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Plutonium silicide

From Wikipedia, the free encyclopedia
Plutonium silicide
Names
Other names
Plutonium monosilicide
Identifiers
3D model (JSmol)
  • InChI=1S/Pu.Si
    Key: OBLLPTWSBXXIIY-UHFFFAOYSA-N
  • [Pu].[Si]
Properties
PuSi
Molar mass272.09 g/mol
AppearanceGrey crystals
Density10.15
Melting point1,576[1] °C (2,869 °F; 1,849 K)
insoluble
Hazards
GHS labelling:
Warning
Related compounds
Related compounds
Neptunium silicide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Plutonium silicide is a binaryinorganic compound ofplutonium andsilicon with the chemical formula PuSi.[2][3][4] The compound forms gray crystals.

Synthesis

[edit]

Reaction ofplutonium dioxide andsilicon carbide:

PuO2+SiC T PuSi+CO2{\displaystyle {\mathsf {PuO_{2}+SiC\ {\xrightarrow {T}}\ PuSi+CO_{2}\uparrow }}}

Reaction ofplutonium trifluoride with silicon:

4PuF3+7Si T 4PuSi+3SiF4{\displaystyle {\mathsf {4PuF_{3}+7Si\ {\xrightarrow {T}}\ 4PuSi+3SiF_{4}}}}

Physical properties

[edit]

Plutonium silicide forms gray crystals oforthorhombic crystal system, space groupPnma, cell parameters: a = 0.7933 nm, b = 0.3847 nm, c = 0.5727 nm, Z = 4, TiSi type structure.

At a temperature of 72 K, plutonium silicide undergoes aferromagnetic transition.[5]

References

[edit]
  1. ^Macintyre, Jane E. (July 23, 1992).Dictionary of Inorganic Compounds.CRC Press. p. 3783.ISBN 9780412301209. Retrieved16 August 2021.
  2. ^Krikorian, Oscar H.; Hagerty, David C. (1 May 1990)."Exchange reactions of plutonium with silicides and estimation of the enthalpy of formation of Pu5Si3".Journal of Nuclear Materials.171 (2–3):237–244.Bibcode:1990JNuM..171..237K.doi:10.1016/0022-3115(90)90371-S.ISSN 0022-3115. Retrieved16 August 2021.
  3. ^"plutonium silicide - 一矽化鈽". terms.naer.edu.tw. Retrieved16 August 2021.
  4. ^Fish, B. R.; Keilholtz, G. W.; Snyder, W. S.; Swisher, S. D. (November 1972).CALCULATION OF DOSES DUE TO ACCIDENTALLY RELEASED PLUTONIUM FROM AN LMFBR(PDF). Nuclear Safety Information Center. p. 39. Retrieved16 August 2021.
  5. ^Boulet, P.; Wastin, F.; Colineau, E.; Griveau, J. C.; Rebizant, J. (July 2003)."The binary system Pu–Si: crystallochemistry and magnetic properties".Journal of Physics: Condensed Matter.15 (28):S2305 –S2308.Bibcode:2003JPCM...15S2305B.doi:10.1088/0953-8984/15/28/372.ISSN 0953-8984.S2CID 250907789. Retrieved16 August 2021.
Plutonium(II)
Plutonium(III)
Plutonium(IV)
Plutonium(V)
Plutonium(VI)
Plutonium(VIII)
Si(II)
Si(III)
Si(IV)
Salts and covalent derivatives of thesilicide ion
SiH4
+H
He
LiSiBe2SiSiB3
SiB6
+B
SiC
+C
Si3N4
-N
+N
SiO2SiF4Ne
NaSiMg2SiAlSi4−SiP, SiP2
-P
+P
SiS2
-S
SiCl4Ar
KSiCaSi
CaSi2
ScSi Sc5Si3 Sc2Si3 Sc5Si4TiSi
TiSi2
V3Si V5Si3, V6Si5, VSi2, V6Si5Cr3Si Cr5Si3, CrSi, CrSi2MnSi,MnSi2, Mn9Si2, Mn3Si,Mn5Si3, Mn11Si9FeSi2
FeSi
Fe5Si3
Fe2Si
Fe3Si
CoSi,CoSi2,Co2Si, Co3SiNiSi,more…Cu17Si3, Cu56Si11, Cu5Si, Cu33Si7, Cu4Si, Cu19Si6, Cu3Si, Cu87Si13ZnGaGeSi
+Ge
SiAs, SiAs2
-As
+As
SiSe2 SiSeSiBr4Kr
RbSiSrSi2YSi Y5Si3, Y5Si4, Y3Si5, YSi1.4ZrSi Zr5Si3, Zr5Si4,ZrSi2, Zr3Si2, Zr2Si, Zr3SiNb4Si Nb5Si3MoSi2
Mo3Si Mo5Si3
TcRuSi Ru2Si, Ru4Si3, Ru2Si3RhSi Rh2Si, Rh5Si3, Rh3Si2, Rh20Si13PdSi Pd5Si, Pd9Si2, Pd3Si, Pd2SiAgCdInSnSbTeSi2 Te2Si3SiI4Xe
CsSiBa2Si BaSi2, Ba5Si3 Ba3Si4*Lu5Si3HfSi Hf2Si, Hf3Si2, Hf5Si4, HfSi2Ta9Si2, Ta3Si, Ta5Si3WSi2 W5Si3ReSi Re2Si, ReSi1.8 Re5Si3OsSiIrSiPtSiAuHgTlPbBiPoAtRn
FrRa**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*LaSi2 La5Si3, La3Si2, La5Si4, LaSiCeSi2 Ce5Si3, Ce3Si2, Ce5Si4,CeSi, Ce3Si5PrSi2 Pr5Si3, Pr3Si2, Pr5Si4, PrSiNdSi Nd5Si3, Nd5Si4, Nd5Si3, Nd3Si4, Nd2Si3, NdSixPmSmSi2 Sm5Si4, Sm5Si3, SmSi, Sm3Si5Eu?GdSi2 Gd5Si3, Gd5Si4, GdSiTbSi2 SiTb, Si4Tb5, Si3Tb5DySi2 DySiHoSi2 Ho5Si3, Ho5Si4, HoSi, Ho4Si5ErSi2 Er5Si3, Er5Si4, ErSiTm?YbSi Si1.8Yb, Si5Yb3, Si4Yb3, Si4Yb5, Si3Yb5
**AcThSiPaSiUSi2NpSi2PuSiAmCmBkCfEsFmMdNo
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