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Cobalt germanide

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(December 2024)
Cobalt germanide
Structures of left-handed and right-handed cubic CoGe crystals (3 presentations, with different numbers of atoms per unit cell; orange atoms are Ge)
Names
IUPAC name
Cobalt germanide
Identifiers
3D model (JSmol)
  • InChI=1S/Co.Ge
    Key: DDHRUTNUHBNAHW-UHFFFAOYSA-N
  • [Co].[Ge]
Properties
CoGe
Molar mass131.56 g/mol
1.3×10−6 emu/g[1]
Structure
Monoclinic[1]
C2/m (No. 12),mS16
a = 1.165 nm,b = 0.3807 nm,c = 0.4945 nm
α = 90°, β = 101.1°, γ = 90°
8
Hazards
Flash pointNon-flammable
Related compounds
Otheranions
Cobalt silicide
Othercations
Iron germanide
Manganese germanide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N (what is checkY☒N ?)
Chemical compound

Cobalt germanide (CoGe) is anintermetallic compound, agermanide ofcobalt.

Cubic CoGe crystals (space group P213,cP8,a = 0.4631 nm) can be produced by processing a mixture of Co and Ge powders at a pressure of 4 GPa and a temperature of 800–1000 °C for 1 to 3 hours. They have noinversion center, and are therefore helical, with right-hand and left-handedchiralities. The cubic CoGe ismetastable, and converts into amonoclinic phase upon subsequent heating to 600 °C at ambient pressure.[1]

Cubic CoGe is anantiferromagnet with a transition temperatureTc of 132 K.[1]

References

[edit]
  1. ^abcdTakizawa, H.; Sato, T.; Endo, T.; Shimada, M. (1988). "High-pressure synthesis and electrical and magnetic properties of MnGe and CoGe with the cubic B20 structure".Journal of Solid State Chemistry.73 (1):40–46.Bibcode:1988JSSCh..73...40T.doi:10.1016/0022-4596(88)90051-5.
Cobalt(I)
Cobalt(II)
Cobalt(0,III)
Cobalt(II,III)
Cobalt(III)
Cobalt(III,IV)
Cobalt(IV)
Cobalt(V)
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