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Terbium phosphide

From Wikipedia, the free encyclopedia
Erbium compound
Terbium phosphide
Names
Other names
Terbium monophosphide, phosphanylidyneterbium
Identifiers
3D model (JSmol)
EC Number
  • 234-861-0
  • InChI=1S/P.Tb
    Key: YSYUNNARJACYRQ-UHFFFAOYSA-N
  • P#[Tb]
Properties
PTb
Molar mass189.899
AppearanceBlack crystals
Density6.82 g/cm3
Structure
Cubic
Related compounds
Otheranions
Terbium nitride
Terbium arsenide
Terbium antimonide
Terbium bismuthide
Othercations
Gadolinium phosphide
Dysprosium phosphide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Terbium phosphide is aninorganic compound ofterbium andphosphorus with the chemical formula TbP.[1][2]

Synthesis

[edit]

TbP can be obtained by the reaction of terbium andred phosphorus at 800–1000 °C:

4 Tb + P4 → 4 TbP

The compound can also be obtained by the reaction ofsodium phosphide and anhydrousterbium chloride at 700~800 °C.[3]

Physical properties

[edit]

TbP undergoes aphase transition at 40 GPa from aNaCl-structure to aCsCl-structure.[4] The compound can be sintered withzinc sulfide to make a green phosphor layer.[5]

TbP forms crystals of acubic system,space groupFm3m.[6]

Uses

[edit]

The compound is asemiconductor used in high power, high frequency applications and inlaser diodes and otherphoto diodes.[1]

References

[edit]
  1. ^ab"Terbium Phosphide".American Elements. Retrieved9 January 2022.
  2. ^Knorr, K.; Loidl, A.; Kjems, J. K.; Lüthi, B. (2 December 1979)."Magnetic excitations in TbP".Journal of Magnetism and Magnetic Materials.14 (2):270–272.Bibcode:1979JMMM...14..270K.doi:10.1016/0304-8853(79)90136-7.ISSN 0304-8853. Retrieved9 January 2022.
  3. ^Rowley, Adrian T.; Parkin, Ivan P. (1 January 1993)."Convenient synthesis of lanthanide and mixed lanthanide phosphides by solid-state routes involving sodium phosphide".Journal of Materials Chemistry.3 (7):689–692.doi:10.1039/JM9930300689.ISSN 1364-5501. Retrieved9 January 2022.
  4. ^Adachi, Takafumi; Shirotani, Ichimin; Hayashi, Junichi; Shimomura, Osamu (28 December 1998)."Phase transitions of lanthanide monophosphides with NaCl-type structure at high pressures".Physics Letters A.250 (4–6):389–393.Bibcode:1998PhLA..250..389A.doi:10.1016/S0375-9601(98)00840-8. Retrieved9 January 2022.
  5. ^Raffius, G.; Kötzler, J. (7 February 1983)."Field-dependence of the first-order phase transition in terbium phosphide".Physics Letters A.93 (8):423–425.Bibcode:1983PhLA...93..423R.doi:10.1016/0375-9601(83)90477-2.ISSN 0375-9601. Retrieved9 January 2022.
  6. ^"Terbium Phosphide TbP".materialsproject.org. Retrieved24 December 2021.
Phosphides
Other compounds
Terbium(III)
Terbium(III,IV)
Terbium(IV)
Binary phosphides
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
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