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Manganese(II) fluoride

From Wikipedia, the free encyclopedia
Manganese(II) fluoride
Names
IUPAC name
Manganese(II) fluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.029.054Edit this at Wikidata
EC Number
  • 231-960-0
RTECS number
  • OP0875000
UNII
  • InChI=1S/2FH.Mn/h2*1H;/q;;+2/p-2 ☒N
    Key: CTNMMTCXUUFYAP-UHFFFAOYSA-L ☒N
  • InChI=1/2FH.Mn/h2*1H;/q;;+2/p-2
    Key: CTNMMTCXUUFYAP-NUQVWONBAJ
  • F[Mn]F
Properties
MnF2
Molar mass92.934855 g/mol
Appearancepale pink crystalline
Density3.98 g/cm3[1]
Melting point856 °C (1,573 °F; 1,129 K)[1]
Boiling point1,820 °C (3,310 °F; 2,090 K)
1.02 g/100 ml
+10,700·10−6 cm3/mol
Hazards[2]
GHS labelling:
GHS07: Exclamation mark
Warning
H302,H312,H315,H319,H332,H335
P261,P264,P270,P271,P280,P301+P312,P302+P352,P304+P312,P304+P340,P305+P351+P338,P312,P321,P322,P330,P332+P313,P337+P313,P362,P363,P403+P233,P405,P501
Flash pointnon-flammable
Related compounds
Otheranions
Manganese(II) chloride
Manganese(II) bromide
Manganese(II) iodide
Othercations
Technetium(VI) fluoride
Rhenium(VII) fluoride
Manganese(III) fluoride
Manganese(IV) fluoride
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

Manganese(II) fluoride is thechemical compound composed ofmanganese andfluoride with theformula MnF2. It is a light pink solid, the light pink color being characteristic for manganese(II) compounds. It is made by treating manganese and diverse compounds of manganese(II) inhydrofluoric acid. Like some other metal difluorides, MnF2 crystallizes in therutile structure, which features octahedral Mn centers.[3]

Uses

[edit]

MnF2 is used in the manufacture of special kinds ofglass andlasers.[4]It is a canonical example of uniaxial antiferromagnet (with Neel temperature of 68 K)[5] which has been experimentally studied since early on.[6]

References

[edit]
  1. ^abMaurice Griffel; J. W. Stout (1950). "Preparation of Single Crystals of Manganous Fluoride. The Crystal Structure from X-Ray Diffraction. The Melting Point and Density".Journal of the American Chemical Society.72 (10):4351–4353.doi:10.1021/ja01166a004.
  2. ^"339288 Manganese(II) fluoride 98%". Sigma-Aldrich. Retrieved2008-06-18.
  3. ^Stout, J. W.; Reed, Stanley A. (1954). "The Crystal Structure of MnF2, FeF2, CoF2, NiF2 and ZnF2".J. Am. Chem. Soc.76 (21):5279–5281.doi:10.1021/ja01650a005.
  4. ^Ayres, D. C.; Hellier, Desmond (1997).Dictionary of Environmentally Important Chemicals. CRC Press. p. 195.ISBN 0-7514-0256-7. Retrieved2008-06-18.
  5. ^Felcher, G. P; Kleb, R (20 November 1996). "Antiferromagnetic domains and the spin-flop transition of MnF 2".Europhysics Letters (EPL).36 (6):455–460.Bibcode:1996EL.....36..455F.doi:10.1209/epl/i1996-00251-7.S2CID 250849056.
  6. ^Stout, J. W.; Matarrese, L. M. (1 January 1953). "Magnetic Anisotropy of the Iron-Group Fluorides".Reviews of Modern Physics.25 (1):338–343.Bibcode:1953RvMP...25..338S.doi:10.1103/RevModPhys.25.338.
Manganese(−I)
Manganese(0)
Manganese(I)
Manganese(II)
Manganese(II,III)
Manganese(II,IV)
Manganese(III)
Manganese(IV)
Manganese(V)
Manganese(VI)
Manganese(VII)
Salts and covalent derivatives of thefluoride ion
HF?HeF2
LiFBeF2BF
BF3
B2F4
+BO3
CF4
CxFy
+CO3
NF3
FN3
N2F2
NF
N2F4
NF2
?NF5
+N
+NO3
OF2
O2F2
OF
O3F2
O4F2
?OF4
F2Ne
NaFMgF2AlF
AlF3
SiF4P2F4
PF3
PF5
+PO4
S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4
ClF
ClF3
ClF5
?ArF2
?ArF4
KFCaF
CaF2
ScF3TiF2
TiF3
TiF4
VF2
VF3
VF4
VF5
CrF2
CrF3
CrF4
CrF5
?CrF6
MnF2
MnF3
MnF4
?MnF5
FeF2
FeF3
FeF4
CoF2
CoF3
CoF4
NiF2
NiF3
NiF4
CuF
CuF2
?CuF3
ZnF2GaF2
GaF3
GeF2
GeF4
AsF3
AsF5
Se2F2
SeF4
SeF6
+SeO3
BrF
BrF3
BrF5
KrF2
?KrF4
?KrF6
RbFSrF
SrF2
YF3ZrF2
ZrF3
ZrF4
NbF4
NbF5
MoF4
MoF5
MoF6
TcF4
TcF
5

TcF6
RuF3
RuF
4

RuF5
RuF6
RhF3
RhF4
RhF5
RhF6
PdF2
Pd[PdF6]
PdF4
?PdF6
Ag2F
AgF
AgF2
AgF3
CdF2InF
InF3
SnF2
SnF4
SbF3
SbF5
TeF4
?Te2F10
TeF6
+TeO3
IF
IF3
IF5
IF7
+IO3
XeF2
XeF4
XeF6
?XeF8
CsFBaF2 LuF3HfF4TaF5WF4
WF5
WF6
ReF4
ReF5
ReF6
ReF7
OsF4
OsF5
OsF6
?OsF
7

?OsF
8
IrF2
IrF3
IrF4
IrF5
IrF6
PtF2
Pt[PtF6]
PtF4
PtF5
PtF6
AuF
AuF3
Au2F10
?AuF6
AuF5•F2
Hg2F2
HgF2
?HgF4
TlF
TlF3
PbF2
PbF4
BiF3
BiF5
?PoF2
PoF4
PoF6
AtF
?AtF3
?AtF5
RnF2
?RnF
4

?RnF
6
FrFRaF2 LrF3RfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
LaF3CeF3
CeF4
PrF3
PrF4
NdF2
NdF3
NdF4
PmF3SmF
SmF2
SmF3
EuF2
EuF3
GdF3TbF3
TbF4
DyF2
DyF3
DyF4
HoF3ErF3TmF2
TmF3
YbF2
YbF3
AcF3ThF3
ThF4
PaF4
PaF5
UF3
UF4
UF5
UF6
NpF3
NpF4
NpF5
NpF6
PuF3
PuF4
PuF5
PuF6
AmF2
AmF3
AmF4
?AmF6
CmF3
CmF4
 ?CmF6
BkF3
BkF
4
CfF3
CfF4
EsF3
EsF4
?EsF6
FmMdNo
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