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Praseodymium(III) bromide

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Praseodymium(III) bromide
Names
IUPAC name
Tribromopraseodymium
Systematic IUPAC name
Praseodymium(III) bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.033.524Edit this at Wikidata
EC Number
  • 236-893-0236-893-0
  • InChI=1S/3BrH.Pr/h3*1H;/q;;;+3/p-3
    Key: PLKCYEBERAEWDR-UHFFFAOYSA-K
  • Br[Pr](Br)Br
Properties
PrBr3
Molar mass380.62 g/mol
AppearanceGreen crystalline solid
Density5.28 g/cm3
Melting point691 °C (1,276 °F; 964 K)[2] Some sources say 693 °C[1]
Boiling point1,547 °C (2,817 °F; 1,820 K)[1]
Structure
Tricapped trigonal prismatic
9
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Irritation
GHS labelling:
GHS07: Exclamation mark
Warning
H315,H319
P261,P280,P305+P351+P338
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Praseodymium(III) bromide is a crystalline compound of onepraseodymium atom and threebromine atoms.[2][3]

Characteristics

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Appearance

[edit]

Praseodymium(III) bromide is a green solid at room temperature.[2][1]It is usually handled as a powder.

Physical

[edit]

Praseodymium(III) bromide's molecular weight is 380.62 g.[2][3][4][5] Praseodymium bromide has a density of 5.28 g/cm2.[6][5]

PrBr3 adopts theUCl3 crystal structure.[7] The praseodymium ions are 9-coordinate and adopt atricapped trigonal prismatic geometry.[8] The praseodymium–bromine bond lengths are 3.05 Å and 3.13 Å.[9]

Chemical

[edit]

Praseodymium(III) bromide ishygroscopic.[4] Praseodymium(III) bromide has anoxidation number of 3.[1]

Hazard

[edit]

Praseodymium(III) bromide can cause skin irritation (H315/R38), eye irritation (H319/R36), and that breathing dust/fume/gas/mist/vapours/spray of Praseodymium(III) bromide should be avoided (P261/S23), that one should wash hands thoroughly after handling (P264), one should wear protective gloves and clothes clothing, and wear eye protection and face protection (P280/S36/S37/S39), and that if one gets Praseodymium(III) bromide in their eyes, that they should wash their eyes cautiously for several minutes, removing contact lenses if possible (P305).[10]

References

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  1. ^abcdWinter, Mark."Praseodymium»praseodymium tribromide [WebElements Periodic Table]".www.webelements.com. Retrieved20 December 2016.
  2. ^abcd"Praseodymium Bromide".American Elements. Retrieved20 December 2016.
  3. ^ab"Praseodymium bromide Br3Pr - PubChem".pubchem.ncbi.nlm.nih.gov. Retrieved20 December 2016.
  4. ^abChambers, Michael."ChemIDplus - 0013536533 - PLKCYEBERAEWDR-UHFFFAOYSA-K - Praseodymium bromide (PrBr3) - Similar structures search, synonyms, formulas, resource links, and other chemical information".chem.nlm.nih.gov. Retrieved20 December 2016.
  5. ^abPhillips, Sidney L. (1995). Dale L. Perry (ed.).Handbook of inorganic compounds. Boca Raton: CRC Press. p. 323.ISBN 9780849386718.
  6. ^"Information on praseodymium bromide: Etacude.com".chemicals.etacude.com. Retrieved20 December 2016.
  7. ^Wells, A. F. (1984).Structural Inorganic Chemistry (5th ed.). Oxford University Press. p. 421.ISBN 978-0-19-965763-6.
  8. ^Greenwood, Norman N.; Earnshaw, Alan (1997).Chemistry of the Elements (2nd ed.).Butterworth-Heinemann. pp. 1240–1241.ISBN 978-0-08-037941-8.
  9. ^Schmid, B.; Hälg, B.; Furrer, A. (1987). "Structure and crystal fields of PrBr3 and PrCl3: A neutron study".J. Appl. Phys.61 (8):3426–3428.Bibcode:1987JAP....61.3426S.doi:10.1063/1.338741.
  10. ^"Praseodymium Bromide | ProChem, Inc".prochemonline.com. Retrieved20 December 2016.
Pr(II)
Pr(III)
Organopraseodymium(III) compounds
Pr(III,IV)
Pr(IV)
Pr(V)
Salts and covalent derivatives of thebromide ion
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