![]() Nonahydrate | |
![]() Chemical structure of [Cr(H2O)6](NO3)3 | |
Names | |
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IUPAC name Chromium(III) nitrate | |
Other names Nitric acid, chromium(3+) salt | |
Identifiers | |
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3D model (JSmol) | |
ChemSpider |
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ECHA InfoCard | 100.033.550![]() |
RTECS number |
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UNII |
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UN number | 2720 |
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Properties | |
Cr(NO3)3 (anhydrous) [Cr(H2O)6](NO3)3•3H2O (nonahydrate) | |
Molar mass | 238.011 g/mol (anhydrous) 400.21 g/mol (nonahydrate) |
Appearance | Blue-violet crystals (anhydrous) Purple crystals (nonahydrate) |
Density | 1.85 g/cm3 (nonahydrate) |
Melting point | 60.06 °C (140.11 °F; 333.21 K) nonahydrate |
Boiling point | > 100 °C (212 °F; 373 K) (decomposes) |
81 g/100 mL (20 °C) | |
Hazards | |
NFPA 704 (fire diamond) | |
Flash point | Non-flammable |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) | 3250 mg/kg (rat, oral, nonahydrate) 110 mg/kg (mouse, oral)[1] |
Safety data sheet (SDS) | Oxford MSDS |
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa). |
Chromium(III) nitrate describes severalinorganic compounds consisting of chromium, nitrate and varying amounts of water. Most common is the dark violet hygroscopic solid. Ananhydrous green form is also known. Chromium(III) nitrate compounds are of a limited commercial importance, finding some applications in the dyeing industry.[2] It is common in academic laboratories for the synthesis of chromiumcoordination complexes.
The relatively complicatedformula - [Cr(H2O)6](NO3)3•3H2O - betray a simple structure of this material. The chromium centers are bound to sixaquo ligands, and the remaining volume of the solid is occupied by three nitrate anions and threemolecules of water of crystallization.[3]
Theanhydrous salt forms green crystals and is very soluble in water (in contrast to anhydrouschromium(III) chloride which dissolves very slowly except under special conditions). At 100 °C it decomposes. The red-violet hydrate is highly soluble in water. Chromium nitrate is used in the production ofalkali metal-freecatalysts and inpickling.
Chromium nitrate can be prepared by dissolvingchromium oxide innitric acid.[2]