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Ice crystal

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Water ice in symmetrical shapes
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A close-up of growing ice crystals displaying typical hexagonal symmetry

Ice crystals are solidice insymmetrical shapes includinghexagonal columns, hexagonal plates, anddendritic crystals.[1] Ice crystals are responsible for variousatmospheric optical displays andcloud formations.[1][2]

Formation

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An example of a hexagonal plate (top) and a hexagonal column (bottom), typical ice crystal shapes.

 At ambient temperature and pressure,water molecules have a V shape. The twohydrogen atoms bond to theoxygen atom at a 105° angle.[3] Ice crystals have a hexagonalcrystal lattice, meaning the water molecules arrange themselves into layeredhexagons upon freezing.[1]

Slower crystal growth from colder and drier atmospheres produces more hexagonal symmetry.[2] Depending on environmentaltemperature andhumidity, ice crystals can develop from the initial hexagonal prism into many symmetric shapes.[4] Possible shapes for ice crystals are columns,needles, plates anddendrites. Mixed patterns are also possible.[1] The symmetric shapes are due todepositionalgrowth, which is when ice forms directly from water vapor in the atmosphere.[5] Small spaces in atmosphericparticles can also collect water, freeze, and form ice crystals.[6][7] This is known asnucleation.[8]Snowflakes form when additional vapor freezes onto an existing ice crystal.[9][10]

Further freezing of water on an ice crystal producessnowflakes.

Trigonal and cubic crystals

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Supercooled water refers to water below itsfreezing point that is still liquid.[11] Ice crystals formed from supercooled water havestacking defects in their layered hexagons. This causes ice crystals to displaytrigonal orcubic symmetry depending on the temperature. Trigonal or cubic crystals form in the upper atmosphere where supercooling occurs.[12][13]

Square crystals

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Water can pass throughlaminated sheets ofgraphene oxide unlike smaller molecules such ashelium. When squeezed between two layers ofgraphene, water forms square ice crystals at room temperature. Researchers believe high pressure and thevan der Waals force, anattractive force present between all molecules, drives the formation. The material is a new crystalline phase of ice.[3][14]

Weather phenomena

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Ahalo created by light reflecting off of ice crystals in cirrus clouds. This specific halo is called a46° halo.

Ice crystals create opticalphenomena likediamond dust andhalos in the sky due to light reflecting off of the crystals in a process calledscattering.[1][2][15]

Cirrus clouds andice fog are made of ice crystals.[1][16] Cirrus clouds are often the sign of an approachingwarm front, where warm and moist air rises and freezes into ice crystals.[17][18] Ice crystals rubbing against each other also produceslightning.[19][20] The crystals normally fall horizontally,[21] butelectric fields can cause them to clump together and fall in other directions.[22][23]

Detection

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Dendritic ice crystals imaged with ascanning electron microscope. Thecolors are computer generated.

Theaerospace industry is working to design a radar that can detect ice crystal environments to discern hazardous flight conditions. Ice crystals can melt when they touch the surface of warm aircraft, and refreeze due to environmental conditions. The accumulation of ice around the engine damages the aircraft.[24][25] Weather forecasting uses differential reflectivityweather radars to identify types ofprecipitation by comparing a droplet's horizontal and vertical lengths.[26] Ice crystals are larger in the horizontal direction[15] and are thus detectable.

See also

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References

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  1. ^abcdef"ice crystal".Glossary of Meteorology.American Meteorological Society. Retrieved2023-03-29.
  2. ^abc"Ice Crystal Halos".its.caltech.edu. Retrieved2023-03-30.
  3. ^abPuiu, Tibi (2015-03-27)."Sandwiching water between graphene makes square ice crystals at room temperature".ZME Science. Retrieved2023-03-30.
  4. ^Visconti, Guido (2001).Fundamentals of physics and chemistry of the atmosphere. Berlin: Springer.ISBN 3-540-67420-9.OCLC 46320998.
  5. ^"Sublimation and deposition - Energy Education".energyeducation.ca. Retrieved2023-04-10.
  6. ^Utah, University of."We've been thinking of how ice forms in cirrus clouds all wrong".phys.org. Retrieved2023-03-30.
  7. ^"How ice crystals form in clouds".Wiley Analytical Science Magazine. Retrieved2023-03-29.
  8. ^UCL (2016-12-09)."Understanding how ice crystals form in clouds".UCL News. Retrieved2023-04-10.
  9. ^"Growth Rates and Habits of Ice Crystals between −20° and −70°C - Google Search".www.google.com. Retrieved2024-03-10.
  10. ^"How do snowflakes form? Get the science behind snow".www.noaa.gov. 19 December 2016. Retrieved2023-03-30.
  11. ^"Supercool Clouds".earthobservatory.nasa.gov. 2014-12-20. Retrieved2023-04-10.
  12. ^Murray, Benjamin J.; Salzmann, Christoph G.; Heymsfield, Andrew J.; Dobbie, Steven; Neely, Ryan R.; Cox, Christopher J. (2015-09-01)."Trigonal Ice Crystals in Earth's Atmosphere".Bulletin of the American Meteorological Society.96 (9):1519–1531.Bibcode:2015BAMS...96.1519M.doi:10.1175/BAMS-D-13-00128.1.ISSN 0003-0007.S2CID 120907603.
  13. ^"Cubic ice (ice Ic) structure".water.lsbu.ac.uk. Retrieved2023-04-10.
  14. ^Algara-Siller, G.; Lehtinen, O.; Wang, F. C.; Nair, R. R.; Kaiser, U.; Wu, H. A.; Geim, A. K.; Grigorieva, I. V. (2015)."Square ice in graphene nanocapillaries".Nature.519 (7544):443–445.arXiv:1412.7498.Bibcode:2015Natur.519..443A.doi:10.1038/nature14295.ISSN 1476-4687.PMID 25810206.S2CID 4462633.
  15. ^abGedzelman, S. D. (2003-01-01),"OPTICS, ATMOSPHERIC | Optical Phenomena", in Holton, James R. (ed.),Encyclopedia of Atmospheric Sciences, Oxford: Academic Press, pp. 1583–1594,doi:10.1016/b0-12-227090-8/00284-0,ISBN 978-0-12-227090-1, retrieved2023-03-30
  16. ^"Ice fog".Glossary of Meteorology. American Meteorological Society. Retrieved2023-03-29.
  17. ^"Cirrus Clouds | Center for Science Education".scied.ucar.edu. Retrieved2023-03-30.
  18. ^"Cirrus clouds".Met Office. Retrieved2023-03-30.
  19. ^Plait, Phil (2016-11-16)."Ice Crystals Above Clouds Dance to the Tune of Electricity".Slate.ISSN 1091-2339. Retrieved2023-03-30.
  20. ^Canada, Environment and Climate Change (2011-04-15)."How lightning works".www.canada.ca. Retrieved2023-03-30.
  21. ^Stillwell, Robert A.; Neely, Ryan R.; Thayer, Jeffrey P.; Walden, Von P.; Shupe, Matthew D.; Miller, Nathaniel B. (2019-11-27)."Radiative Influence of Horizontally Oriented Ice Crystals over Summit, Greenland".Journal of Geophysical Research: Atmospheres.124 (22):12141–12156.Bibcode:2019JGRD..12412141S.doi:10.1029/2018JD028963.ISSN 2169-897X.S2CID 210640681.
  22. ^Libbrecht, Kenneth G."Electric Snow Crystal Growth".www.its.caltech.edu. Retrieved2023-03-30.
  23. ^Latham, J.; Saunders, C. P. R. (1964)."Aggregation of Ice Crystals in Strong Electric Fields".Nature.204 (4965):1293–1294.Bibcode:1964Natur.204.1293L.doi:10.1038/2041293a0.ISSN 1476-4687.S2CID 8747928.
  24. ^Heidman, Kelly (2015-08-11)."Flight Campaign Studies Radar Detection of Ice Crystal Icing".NASA. Retrieved2023-03-30.
  25. ^Lukas, Jan; Badin, Pavel (2019-06-10)."High Altitude Ice Crystal Detection with Aircraft X-band Weather Radar".SAE International Journal of Advances and Current Practices in Mobility.2 (1):256–264.doi:10.4271/2019-01-2026.ISSN 2641-9637.S2CID 182542723.
  26. ^US Department of Commerce, NOAA."Dual-Pol Products".www.weather.gov. Retrieved2023-03-30.

External links

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