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Mohs scale

From Wikipedia, the free encyclopedia
Qualitative scale characterizing scratch resistance

Open wooden box with ten compartments, each containing a numbered mineral specimen.
Mohs hardness kit, containing one specimen of each mineral on the ten-point hardness scale

TheMohs scale (/mz/MOHZ) of mineral hardness is aqualitativeordinal scale, from 1 to 10, characterizingscratch resistance ofminerals through the ability of harder material to scratch softer material.

The scale was introduced in 1812 by the Germangeologist andmineralogistFriedrich Mohs, in his bookVersuch einer Elementar-Methode zur naturhistorischen Bestimmung und Erkennung der Fossilien (English: Attempt at an elementary method for the natural-historical determination and recognition of fossils);[1][2][a] it is one of several definitions ofhardness inmaterials science, some of which are more quantitative.[3]

The method of comparing hardness by observing which minerals can scratch others is of great antiquity, having been mentioned byTheophrastus in his treatiseOn Stones,c. 300 BC, followed byPliny the Elder in hisNaturalis Historia,c. AD 77.[4][5][6] The Mohs scale is useful for identification of minerals in thefield, but is not an accurate predictor of how well materials endure in an industrial setting.[7]

Reference minerals

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The Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to visibly scratch another mineral.Minerals are chemically pure solids found in nature.Rocks are mixtures of one or more minerals.

Mohs scale along the horizontal axis matched with
one of theabsolute hardness scales along the
vertical. Vertical scale is logarithmic.

Diamond was the hardest known naturally occurring mineral when the scale was designed, and defines the top of the scale, arbitrarily set at 10. The hardness of a material is measured against the scale by finding the hardest material that the given material can scratch, or the softest material that can scratch the given material. For example, if some material is scratched byapatite but not byfluorite, its hardness on the Mohs scale would be between 4 and 5.[8]

Technically, "scratching" a material for the purposes of the Mohs scale means creating non-elastic dislocations visible to the naked eye. Frequently, materials that are lower on the Mohs scale can create microscopic, non-elastic dislocations on materials that have a higher Mohs number. While these microscopic dislocations are permanent and sometimes detrimental to the harder material's structural integrity, they are not considered "scratches" for the determination of a Mohs scale number.[9]

Each of the ten hardness values in the Mohs scale is represented by areference mineral, most of which are widespread in rocks.

The Mohs scale is anordinal scale. For example,corundum (9) is twice as hard astopaz (8), but diamond (10) is four times as hard as corundum.[citation needed] The table below shows the comparison with theabsolute hardness measured by asclerometer, with images of the reference minerals in the rightmost column.[10][11]

Mohs
hardness
Reference
mineral
Chemical formulaAbsolute
hardness[12]
Example image
1TalcMg3Si4O10(OH)21
2GypsumCaSO4·2H2O2
3CalciteCaCO314
4FluoriteCaF221
5ApatiteCa5(PO4)3(OH,Cl,F)48
6Orthoclase
feldspar
KAlSi3O872
7QuartzSiO2100
8TopazAl2SiO4(OH,F)2200
9CorundumAl2O3400
10DiamondC1500

Examples

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Below is a table of more materials by Mohs scale. Some of them have a hardness between two of the Mohs scale reference minerals. Some solid substances that are not minerals have been assigned a hardness on the Mohs scale. Hardness may be difficult to determine, or may be misleading or meaningless, if a material is a mixture of two or more substances; for example, some sources have assigned a Mohs hardness of 6 or 7 to granite but it is a rock made of several minerals, each with its own Mohs hardness (e.g. topaz-rich granite contains: topaz — Mohs 8, quartz — Mohs 7, orthoclase — Mohs 6, plagioclase — Mohs 6–6.5, mica — Mohs 2–4).

HardnessSubstance
0.2–0.4Potassium[13]
0.5–0.6Lithium[13]
1Talc
1.5Lead[13]
2Hardwood[14]
2–2.5Plastic
2.5Zinc[13]
2.5–3Copper[13]
3Brass
3.5Adamite
3.5-4Sphalerite
4Iron[13]
4–4.5Ordinarysteel
4.5Colemanite
5Apatite
5-5.5Goethite
5.5Glass
5.5–6Opal
6Rhodium[13]
6-6.5Rutile
6.5Silicon[13]
6.5–7Jadeite
7Porcelain
7-7.5Garnet
7.5Tungsten[13]
7.5–8Emerald
8Topaz
8.5Chromium[13]
9Sapphire
9–9.5Moissanite
9.5–near 10Boron[13]
10Diamond

Use

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Despite its lack of precision, the Mohs scale is relevant for field geologists, who use it to roughly identify minerals using scratch kits. The Mohs scale hardness of minerals can be commonly found in reference sheets.

Mohs hardness is useful inmilling. It allows the assessment of which type of mill and grinding medium will best reduce a given product whose hardness is known.[15]

Electronic manufacturers use the scale for testing the resilience of flat panel display components (such as cover glass forLCDs or encapsulation forOLEDs), as well as to evaluate the hardness of touch screens in consumer electronics.[16]

Comparison with Vickers scale

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Comparison between Mohs hardness andVickers hardness:[17]

Mineral
name
Hardness (Mohs)Hardness (Vickers)
(kg/mm2)
Tin1.5VHN10 = 7–9
Bismuth2–2.5VHN100 = 16–18
Gold2.5VHN10 = 30–34
Silver2.5VHN100 = 61–65
Chalcocite2.5–3VHN100 = 84–87
Copper2.5–3VHN100 = 77–99
Galena2.5VHN100 = 79–104
Sphalerite3.5–4VHN100 = 208–224
Heazlewoodite4VHN100 = 230–254
Goethite5–5.5VHN100 = 667
Chromite5.5VHN100 = 1,278–1,456
Anatase5.5–6VHN100 = 616–698
Rutile6–6.5VHN100 = 894–974
Pyrite6–6.5VHN100 = 1,505–1,520
Bowieite7VHN100 = 858–1,288
Euclase7.5VHN100 = 1,310
Chromium8.5VHN100 = 1,875–2,000

Footnotes

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  1. ^
    In demselben Jahre (1812) wurde MOHS als Professor am Joanneum angestellt und veröffentliche den ersten Teil seines WerkesVersuch einer Elementarmethode zur naturhistorischen Bestimmung und Erkennung der Fossilien, in welcher die bekannte Härteskala aufgestellt wurde.von Groth (1926)
     
    In the same year (1812) MOHS was employed as a professor at the Joanneum and published the first part of his workAttempt at an elementary method for the natural-historical determination and recognition of fossils, in which the well-known hardness scale was set up.[1]

See also

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References

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  1. ^abvon Groth, Paul Heinrich (1926).Entwicklungsgeschichte der Mineralogischen Wissenschaften [History of the development of the mineralogical sciences] (in German). Berlin: Springer. p. 250.ISBN 9783662409107.{{cite book}}:ISBN / Date incompatibility (help)
  2. ^"Mohs hardness".Encyclopædia Britannica (online ed.).
  3. ^"Mohs scale of hardness".Mineralogical Society of America. Retrieved10 February 2021.
  4. ^Theophrastus.Theophrastus on Stones. Retrieved10 December 2011 – via Farlang.com.
  5. ^Pliny the Elder."Book 37, Chap. 15".Naturalis Historia.Adamas: Six varieties of it. Two remedies.
  6. ^Pliny the Elder."Book 37, Chap. 76".Naturalis Historia.The methods of testing precious stones.
  7. ^"Hardness". Materials Mechanical Hardness. Non-Destructive Testing Resource Center. Archived fromthe original on 14 February 2014.
  8. ^"Mohs scale of mineral hardness".American Federation of Mineralogical Societies – via amfed.org.
  9. ^Geels, Kay (26 April 2000). "The true microstructure of materials".Materialographic Preparation from Sorby to the Present(PDF). Application notes and guides (Report). The Struers metallographic library. Copenhagen, DK: Struers A/S. pp. 5–13. Archived fromthe original(PDF) on 7 March 2016.
  10. ^"What is important about hardness?". Amethyst galleries. Mineral gallery. Archived fromthe original on 30 December 2006 – via galleries.com.
  11. ^"Mineral hardness and hardness scales". Inland Lapidary.Archived from the original on 17 October 2008 – via inlandlapidary.com.
  12. ^Mukherjee, Swapna (2012).Applied Mineralogy: Applications in industry and environment. Springer Science & Business Media. p. 373.ISBN 978-94-007-1162-4 – via Google books.
  13. ^abcdefghijkSamsonov, G.V., ed. (1968). "Mechanical properties of the elements".Handbook of the Physicochemical Properties of the Elements. New York, NY: IFI-Plenum. p. 432.doi:10.1007/978-1-4684-6066-7.ISBN 978-1-4684-6068-1.
  14. ^"Mohs Hardness Scale: Testing the Resistance to Being Scratched".geology.com. Retrieved9 August 2021.
  15. ^"Size reduction, comminution". Grinding and milling. PowderProcess.net. Retrieved27 October 2017.
  16. ^Purdy, Kevin (16 May 2014)."Hardness is not toughness: Why your phone's screen may not scratch, but will shatter".Computerworld. IDG Communications Inc. Retrieved16 April 2021.
  17. ^Ralph, Jolyon."Welcome to mindat.org".mindat.org. Hudson Institute of Mineralogy. Retrieved16 April 2017.

Further reading

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