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Manganese(II) acetate

From Wikipedia, the free encyclopedia
Manganese(II) acetate[1]
Names
IUPAC name
Manganese(II) acetate
Other names
Manganese diacetate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.010.305Edit this at Wikidata
UNII
  • InChI=1S/2C2H4O2.Mn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2 checkY
    Key: UOGMEBQRZBEZQT-UHFFFAOYSA-L checkY
  • CC([O-])=O.CC([O-])=O.[Mn+2]
Properties
Mn(CH3CO2)2 (anhydrous)
Mn(CH3CO2)2·4H2O (tetrahydrate)
Molar mass173.027 g/mol (anhydrous)
245.087 g/mol (tetrahydrate)
Appearancewhite crystals (anhydrous)
light pinkmonoclinic crystals (tetrahydrate)
Density1.74 g/cm3 (anhydrous)
1.59 g/cm3 (tetrahydrate)
Melting point210 °C (410 °F; 483 K) (anhydrous)
80 °C (tetrahydrate)
Solubilitysoluble inwater (about 700g/L at 20°C for tetrahydrate),methanol,acetic acid (anhydrous)
soluble inwater,ethanol (tetrahydrate)
+13,650·10−6 cm3/mol
Hazards
NFPA 704 (fire diamond)
Flash point> 130 °C (266 °F; 403 K) (tetrahydrate)
Lethal dose or concentration (LD, LC):
2940 mg/kg (rat, oral)[2]
Related compounds
Otheranions
Manganese(II) fluoride
Manganese(II) chloride
Manganese(II) bromide
Othercations
Zinc acetate
Mercury(II) acetate
Silver acetate
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound

Manganese(II) acetate arechemical compounds with the formulaMn(CH3CO2)2·(H2O)n where n = 0, 2, 4. These materials are white or pale pink solids. Some of these compounds are used as acatalyst and asfertilizer.[3]

Preparation

[edit]

Manganese(II) acetate can be formed by treating eithermanganese(II,III) oxide ormanganese(II) carbonate with acetic acid:[4]

Mn3O4 + 2 CH3CO2H → Mn(CH3CO2)2 + Mn2O3 + H2O
MnCO3 + 2 CH3CO2H → Mn(CH3CO2)2 + CO2 + H2O

Structure

[edit]

The anhydrous material and dihydrateMn(CH3CO2)2·2H2O arecoordination polymers. The dihydrate has been characterized by X-ray crystallography. Each Mn(II) center is surrounded by six oxygen centers provided byaquo ligands and acetates.

Subunit of the structure of the dihydrate of manganese(II) acetate.[5]

References

[edit]
  1. ^Lide, David R. (1998),Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 3–354,4–68,ISBN 0-8493-0594-2
  2. ^"Manganese compounds (as Mn)".Immediately Dangerous to Life or Health Concentrations (IDLH).National Institute for Occupational Safety and Health (NIOSH).
  3. ^Thomas Scott; Mary Eagleson (1994),Concise Encyclopedia Chemistry, Walter de Gruyter, p. 620,ISBN 3-11-011451-8, retrieved2009-07-20
  4. ^Arno H. Reidies (2002). "Manganese Compounds".Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH.doi:10.1002/14356007.a16_123.ISBN 3527306730.
  5. ^Chih-Yi Cheng; Sue-Lein Wang (1991). "Structure of manganese acetate dihydrate".Acta Crystallographica Section C.47 (8): 1734.doi:10.1107/S0108270191002202.
Manganese(−I)
Manganese(0)
Manganese(I)
Manganese(II)
Manganese(II,III)
Manganese(II,IV)
Manganese(III)
Manganese(IV)
Manganese(V)
Manganese(VI)
Manganese(VII)
Acetyl halides and salts of theacetate ion
Retrieved from "https://en.wikipedia.org/w/index.php?title=Manganese(II)_acetate&oldid=1183997957"
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