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Platinum(IV) iodide

From Wikipedia, the free encyclopedia
Platinum(IV) iodide
Names
IUPAC name
tetraiodoplatinum
Other names
Platinum tetraiodide, platinic iodide, platinum(4+) tetraiodide
Identifiers
3D model (JSmol)
ECHA InfoCard100.029.280Edit this at Wikidata
EC Number
  • 232-207-9
UNII
  • InChI=1S/4HI.Pt/h4*1H;/q;;;;+4/p-4
    Key: RNJPWBVOCUGBGY-UHFFFAOYSA-J
  • I[Pt](I)(I)I
Properties
I4Pt
Molar mass702.702 g·mol−1
Appearancebrown crystals
Density6.06 g/cm3
Melting point130 °C (266 °F; 403 K)
decomposes in water
Related compounds
Related compounds
Iridium tetraiodide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Platinum(IV) iodide is ainorganic compound with the formulaPtI4.[1] it is a dark browndiamagnetic solid and is one of several binary iodides of platinum.

Preparation

[edit]

Platinum(IV) iodide can be prepared from the effect of iodine on platinum:[2]

Pt + 2I2 → PtI4

Iodide accelerates this process.[3]

It can also be obtained from the decomposition of hydrogen hexaiodoplatinate(IV) at 80 °C:

H2[PtI6] → PtI4 + 2HI

Physical properties

[edit]

Platinum(IV) iodide forms dark brown crystals of several modifications:[4]

Platinum(IV) iodide decomposes in water. It is also soluble inethanol,acetone,alkali, HI, KI, liquidNH3.[6]

Chemical properties

[edit]

It decomposes when heated:

PtI4 → Pt + 2I2

When dissolved inhydroiodic acid, platinum(IV) iodide forms hydrogen hexaiodoplatinate(IV):

PtI4 + 2HI → H2[PtI6]

References

[edit]
  1. ^Greenwood, Norman N.; Earnshaw, Alan (1997).Chemistry of the Elements (2nd ed.).Butterworth-Heinemann.ISBN 978-0-08-037941-8.
  2. ^Wicks, Charles E.; Block, Frank E. (1963).Thermodynamic Properties of 65 Elements: Their Oxides, Halides, Carbides and Nitrides.U.S. Government Printing Office. p. 92. Retrieved28 March 2024.
  3. ^Olsen, Espen; Hagen, Georg; Eric Lindquist, Sten (2000). "Dissolution of platinum in methoxy propionitrile containing LiI/I2".Solar Energy Materials and Solar Cells.63 (3):267–273.doi:10.1016/s0927-0248(00)00033-7.
  4. ^Macintyre, Jane E. (23 July 1992).Dictionary of Inorganic Compounds.CRC Press. p. 3510.ISBN 978-0-412-30120-9. Retrieved28 March 2024.
  5. ^Donnay, Joseph Désiré Hubert (1978).Crystal Data: Inorganic compounds 1967-1969.National Bureau of Standards. p. 153. Retrieved28 March 2024.
  6. ^"Platinum(IV) iodide, 99.95% (Metals basis), Pt 27.3% min., Thermo Scientific Chemicals, Premion | Fisher Scientific".Fisher Scientific. Retrieved28 March 2024.
Pt(−II)
Pt(0)
Pt(II)
Organoplatinum(II) compounds
Pt(IV)
Pt(V)
Pt(VI)
Salts and covalent derivatives of theiodide ion
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