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Diiodine oxide

From Wikipedia, the free encyclopedia
(Redirected fromIodine(I) oxide)
This article is about the compound I2O. For the molecule IO, seeIodine monoxide.
Diiodine oxide or Iodo hypoiodite
Names
IUPAC name
Diiodine oxide
Systematic IUPAC name
Iodo hypoiodite[1]
Other names
Iodine hypoiodide, diiodooxidane, diiodine monoxide, hypoiodous anhydride
Identifiers
3D model (JSmol)
  • InChI=1S/I2O/c1-3-2
    Key: VSHDHKDWBUMJIJ-UHFFFAOYSA-N
  • O(I)I
Properties
I2O
Molar mass269.808 g/mol
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Diiodine oxide, also known asiodo hypoiodite, is anoxide of iodine that is equivalent to an acid anhydride ofhypoiodous acid. This substance is unstable and it is very difficult to isolate.[2]

Preparation

[edit]

Diiodine oxide can be prepared by reacting iodine withpotassium iodate (KIO3) in 96%sulfuric acid and then extracting it into chlorinated solvents.[2]

Reactions

[edit]

Diiodine oxide reacts with water to formhypoiodous acid:

I2O + H2O → 2 HIO

References

[edit]
  1. ^"Epoxy-iodide".
  2. ^abFurrow, Stanley D.; Schmitz, Guy E. (2019-09-01)."I2O in solution and volatility".Chemical Physics Letters.730:186–190.Bibcode:2019CPL...730..186F.doi:10.1016/j.cplett.2019.05.052.ISSN 0009-2614.S2CID 191207025.
Iodine(−I)
Iodine(I)
Iodine(II)
Iodine(III)
Iodine(IV)
Iodine(V)
Iodine(VII)
Mixed oxidation states
+1 oxidation state
+2 oxidation state
+3 oxidation state
+4 oxidation state
+5 oxidation state
+6 oxidation state
+7 oxidation state
+8 oxidation state
Related
Oxides are sorted byoxidation state.Category:Oxides
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