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Bixin

From Wikipedia, the free encyclopedia
(Redirected fromNorbixin)
Bixin[1]
Skeletal formula
Skeletal formula
Names
IUPAC name
(2E,4E,6E,8E,10E,12E,14E,16Z,18E)-20-Methoxy-4,8,13,17-tetramethyl-20-oxoicosa-2,4,6,8,10,12,14,16,18-nonaenoic acid
Other names
cis-Bixin; α-Bixin; 9-cis-6,6'-Diapo-ψ,ψ-carotenedioic acid, 6-methyl ester
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard100.027.499Edit this at Wikidata
UNII
  • InChI=1S/C25H30O4/c1-20(12-8-14-22(3)16-18-24(26)27)10-6-7-11-21(2)13-9-15-23(4)17-19-25(28)29-5/h6-19H,1-5H3,(H,26,27)/b7-6+,12-8+,13-9+,18-16+,19-17+,20-10+,21-11+,22-14+,23-15+ checkY
    Key: RAFGELQLHMBRHD-IFNPSABLSA-N checkY
  • InChI=1/C25H30O4/c1-20(12-8-14-22(3)16-18-24(26)27)10-6-7-11-21(2)13-9-15-23(4)17-19-25(28)29-5/h6-19H,1-5H3,(H,26,27)/b7-6+,12-8+,13-9+,18-16+,19-17+,20-10+,21-11+,22-14+,23-15-
    Key: RAFGELQLHMBRHD-SLEZCNMEBU
  • O=C(O)\C=C\C(=C\C=C\C(=C\C=C\C=C(\C=C\C=C(/C=C/C(=O)OC)C)C)C)C
Properties
C25H30O4
Molar mass394.511 g·mol−1
AppearanceOrange crystals
Melting point198 °C (cis-isomer)
217 °C (trans-isomer)
Insoluble
Hazards
NFPA 704 (fire diamond)
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

Bixin is anapocarotenoid found in the seeds of theachiote tree (Bixa orellana)[2] from which it derives its name. It is commonly extracted from the seeds to formannatto, a naturalfood coloring, containing about 5% pigments, of which 70–80% are bixin.[3]

Applications

[edit]
Red seeds of the achiote tree
Bixin is one of the colorants used in the snack Cheetos.

Several thousand tons are harvested annually.[4]

Chemical properties

[edit]

Bixin is unstable. Itisomerizes intotrans-bixin (β-bixin), thedouble-bond isomer.[1]

Chemical structure oftrans-bixin

Bixin is soluble in fats andalcohols but insoluble in water. Upon exposure toalkali, themethylester ishydrolyzed to produce thedicarboxylic acidnorbixin, a water-soluble derivative.

Chemical structure of norbixin

References

[edit]
  1. ^abMerck Index, 11th Edition,1320
  2. ^Bouvier, Florence; Dogbo, Odette; Camara, Bilal (2003)."Biosynthesis of the Food and Cosmetic Plant Pigment Bixin (Annatto)".Science.300 (5628):2089–2091.Bibcode:2003Sci...300.2089B.doi:10.1126/science.1085162.ISSN 0036-8075.JSTOR 3834418.PMID 12829782.S2CID 560600.
  3. ^Executive Summary BixinArchived July 21, 2011, at theWayback Machine, National Toxicology Program
  4. ^Stringheta, Paulo C.; Silva, Pollyanna I.; Costa, André G.V. (2018). "Annatto/Urucum— Bixa orellana".Exotic Fruits. pp. 23–30.doi:10.1016/B978-0-12-803138-4.00006-X.ISBN 9780128031384.
Carotenes (C40)
Xanthophylls (C40)
Apocarotenoids (C<40)
Vitamin A retinoids (C20)
Retinoid drugs
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