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Protactinium(V) iodide

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(Redirected fromProtactinium pentaiodide)
Protactinium(V) iodide
Identifiers
Properties
I5Pa
Molar mass865.55823 g·mol−1
Appearanceblack needle crystals[1]
Related compounds
Otheranions
Protactinium(V) fluoride
Protactinium(V) chloride
Protactinium(V) bromide
Othercations
Praseodymium(III) iodide
Thorium(IV) iodide
Uranium(IV) iodide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Protactinium(V) iodide is aninorganic compound, with thechemical formula of PaI5.

Preparation

[edit]

It can be prepared by the reaction of metalsprotactinium andiodine, or by reactingprotactinium(V) chloride,protactinium(V) bromide orprotactinium(V) oxide withsilicon tetraiodide.[2]

Properties

[edit]

It reacts withantimony trioxide in a vacuum at 150 °C to give the iodide oxides PaOI3 and PaO2I; it reacts with protactinium(V) bromide at 350 °C to obtain mixed halides PaBr3I2.[2] It reacts with the monocarbide at 600 °C to givetetraiodide.[3]

Aristid von Grosse was able to produce pure metallic protactinium with the decomposition of protactinium(V) iodide.[4][5]

When heated at 300 °C for a long time, it decomposes and iodine is released:[1]

PaI5 → PaI3 + I2

References

[edit]
  1. ^abV. Scherer, F. Weigel, M. Van Ghemen (December 1967)."Evidence for the existence of protactinium(III) in solid state".Inorganic and Nuclear Chemistry Letters.3 (12):589–595.doi:10.1016/0020-1650(67)80033-3. Archived fromthe original on 2018-06-17. Retrieved2021-09-25.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  2. ^abD. Brown, J. F. Easey, P. J. Jones (1967)."Protactinium(V) iodides".Journal of the Chemical Society A: Inorganic, Physical, Theoretical:1698–1702.doi:10.1039/j19670001698.ISSN 0022-4944. Retrieved2021-09-25.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  3. ^Brown, David; De Paoli, Giovanni; Whittaker, Brian. Conversion of protactinium monocarbide to the penta- and tetrahalides.Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1976. 14: 1336-1338.
  4. ^von Grosse, Aristid (1934). "Element 91".Science.80 (2084):512–516.Bibcode:1934Sci....80..512G.doi:10.1126/science.80.2084.512.PMID 17734249.
  5. ^von Grosse, Aristid (1935). "Zur Herstellung von Protactinium" [For the production of protactinium].Berichte der deutschen chemischen Gesellschaft (A and B Series) (in German).68 (2):307–309.doi:10.1002/cber.19350680218.
Pa(II)
Pa(III)
Pa(IV)
Pa(V)
Salts and covalent derivatives of theiodide ion
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