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Holmium phosphide

From Wikipedia, the free encyclopedia
Holmium phosphide
Names
Other names
Phosphanylidyneholmium, holmium monophosphide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.031.566Edit this at Wikidata
EC Number
  • 234-737-6
  • InChI=1S/Ho.P
    Key: MPCFEQUPROVEQK-UHFFFAOYSA-N
  • P#[Ho]
Properties
HoP
Molar mass195.90
AppearanceDark crystals
Density7.90 g/cm3[1]
Insoluble
Related compounds
Otheranions
Holmium nitride
Holmium arsenide
Holmium antimonide
Holmium bismuthide
Othercations
Dysprosium phosphide
Erbium phosphide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Holmium phosphide is a binaryinorganic compound ofholmium andphosphorus with the chemical formula HoP.[2][3][4] The compound forms dark crystals, is stable in air, and does not dissolve in water.[1]

Synthesis

[edit]

Heating powdered holmium andred phosphorus in an inert atmosphere or vacuum:[5]

4Ho + P4 → 4HoP

Properties

[edit]

HoP belongs to the large class ofNaCl-structured rare earth monopnictides.[6]

Ferromagnetic at low temperatures.[7][8]

HoP actively reacts withnitric acid.[citation needed]

Uses

[edit]

The compound is asemiconductor used in high power, high frequency applications and inlaser diodes.[4]

References

[edit]
  1. ^ab"mp-1001843: HoP (cubic, Pm-3m, 221)".Materials Project. Retrieved25 May 2024.
  2. ^Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Cumulative Supplement to the Initial Inventory: User Guide and Indices.United States Environmental Protection Agency. 1980. p. 170. Retrieved23 December 2021.
  3. ^Fischer, P.; Furrer, A.; Kaldis, E.; Kim, D.; Kjems, J. K.; Levy, P. M. (1 January 1985)."Phase diagrams and magnetic excitations in holmium phosphide".Physical Review B.31 (1):456–469.Bibcode:1985PhRvB..31..456F.doi:10.1103/PhysRevB.31.456.PMID 9935448. Retrieved23 December 2021.
  4. ^ab"Holmium Phosphide".American Elements. Retrieved23 December 2021.
  5. ^Sicius, Hermann (13 November 2024).Handbook of the Chemical Elements.Springer Nature. p. 963.ISBN 978-3-662-68921-9. Retrieved23 December 2024.
  6. ^Furrer, A. (6 December 2012).Crystal Field Effects in Metals and Alloys.Springer Science & Business Media. p. 24.ISBN 978-1-4615-8801-6. Retrieved23 December 2021.
  7. ^Fysikafdelingen, Forsøgsanlæg Risø (1983).Annual progress report. Risø National Laboratory. p. 11.ISBN 978-87-550-0960-8. Retrieved23 December 2021.
  8. ^Donnay, Joseph Désiré Hubert (1978).Crystal Data: Inorganic compounds 1967-1969.National Bureau of Standards. p. 71. Retrieved23 December 2021.
Phosphides
Other compounds
Binary phosphides
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
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