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Rubidium bromide

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Rubidium bromide
Rubidium bromide
Rubidium bromide
Names
IUPAC name
Rubidium bromide
Other names
Rubidium(I) bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.029.238Edit this at Wikidata
UNII
  • InChI=1S/BrH.Rb/h1H;/q;+1/p-1 checkY
    Key: JAAGVIUFBAHDMA-UHFFFAOYSA-M checkY
  • InChI=1/BrH.Rb/h1H;/q;+1/p-1
    Key: JAAGVIUFBAHDMA-REWHXWOFAB
  • [Rb+].[Br-]
Properties
RbBr
Molar mass165.372 g/mol
Appearancewhite crystalline solid
Density3.350 g/cm3
Melting point693 °C (1,279 °F; 966 K)
Boiling point1,340 °C (2,440 °F; 1,610 K)
98 g/100 mL
−56.4·10−6 cm3/mol
Hazards
Flash pointNon-flammable
Related compounds
Otheranions
Rubidium fluoride
Rubidium chloride
Rubidium iodide
Rubidium astatide
Othercations
Lithium bromide
Sodium bromide
Potassium bromide
Caesium bromide
Francium bromide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound

Rubidium bromide is aninorganic compound with thechemical formulaRbBr. It is asalt ofhydrogen bromide. It consists ofbromideanionsBr andrubidiumcationsRb+. It has aNaCl crystal structure, with a lattice constant of 685 picometres.[1]

There are several methods for synthesising rubidium bromide. One involves reactingrubidium hydroxide withhydrobromic acid:

RbOH + HBr → RbBr + H2O

Another method is to neutralizerubidium carbonate with hydrobromic acid:

Rb2CO3 + 2 HBr → 2 RbBr + H2O + CO2

Rubidium metal would react directly with bromine to form RbBr, but this is not a sensible production method, since rubidium metal is substantially more expensive than the carbonate or hydroxide; moreover, the reaction would be explosive.

References

[edit]
  1. ^G. Chern; J. G. Skofronick; W. P. Brug; S. A. Safron (1989). "Surface phonon modes of the RbBr(001) crystal surface by inelastic He-atom scattering".Phys. Rev. B.39 (17):12838–12844.Bibcode:1989PhRvB..3912838C.doi:10.1103/PhysRevB.39.12838.PMID 9948158.
Br(−I)
Br(−I,I)
Br(I)
Br(II)
Br(I,V)
Br(III)
Br(IV)
Br(V)
Br(VII)
Authority control databases: NationalEdit this at Wikidata


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