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Niobium phosphide

From Wikipedia, the free encyclopedia
Niobium phosphide
Names
Other names
Phosphanylidyneniobium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.031.633Edit this at Wikidata
EC Number
  • 234-810-2
  • InChI=1S/Nb.P
    Key: OATFOCVSPXTLNR-UHFFFAOYSA-N
  • P#[Nb]
Properties
NbP
Molar mass123.88
AppearanceDark-gray crystals
Density6,48 g/cm3
Insoluble
Structure
Tetragonal
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Niobium phosphide is aninorganic compound ofniobium andphosphorus with the chemical formula NbP.[1]

Synthesis

[edit]

Sintering powdered niobium and phosphorus:

4 Nb + P4 → 4 NbP

Physical properties

[edit]

The compound is a unique material combining topological and conventional electronic phases. Its superfast electrons demonstrate extremely largemagnetoresistance, so NbP may be suitable for use in new electronic components.[2]

Niobium phosphide forms dark gray crystals of thetetragonal system,space groupI 41md, cell parametersa = 0.3334 nm,c = 1.1378 nm,Z = 4.[3]

It does not dissolve in water.

Niobium phosphide, liketantalum arsenide TaAs, is a topologicalWeyl semimetal.[4][5]

Uses

[edit]

The compound is asemiconductor used in high power, high frequency applications and in laser diodes.[1]

Niobium phosphate is also being explored specifically for replacing copper as an ultra-thin nanometer film, where it exhibits much lower resistance than the conventional metal.[6]

References

[edit]
  1. ^ab"Niobium Phosphide".American Elements. Retrieved15 December 2021.
  2. ^Chen, Yulin (July 13, 2015)."Niobium Phosphide (NbP) Holds Promise for New Magnetoresistance Components".Power Electronics. Retrieved15 December 2021.
  3. ^Lomnits’ka, Ya. F.; Shupars’ka, A. I. (1 July 2006)."Reactions of niobium and tungsten with phosphorus".Powder Metallurgy and Metal Ceramics.45 (7–8):361–364.doi:10.1007/s11106-006-0090-1.S2CID 102218365. Retrieved15 December 2021.
  4. ^Xu, Di-Fei; Du, Yong-Ping; Wang, Zhen; Li, Yu-Peng; Niu, Xiao-Hai; Yao, Qi; Pavel, Dudin; Xu, Zhu-An; Wan, Xian-Gang; Feng, Dong-Lai (18 September 2015)."Observation of Fermi Arcs in Non-Centrosymmetric Weyl Semi-Metal Candidate NbP".Chinese Physics Letters.32 (10): 107101.arXiv:1509.03847.Bibcode:2015ChPhL..32j7101X.doi:10.1088/0256-307x/32/10/107101.S2CID 124554632. Retrieved15 December 2021.
  5. ^Fu, Yan-Long; Sang, Hai-Bo; Cheng, Wei; Zhang, Feng-Shou (1 September 2020)."Topological properties after light ion irradiation on Weyl semimetal niobium phosphide from first principles".Materials Today Communications.24: 100939.doi:10.1016/j.mtcomm.2020.100939.S2CID 212936560. Retrieved15 December 2021.
  6. ^Zhai, Enzi; Liang, Tianyu; Liu, Ruizi; Cai, Mingyang; Li, Ran; Shao, Qiming; Su, Cong; Lin, Yuxuan Cosmi (August 2024)."The rise of semi-metal electronics".Nature Reviews Electrical Engineering.1 (8):497–515.doi:10.1038/s44287-024-00068-z.ISSN 2948-1201.
Niobium(II)
Niobium(III)
Niobium(IV)
Niobium(V)
Organoniobium(V)
Phosphides
Other compounds
Binary phosphides
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
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