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Neodymium(III) hydroxide

From Wikipedia, the free encyclopedia
Neodymium(III) hydroxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.036.816Edit this at Wikidata
EC Number
  • 240-514-4
  • InChI=1S/Nd.3H2O/h;3*1H2/q+3;;;/p-3
    Key: ZBAQHMBLDSQPHC-UHFFFAOYSA-K
  • [Nd+3].[OH-].[OH-].[OH-]
Properties
Nd(OH)3
Molar mass195.266
Appearancerose solid[1]
Related compounds
Otheranions
neodymium(III) oxide
Othercations
praseodymium(III) hydroxide
samarium(III) hydroxide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Neodymium(III) hydroxide is an insolubleinorganic compound with thechemical formula Nd(OH)3.[2][3]

Preparation

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Neodymium(III) nitrate andammonia water will react to produce neodymium(III) hydroxide:[4]

Nd(NO3)3 + 3 NH3·H2O → Nd(OH)3↓ + 3 NH4NO3

If the amount of Nd(NO3)3 is 40g/L, the amount of ammonia water needed is 0.50 mol/L. The ammonia water is mixed into the Nd(NO3)3 solution at the speed of 1.5mL/min, andpolyethylene glycol is used to control pH. The process will produce neodymium(III) hydroxide powder with grain size ≤1μm.[5]

Chemical properties

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Neodymium(III) hydroxide can react withacid and produceneodymium salts:

Nd(OH)3 + 3 H+ → Nd3+ + 3 H2O

For example, to createneodymium acetate with neodymium(III) hydroxide:[6]

Nd(OH)3 + 3CH3COOH → Nd(CH3COO)3 + 3H2O

See also

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References

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  1. ^《无机化学丛书》. 第七卷 钪 稀土元素. 易宪武 等主编. 科学出版社. P168~171. (2)氢氧化物
  2. ^PubChem."Neodymium hydroxide (Nd(OH)3)".pubchem.ncbi.nlm.nih.gov. Retrieved2022-11-24.
  3. ^Elements, American."Neodymium Hydroxide".American Elements. Retrieved2022-11-24.
  4. ^《无机化合物制备手册》. 朱文祥 主编. 化学工业出版社. 【III-119】氢氧化钕(neodymium hydroxide)
  5. ^刘治平, 王晓铁. 氢氧化镧和氢氧化钕微粉的制备[J]. 《稀土》. Vol.25 No.3 Jun.2004
  6. ^Patnaik, Pradyot (2003).Handbook of inorganic chemicals. McGraw-Hill handbooks. Vol. 40. New York, NY:McGraw Hill Education. pp. 639–640.doi:10.5860/choice.40-6428 (inactive 1 February 2025).ISBN 978-0-07-049439-8.{{cite book}}:|journal= ignored (help)CS1 maint: DOI inactive as of February 2025 (link)
Nd(II)
Nd(III)
Nd(IV)
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