacobson et al. (2007)
    Brazil
     
    Sergio Varvello collectionCassedanne (1983)+1 other referenceCassedanne et al. (1999)Sergio Varvello collection
    Canada
     
    Ontario Mineral deposit Inventory ...
    Czech Republic
     
    A. TomwekPovondra et al. (eds.)+1 other referenceČerný et al. (Weisser Stein)ŠkodaPrachař+6 other referencesWeberJanouš+4 other referencesHouzar S.: Přehled minerálů z ...+1 other reference
    Europe
     
    Berbain et al. (2012)
    France
     
    Chollet Pascal CollectionPierre Le Roch & Jean-Marc Johannet ...Walenta et al. (1980)+1 other referenceChauris (2014)Pierre Le Roch & Jean-Marc Johannet ...Patureau et al. (2011)Johannet (2006)Lièvre et al. (2002)perso.wanadoo.fr (2004)Brongniart A: Tab. Espèces Min. (1833)Boisson (1988)+1 other referenceGuide geologique de la Haute Vienneperso.wanadoo.fr (2005)Berbain et al. (2012)
    Germany
     
    Walenta (1992)Palache et al. (1951)+2 other referenceswww.mineralienatlas.de (n.d.)Dana 7:II:77242. (in German)+2 other referencesDill et al. (2009)web.archive.org (2001)Laubmann et al. (1915)Meier (2005)www.mineralienatlas.de (n.d.)Dana 6: 797+1 other referenceBlaß (2002)Wittern (2001)Stieglitz et al. (1987)+1 other referenceWeiß (1990)Hucko (2010)Weiß (1990)+1 other referenceHucko (2010)Marcus Voigt CollectionWeiß (1990)Schaarschmidt (2014)Witzke et al. (1993)U. LudwigPestel et al. (2012)Wittern (2001)Witzke et al. (2001)Witzke et al. (2001)
    Greece
     
    Kolitsch et al. (2014)+1 other referenceRieck et al. (2020)
    Hungary
     
    Körmendy Regina (2011)
    Italy
     
    Stara P. (1996)Fadda (1989)
    Japan
     
    Matsubara et al. (1980)
    Madagascar
     
    Behier (1960)
    Mexico
     
    Michael Shannon specimens
    Morocco
     
    GAUDEFROY (1955)Fontan (1978)
    Namibia
     
    von Bezing (2007)Der Aufschluss 36:117-119Keller et al. (1989)
    Poland
     
    Włodek et al. (2015)Pieczka et al. (2015)
    Portugal
     
    Nunes (n.d.)Pedro Alves collection and/or ...Alves (2016)Alves (n.d.)4+4 other referencesMartins et al. (2011)Rewitzer et al. (1984)+1 other referenceAlves (n.d.)
    Romania
     
    SzakállSzakáll et al. (2010)Szakáll et al. (2010)
    Rwanda
     
    Royal Museum for Central AfricaDaltry et al. (1998)
    South Africa
     
    Cairncross et al. (1995)Cairncross et al. (1995)
    Spain
     
    Sáinz de Baranda et al. (2004)www.foro-minerales.com (2022)+1 other referenceCalvo Rebollar (2015)Camprubí et al. (Catalunya)Tritlla (1987)
    Sweden
     
    Lorin (2022)
    UK
     
    Palache et al. (1951)+1 other referenceKinch et al. (1886)+3 other referencesP D Trebilcock.Elton et al. (1996)+2 other referencesHartley (1984)+1 other referenceStanley et al. (1991)Kingsbury (1957)
    USA
     
    Lavinsky (n.d.)Barwood et al. (1978)+1 other referenceCook et al. (1982)Rocks & Minerals: 70 (5)+2 other referencesDean (1995)Howard (1987)+1 other referenceSmith (1988)Rocks & Min.:64:297-298.Smith (1988)Jason Smith & M.E. Ciriotti (2005)Rocks & Minerals 54:4 pp161-165Nichael SwansonSEM/EDS analyzed by Lloyd W. Alexander ...+1 other referenceDana 6: 1083.Sherwood et al. (1998)Castor et al. (2004)Rocks & Minerals. Nov. 1999.Jensen et al. (2001)Rocks & Min.: 17:250.+1 other referenceMeyers et al. (1956)USGS Prof Paper 353+3 other referencesThompson et al. (2022)Meyers et al. (1956)+1 other referenceManchester (1931)Jerry Cone CollectionNorthrop et al. (1996)Mineralogical Magazine 60:787-793.+2 other referencesNorthrop et al. (1996)Northrop et al. (1996)Northrop et al. (1996)Genth et al. (1881)Wilson et al. (1978)Jason Smith collectionLoomis (2011)Campbell et al. (1985)Loomis (2011)USGS Bull 380DRocks & Minerals: 67 (6)USGS Prof Paper 297BParis (2011)Edwin B (1938)+1 other referenceWatson (1907)+1 other referenceRocks&Min. 47:594 (1972)Cannon (1975)
     
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