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Optical depth

From Wikipedia, the free encyclopedia
Physics concept
For other uses, seeOptical depth (astrophysics).
Aerosol Optical Depth (AOD) at 830 nm measured with the same LED sun photometer from 1990 to 2016 at Geronimo Creek Observatory, Texas. Measurements made at or near solar noon when the Sun is not obstructed by clouds. Peaks indicate smoke, dust and smog. Saharan dust events are measured each summer.

Inphysics,optical depth oroptical thickness is thenatural logarithm of the ratio of incident totransmittedradiant power through a material.Thus, the larger the optical depth, the smaller the amount of transmitted radiant power through the material.Spectral optical depth orspectral optical thickness is the natural logarithm of the ratio of incident to transmittedspectral radiant power through a material.[1] Optical depth isdimensionless, and in particular is not a length, though it is a monotonically increasing function ofoptical path length, and approaches zero as the path length approaches zero. The use of the term "optical density" for optical depth is discouraged.[1]

Inchemistry, a closely related quantity called "absorbance" or "decadic absorbance" is used instead of optical depth: thecommon logarithm of the ratio of incident to transmitted radiant power through a material. It is the optical depth divided byloge(10), because of the different logarithm bases used.

Mathematical definitions

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Optical depth

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The optical depth of a material, denotedτ{\textstyle \tau }, is given by:[2]τ=ln(ΦeiΦet)=lnT{\displaystyle \tau =\ln \!\left({\frac {\Phi _{\mathrm {e} }^{\mathrm {i} }}{\Phi _{\mathrm {e} }^{\mathrm {t} }}}\right)=-\ln T}where

The absorbanceA{\textstyle A} is related to optical depth by:τ=Aln10{\displaystyle \tau =A\ln {10}}

Spectral optical depth

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The spectral optical depth in frequency (denotedτν{\displaystyle \tau _{\nu }}) or in wavelength (τλ{\displaystyle \tau _{\lambda }}) of a material is given by:[1]τν=ln(Φe,νiΦe,νt)=lnTν{\displaystyle \tau _{\nu }=\ln \!\left({\frac {\Phi _{\mathrm {e} ,\nu }^{\mathrm {i} }}{\Phi _{\mathrm {e} ,\nu }^{\mathrm {t} }}}\right)=-\ln T_{\nu }}τλ=ln(Φe,λiΦe,λt)=lnTλ,{\displaystyle \tau _{\lambda }=\ln \!\left({\frac {\Phi _{\mathrm {e} ,\lambda }^{\mathrm {i} }}{\Phi _{\mathrm {e} ,\lambda }^{\mathrm {t} }}}\right)=-\ln T_{\lambda },}where

Spectral absorbance is related to spectral optical depth by:τν=Aνln10,{\displaystyle \tau _{\nu }=A_{\nu }\ln 10,}τλ=Aλln10,{\displaystyle \tau _{\lambda }=A_{\lambda }\ln 10,}where

Relationship with attenuation

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Attenuation

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Main article:Attenuation

Optical depth measures the attenuation of the transmitted radiant power in a material. Attenuation can be caused by absorption, but also reflection, scattering, and other physical processes. Optical depth of a material is approximately equal to itsattenuation when both the absorbance is much less than 1 and the emittance of that material (not to be confused withradiant exitance oremissivity) is much less than the optical depth:Φet+Φeatt=Φei+Φee,{\displaystyle \Phi _{\mathrm {e} }^{\mathrm {t} }+\Phi _{\mathrm {e} }^{\mathrm {att} }=\Phi _{\mathrm {e} }^{\mathrm {i} }+\Phi _{\mathrm {e} }^{\mathrm {e} },}T+ATT=1+E,{\displaystyle T+ATT=1+E,}where

  • Φet is the radiant power transmitted by that material;
  • Φeatt is the radiant power attenuated by that material;
  • Φei is the radiant power received by that material;
  • Φee is the radiant power emitted by that material;
  • T = Φetei is the transmittance of that material;
  • ATT = Φeattei is the attenuation of that material;
  • E = Φeeei is the emittance of that material,

and according to theBeer–Lambert law,T=eτ,{\displaystyle T=e^{-\tau },}so:ATT=1eτ+Eτ+Eτ,if τ1 and Eτ.{\displaystyle ATT=1-e^{-\tau }+E\approx \tau +E\approx \tau ,\quad {\text{if}}\ \tau \ll 1\ {\text{and}}\ E\ll \tau .}

Attenuation coefficient

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Optical depth of a material is also related to itsattenuation coefficient by:τ=0lα(z)dz,{\displaystyle \tau =\int _{0}^{l}\alpha (z)\,\mathrm {d} z,}where

  • l is the thickness of that material through which the light travels;
  • α(z) is the attenuation coefficient or Napierian attenuation coefficient of that material atz,

and ifα(z) is uniform along the path, the attenuation is said to be a linear attenuation and the relation becomes:τ=αl{\displaystyle \tau =\alpha l}

Sometimes the relation is given using theattenuation cross section of the material, that is its attenuation coefficient divided by itsnumber density:τ=0lσn(z)dz,{\displaystyle \tau =\int _{0}^{l}\sigma n(z)\,\mathrm {d} z,} where

  • σ is the attenuation cross section of that material;
  • n(z) is the number density of that material atz,

and ifn{\displaystyle n} is uniform along the path, i.e.,n(z)N{\displaystyle n(z)\equiv N}, the relation becomes:τ=σNl{\displaystyle \tau =\sigma Nl}

Applications

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Atomic physics

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Inatomic physics, the spectral optical depth of a cloud of atoms can be calculated from the quantum-mechanical properties of the atoms. It is given byτν=d2nν2cε0σγ{\displaystyle \tau _{\nu }={\frac {d^{2}n\nu }{2\mathrm {c} \hbar \varepsilon _{0}\sigma \gamma }}}where

Atmospheric sciences

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See also:Beer–Lambert law

Inatmospheric sciences, one often refers to the optical depth of the atmosphere as corresponding to the vertical path from Earth's surface to outer space; at other times the optical path is from the observer's altitude to outer space. The optical depth for a slant path isτ =, whereτ′ refers to a vertical path,m is called therelative airmass, and for a plane-parallel atmosphere it is determined asm = secθ whereθ is thezenith angle corresponding to the given path. Therefore,T=eτ=emτ{\displaystyle T=e^{-\tau }=e^{-m\tau '}}The optical depth of the atmosphere can be divided into several components, ascribed toRayleigh scattering,aerosols, and gaseousabsorption. The optical depth of the atmosphere can be measured with aSun photometer.

The optical depth with respect to the height within the atmosphere is given by[3]τ(z)=kaw1ρ0Hez/H{\displaystyle \tau (z)=k_{\text{a}}w_{1}\rho _{0}He^{-z/H}}and it follows that the total atmospheric optical depth is given by[3]τ(0)=kaw1ρ0H{\displaystyle \tau (0)=k_{\text{a}}w_{1}\rho _{0}H}

In both equations:

  • ka is the absorption coefficient
  • w1 is the mixing ratio
  • ρ0 is the density of air at sea level
  • H is thescale height of the atmosphere
  • z is the height in question

The optical depth of a plane parallel cloud layer is given by[3]τ=Qe[9πL2HN16ρl2]1/3{\displaystyle \tau =Q_{\text{e}}\left[{\frac {9\pi L^{2}HN}{16\rho _{l}^{2}}}\right]^{1/3}}where:

  • Qe is the extinction efficiency
  • L is theliquid water path
  • H is the geometrical thickness
  • N is the concentration of droplets
  • ρl is the density of liquid water

So, with a fixed depth and total liquid water path,τN1/3{\textstyle \tau \propto N^{1/3}}.[3]

Astronomy

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Main article:Optical depth (astrophysics)

Inastronomy, thephotosphere of a star is defined as the surface where its optical depth is 2/3. This means that each photon emitted at the photosphere suffers an average of less than one scattering before it reaches the observer. At the temperature at optical depth 2/3, the energy emitted by the star (the original derivation is for the Sun) matches the observed total energy emitted.[citation needed][clarification needed]

Note that the optical depth of a given medium will be different for different colors (wavelengths) of light.

Forplanetary rings, the optical depth is the (negative logarithm of the) proportion of light blocked by the ring when it lies between the source and the observer. This is usually obtained by observation of stellar occultations.

Mars dust storm – optical depth tau – May to September 2018
(Mars Climate Sounder;Mars Reconnaissance Orbiter)
(1:38; animation; 30 October 2018;file description)

See also

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References

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  1. ^abcIUPAC,Compendium of Chemical Terminology, 5th ed. (the "Gold Book") (2025). Online version: (2006–) "Absorbance".doi:10.1351/goldbook.A00028
  2. ^Christopher Robert Kitchin (1987).Stars, Nebulae and the Interstellar Medium: Observational Physics and Astrophysics.CRC Press.
  3. ^abcdPetty, Grant W. (2006).A first course in atmospheric radiation. Sundog Pub.ISBN 9780972903318.OCLC 932561283.

External links

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