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Devilline

A valid IMA mineral species - grandfathered
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CaCu4(SO4)2(OH)6 · 3H2O
Colour:
Green, bluish-green; green in transmitted light.
Lustre:
Vitreous, Sub-Vitreous, Pearly
Hardness:
Specific Gravity:
3.084
Crystal System:
Monoclinic
Member of:
Name:
Named in 1872 by Félix Pisani in honor of Henri Étienne Sainte-Claire Deville [March 11, 1818 Saint Thomas, Virgin Islands - July 1, 1881 Boulogne, Hauts-de-Seine, Ile-de-France, France], French chemist. He was professor of chemistry at the University of Besançon from 1845 - 1851. In 1851-1859, he was professor of chemistry at École Normale Supérieure in Paris. He became professor of chemistry at the Sorbonne in 1859 - 1881. Deville discovered the first economical process to refine aluminum.
Type Locality:
Dimorph of:
Devilline Group.

The calcium analogue oflautenthalite andcampigliaite.
A dimorph (Unnamed (Dimorph of Devilline)) has been found in both a slag and a mine dump.

Visually very similar toorthoserpierite and bladedserpierite.


Unique Identifiers
First published:
1864

Classification of Devilline

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
31.6.1.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
6 : (AB)5(XO4)2Zq·xH2O
25.2.17

25 : Sulphates
2 : Sulphates of Cu and Ag

Mineral Symbols
Transparency:
Transparent
Comment:
Pearly on {001} at times
Colour:
Green, bluish-green; green in transmitted light.
Streak:
Light green
Tenacity:
Brittle
Cleavage:
Perfect
On {001} perfect. On {110} and {101}, or {101}, distinct.
Density:
3.084 g/cm3 (Measured)    3.13 g/cm3 (Calculated)

Optical Data of Devilline
Surface Relief:
Moderate
Dispersion:
small
Pleochroism:
Visible
Comments:
X ~ c = Very light green
Y = Green
Z = b = Turquoise-green

Chemistry of Devilline

Crystallography of Devilline
General Appearance of Type Material:
A think crust of microscopic lamellar crystals, covered by langite.
Place of Conservation of Type Material:
n.d.
Associated Minerals at Type Locality:

Synonyms of Devilline

Other Language Names for Devilline

Varieties of Devilline

Relationship of Devilline to other Species
Other Members of Devilline Group:
Aldridgeite(Cd,Ca)(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m :B2/b
CampigliaiteMn2+Cu4(SO4)2(OH)6 · 4H2OMon. 2 :B2
KobyasheviteCu5(SO4)2(OH)6 · 4H2OTric.1 :P1
LautenthalitePbCu4(SO4)2(OH)6 · 3H2OMon. 2/m :P21/b
OrthoserpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OOrth.mm2 :Pca21
SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m :B2/b
Unnamed (Dimorph of Devilline)CaCu4(SO4)2(OH)6 · 3H2OMon. 2/m :P21/b

Common AssociatesMon. 2/m :P21/b7.DD.05FelsőbányaiteAl4(SO4)(OH)10 · 4H2OMon. 2 :P217.DD.07LlantenesiteCu6Al[SeO4](OH)12Cl · 3H2OTrig. 3m :P31c7.DD.10LangiteCu4(SO4)(OH)6 · 2H2OMon.m7.DD.10FehriteMgCu4(SO4)2(OH)6 · 6H2OMon. 2/m :P21/b7.DD.10PosnjakiteCu4(SO4)(OH)6 · H2OMon.m :Pm7.DD.10WroewolfeiteCu4(SO4)(OH)6 · 2H2OMon.m :Pm7.DD.10GobeliniteCoCu4(SO4)2(OH)6 · 6H2OMon. 2/m :P21/m7.DD.15KobyasheviteCu5(SO4)2(OH)6 · 4H2OTric.1 :P17.DD.15SpangoliteCu6Al(SO4)(OH)12Cl · 3H2OTrig. 3m :P31c7.DD.15Unnamed (Dimorph of Devilline)CaCu4(SO4)2(OH)6 · 3H2OMon. 2/m :P21/b7.DD.20KtenasiteZnCu4(SO4)2(OH)6 · 6H2OMon. 2/m :P21/b7.DD.25ChristeliteCu2Zn3(SO4)2(OH)6 · 4H2OTric.1 :P17.DD.30EdwardsiteCu3Cd2(SO4)2(OH)6 · 4H2OMon. 2/m :P21/b7.DD.30NiedermayriteCdCu4(SO4)2(OH)6 · 4H2OMon. 2/m :P21/m7.DD.30SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m :B2/b7.DD.30CampigliaiteMn2+Cu4(SO4)2(OH)6 · 4H2OMon. 2 :B27.DD.30OrthoserpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OOrth.mm2 :Pca217.DD.35ShigaiteMn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig.3 :R37.DD.35Zincaluminite(Zn1-xAlx)(SO4)x/2(OH)2 · nH2O7.DD.35ZincowoodwarditeZn1-xAlx(OH)2[SO4]x/2 · nH2OTrig.7.DD.35NatroglaucoceriniteZn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OHex.7.DD.35Hydrowoodwardite(Cu1-xAlx)(OH)2[SO4]x/2 · nH2OTrig.3m(32/m) :R3m7.DD.35Honessite(Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2OTrig.7.DD.35Carrboydite(Ni1-xAlx)(SO4)x/2(OH)2 · nH2OHex.7.DD.35Glaucocerinite(Zn1-xAlx)(OH)2(SO4)x/2 · nH2OHex.7.DD.35WermlanditeMg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2OTrig.3m(32/m) :P3c17.DD.35NikischeriteFe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig.3 :R37.DD.35Hydrohonessite(Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2OHex.7.DD.35WoodwarditeCu1-xAlx(OH)2(SO4)x/2 · nH2OTrig.3m(32/m) :R3m7.DD.35MotukoreaiteMg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2OTrig.3m(32/m) :R3m7.DD.35Mountkeithite[(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.7.DD.40Lawsonbauerite(Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2OMon. 2/m :P21/b7.DD.40Torreyite(Mg,Mn2+)72Mn2+2Zn4(SO4)2(OH)22 · 8H2OMon. 2/m :P21/b7.DD.40IsseliteCu6(SO4)(OH)10(H2O)4 · H2OOrth.mm2 :Pmn217.DD.45MooreiteMg92Mn2Zn4(SO4)2(OH)26 · 8H2OMon. 2/m :P2/b7.DD.45Hodgesmithite(Cu,Zn)6Zn(SO4)2(OH)10 · 3H2OTrig. 3 :P37.DD.47LahnsteiniteZn4(SO4)(OH)6 · 3H2OTric. 1 :P17.DD.50NamuwiteZn4(SO4)(OH)6 · 4H2OTrig.3 :P37.DD.50Minohlite(Cu,Zn)7(SO4)2(OH)10 · 8H2OHex.7.DD.52LauraniiteCu6Cd2(SO4)2(OH)12 · 5H2OMon. 2/m :P21/b7.DD.55BechereriteZn7Cu(OH)13[(SiO(OH)3(SO4)]Trig. 3 :P37.DD.60Ramsbeckite(Cu,Zn)15(SO4)4(OH)22 · 6H2OMon. 2/m7.DD.65VonbezingiteCa6Cu3(SO4)3(OH)12 · 2H2OMon. 2/m :P21/b7.DD.70RedgilliteCu6(SO4)(OH)10 · H2OMon. 2/m :P21/b7.DD.75NickelalumiteNiAl4(SO4)(OH)12(H2O)3Mon. 2/m7.DD.75KyrgyzstaniteZnAl4(SO4)(OH)12 · 3H2OMon. 2/m7.DD.75ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 :P217.DD.80Schulenbergite(Cu,Zn)7(SO4)2(OH)10 · 3H2OTrig. 37.DD.80UM1992-30-SO:CCuHZn(Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2OTrig. 3 :P37.DD.80ThérèsemagnaniteNaCo4(SO4)(OH)6Cl · 6H2OTrig.3 :P37.DD.80GuarinoiteZn6(SO4)(OH)10 · 5H2OHex.7.DD.85MontetrisaiteCu6(SO4)(OH)10 · 2H2OOrth.mm2 :Cmc21

Other Information
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  • References for DevillineLogatchev-1 hydrothermal field ?Gablina et al. (2006)
    Austria
     
    Niedermayr et al. (2006)Blass et al. (2001)+1 other referenceKolitsch et al. (2013)Blaß et al. (1999)Niedermayr et al. (1995)Pichler (2009)Niedermayr et al. (1998)Niedermayr et al. (1996)Auer (2023)Puttner (1996)G. Niedermayr: Carinthia II 191./111.:97-102 (2001)Niedermayr (1985)Meixner (1965)+1 other referenceStrasser (1989)Auer (1995)Strasser (1989)Brandstätter et al. (2010)Niedermayr (2008)Kolitsch et al. (2009)Strasser (1989)R.Poeverlein (2016)Strasser (1989)R.Poeverlein (2016)Strasser (1989)Strasser (1989)R.Poeverlein (2016)R.Poeverlein (2016)R.Poeverlein (2016)Poeverlein (2008)Strasser (1989)Auer (2020)Strasser (1989)Niedermayr et al. (2009)Strasser (1989)Landesmuseum Joanneum (Graz, Styria)C.Auer (2020)Auer et al. (2017)C.Auer (2019)Gerald GesselbauerNeschen (n.d.)+4 other referencesMeixner (1965)+1 other referenceArchiv f.LagerstättenforschungAuer (2024)Schebesta (1992)Offenbacher (1994)Neschen (n.d.)Heider et al. (2019)Gröbner et al. (2007)W.Paar (1973)Jakely (Hrsg.)Postl et al. (1988)+1 other referencePostl (1977)Postl (1977)Schnorrer et al. (2005)Schnorrer+Poeverlein (2005)C.Auer (2016)C.Auer (2021)- (1994, July)Schnorrer et al. (2002)Der Aufschluß (2006)Poeverlein et al. (2007)Putz et al. (2012)Meixner (1976)Putz et al. (2007)C.Auer (2021)- (1994, July)58.+1 other reference54 (in German)+1 other reference54 (in German)+1 other reference- (1994, July)Arlt et al. (1994)Schnorrer et al. (2007)Schuster et al. (2005)Kolitsch (2018)Kolitsch (2014)Gröbner et al. (2007)
    Belgium
     
    van Tassel (1979)+1 other referencevan Tassel (1979)
    Canada
     
    Sabina (1972)Sabina (1965)Sabina (2003)Estrie and Gaspesie+3 other referencesSabina (1992)Sabina (1966)Horváth et al. (2019)Sabina (1972)Sabina (1972)
    Chile
     
    Lambiel et al. (2012)
    Czech Republic
     
    RÜSENBERG et al. (1996)C.Auer (2016)PaulišPauliš P. et al. (2015)+1 other referenceLapis 2002 (7/8)Möhn et al. (12/2021)Desor (04/2022)Sejkora et al. (2006)Sejkora et al. (2007)NovotnýZimák+5 other referencesSejkora et al. (2012)Sejkora et al. (2015)Analysed by geology lab Green Gas DPBPauliš et al. (2013)+1 other reference
    DR Congo
     
    Gauthier et al. (1989)Deliens (1996)
    France
     
    Juan M. Garriga collection (http://www.mindat.org/photo-191238.html)Designolle J-L. (1993)Chollet et al. (2013)Chollet et al. (2013)De Ascençao Guedes (2003)De Ascenção Guedes et al. (2021)Germain C. et al. (1990)Bari (1982)Wittern et al. (1997)V. Bourgoin (2013)Queneau (n.d.)Queneau (n.d.)Remy Ph. (2003)Forner et al. (1997)Pélisson et al. (1987)Berbain et al. (1998)Favreau et al. (2003)Gol (2015)Queneau (n.d.)Queneau (n.d.)Gol et al. (2010)De Ascenção Guedes et al. (2002)Patrice Queneau CollectionGol et al. (2010)Georges FAVREAU EDX analysisChollet Pascal CollectionY. Vessely collectionwww.mine-capgaronne.fr (2003)+1 other referenceValérie Galéa-Clolus collection - EDX ...+2 other references
    Germany
     
    Weiß (1990)Walenta (1992)Walenta (1989)+1 other referenceWeiß (1990)Weiß (1990)[Wittern (1995)Gottschalk et al. (1995)Blaß et al. (2000)Walenta (1992)Walenta (1992)Walenta (1985)+1 other referenceWalenta (1992)Walenta (1992)Walenta (1992)Walenta (1991)+1 other referenceHanneberg et al. (2009)+1 other referenceWalenta (1992)Walenta (1991)Belendorff (2021)Habel (1998)Weiß (1990)web.archive.org (2001)Dill et al. (2010)From the PETITJEAN CollectionCollection of Steffen MichalskiBelendorff (2021)Blessing et al. (1991)Marko Burkhardt CollectionCollection Detlef HeilwagenWeiß (1990)Weiß (1990)Weiß (1990)Schnorrer-Köhler (1988)+1 other referenceJoachim Gröbner (2019)Weiß (1990)Schnorrer et al. (2009)Fehr (1983)Schnorrer-Köhler (1981)+1 other reference"Lithothek" collection of the ...Nikoleizig et al. (2010)Gröbner et al. (2011)Steinkamm et al. (1988)Neschen (n.d.)Neschen (n.d.)Hotze (1989)Wittern (2001)Luetcke (n.d.)Weiß (1990)Wittern (2001)Schnorrer-Köhler (1991)Günther Schnorrer Köhler (1985)Weiß (1990)+1 other referenceBender et al. (1994)Henrich et al. (2019)Henrich (2008)Mills et al. (2020)Wittern (2001)Blaß et al. (1995)Blaß et al. (1995)Blaß et al. (1995)Blaß et al. (1995)Lapis 1988 (1)Schnorrer-Köhler (1988)Schnorrer-Köhler (1988)Schnorrer-Köhler (1988)Heckmann et al. (2006)Volker Reppke CollectionSchüller et al. (2013)Weiß (1990)+1 other referencewww.mineralienfreunde-der-pfalz.de (2015)www.mgas.de (2003)Noll (1984)Noll (1984)Wittern (2001)Wittern (2001)Müller (2004)Müller (2004)Müller (2004)Müller (2004)Blaß et al. (2004)+1 other referenceThomas Kleser CollectionWeiß (1990)Habel (2006)+1 other referenceWeiß (1990)Wittern (2001)Der Aufschluss Vol.55Wittern (2001)Thomas Lühr CollectionGröbner et al. (2011)Gröbner et al. (2011)Thomas Lühr CollectionWittern (2001)Gröbner et al. (2011)Neschen (n.d.)Gerhard Möhn Collection Analyzed by ...Knoll (2004)Neschen (n.d.)Gerhard Möhn collectionWittern (2001)Wittern (2001)Frenzel (2009)Wittern (2001)Möhn et al. (07/2020)Haas (n.d.)Schnorrer (1995)+1 other referenceHajek (2010)Markus Gerstmann - CollectionWitzke et al. (1998)43-47+2 other referencesWitzke et al. (1998)Witzke et al. (1998)Gröbner et al. (2008)
    Greece
     
    Wendel (2000)+1 other referenceLAPIS 24 (7/8)+1 other referenceLapis et al. (1999)Rieck (n.d.)
    Hungary
     
    Szakáll et al. (1996)Sánoor Szakáll et al. (1997)Szakáll: Minerals of Rudabánya+1 other referenceSzakáll: Minerals of RudabányaSándor et al. (2005)Sánoor Szakáll et al. (1997)100 mineral localities of Hungary: ...+2 other references100 mineral localities of Hungary: ...+3 other referencesSándor et al. (2005)Sándor et al. (2005)Szakáll et al. (2012)Csanad Loranth (XRD analysis)
    Ireland
     
    S. MORETON et al. (1999)Thorne (n.d.)
    Italy
     
    Georges FAVREAU collection and EDX ...Adorni F. (1997)Aspetti mineralogici dei "Gessi ...Bortolozzi et al. (2017)M.E. Ciriotti+1 other referencePagano et al. (2001)Redazionale (2005)Redazione (2005)Ciriotti et al. (2011)Balestra (2016)Agliuzza et al. (2015)A. Palenzona (2005)Castellaro-KampfCarmagnola et al. (2019)Gentile et al. (2023)Taricco et al. (2014)Luigi Chiappino dataStara et al. (1996)Preite et al. (2007)Stara et al. (1996)SEM/EDX I.Campostrini+1 other referenceMair (1996)Daniel LorenzFerretti et al. (2017)Campostrini et al. (2006)Bortolozzi et al. (2022)Ferretti et al. (2018)Bortolozzi et al. (2021)XRD single crystal analysis at Padova ...Campostrini et al. (2005)Gasparetto et al. (2014)Erica Bittarello+3 other referencesdoi:10.3390/min8060248+2 other referencesBiagioni et al. (2018)Francesco Bonotti find & collectionBiagioni (2009)Pegoraro S. et al. (2009)Boscardin et al. (2011)Neschen (n.d.)Domenico Saccardo et al. (2019)+1 other reference
    Japan
     
    Yamada (2004)Yamada (2004)Shimizu et al. (1993)+1 other referenceYamada (2004)Takada et al. (1982)+1 other referenceMasutomi Museum specimens- (unpublished species lists maintained by local collectors)+1 other referenceYamada (2004)
    Kazakhstan
     
    Pavel.M. Kartashov (n.d.)Palache et al. (1951)
    Mexico
     
    Lapis 2001 (1)
    Morocco
     
    Favreau (n.d.)Herve Osana photo
    Namibia
     
    Gebhard (1999)
    New Zealand
     
    Railton et al. (1990)
    Norway
     
    Raade et al. (1990)Folvik (2019)Raade et al. (1990)+1 other referenceNilsen (1993)Nilsen (1993)Pavel M. Kartashov analytical data (2013)Nordrum (1995)Raade et al. (1990)+1 other referenceWitsø (1995)
    Poland
     
    Siuda (2004)Siuda (2001)Ciesielczuk+6 other referencesŁ. Kruszewski PXRD data (Ł.K., M.Ś., R. Siuda, E. Szełęg)
    Portugal
     
    Antonio Jesus Pimentel specimens+1 other referencePedro Alves analytical dataAlves (n.d.)
    Russia
     
    Pekov I.V. et al. (2010)+1 other referenceЕрохин et al. (2008)
    Slovakia
     
    Števko et al. (2016)Aristides (1879)Slavomir ŠIMKOMartin Števko-unpublishedKoděra (1986)Bancík T. (2014)Koděra (1986)Martin Števko-unpublishedVlasáč et al. (2021)Pauliš et al. (2002)Martin Števko-unpublishedŠtevko M. (2022)Martin Števko-unpublishedŠtevko M. (2021)
    Spain
     
    Rewitzer et al. (2020)Carmona Ruiz et al. (2018)César Menor Salván et al. (2014)Calvo Rebollar (2014)Calvo Rebollar (2014)Calvo Rebollar (2014)Calvo (2008)Calvo (2008)Calvo Rebollar (2014)Calvo Rebollar (2014)Ignacio Herrera+13 other referencesGarrido et al. (2013)Joan Abella i Creus and Joan Viñals i Olià (2012)Calvo Rebollar (2014)G.L. Garcia et al. (2011)Calvo Rebollar (2014)Calvo Rebollar (2014)Favreau (n.d.)
    Sweden
     
    Switzerland
     
    Stalder et al. (1998)Gröbner J. (2018)Cuchet et al. (2012)Ansermet (2012)Stalder et al. (1998)+1 other referenceStalder et al. (1998)86. (in German)+2 other referencesBruno Lüscher collection - collected ...Cuchet et al. (2002)Stalder et al. (1998)
    UK (TL)
     
    Acta Cryst. B28 (1972)Tested : John Attard December 2014.Golley et al. (1995)Golley et al. (1995)Golley et al. (1995)S. Rust collection.Golley et al. (1995)P HaasGolley et al. (1995)Braithwaite et al. (2006)Hartley (1984)+1 other referenceHartley (1984)+2 other referencesCooper et al. (1990)Stanley et al. (1991)Bridges (1987)Van Den Berg (1985)+1 other referenceBraithwaite (1982)Render (n.d.)Green (1987)+2 other referencesS.Rust CollectionDay (1999)Day (1999)Dave Evans collectionS. Rust collectionNational Museum of Wales database+1 other reference
    USA
     
    Anthony et al. (1995)Luetcke (n.d.)Luetcke (n.d.)Luetcke (n.d.)Anthony et al. (1995)Rob BowellLeicht (1971)+1 other referenceCollected by Joe Ruiz. Raman analyzed ...Miklancic collectionAnthony et al. (1995)Anthony et al. (1995)Williams et al. (1963)+1 other referenceBideaux (1980)+1 other referenceLuetcke (n.d.)Luetcke (n.d.)Kampf et al. (2016)+1 other referenceMarty et al. (2010)+1 other referenceThorne (n.d.)self collected 10/21/03+1 other referenceAnalysis performed by Tony KampfThorne (n.d.)David Busha collection SEM-EDS by ...Januzzi et al. (1976)Januzzi (1994)Jensen et al. (2012)Tom Loomis specimenCastor et al. (2004)Jensen (1993)Castor et al. (2004)Castor et al. (2004)Am Min 49:1143-1145+1 other referenceCook (1973)+2 other referencesPalache et al. (1951)Patrick Haynes. Most minerals ID'd via ...Butler (1913)Thorne (n.d.)Thorne (n.d.)Thorne (n.d.)Thorne (n.d.)Thorne (n.d.)Kampf et al. (2008)+1 other referenceCanadian Mineralogist (2001)Kampf et al. (2012)Thorne (n.d.)Kampf et al. (2018)Collected and analyzed by Joy Desor.Luetcke (n.d.)Thorne (n.d.)EDS and XRD analyzed by Anatoly ...Thorne (n.d.)
     
    and/or 
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