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Chromium(III) nitrate

From Wikipedia, the free encyclopedia
Chemical compound
Chromium(III) nitrate
Nonahydrate
Chemical structure of [Cr(H2O)6](NO3)3
Names
IUPAC name
Chromium(III) nitrate
Other names
Nitric acid, chromium(3+) salt
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.033.550Edit this at Wikidata
RTECS number
  • GB6300000
UNII
UN number2720
  • InChI=1S/Cr.3NO3/c;3*2-1(3)4/q+2;3*-1 checkY
    Key: BXWGVGRRIQRLLZ-UHFFFAOYSA-N checkY
  • InChI=1/Cr.3NO3/c;3*2-1(3)4/q+2;3*-1
    Key: BXWGVGRRIQRLLZ-UHFFFAOYAO
  • [Cr+3].O=N([O-])=O.[O-]N(=O)=O.[O-]N(=O)=O
Properties
Cr(NO3)3 (anhydrous)
[Cr(H2O)6](NO3)3•3H2O (nonahydrate)
Molar mass238.011 g/mol (anhydrous)
400.21 g/mol (nonahydrate)
AppearanceBlue-violet crystals (anhydrous)
Purple crystals (nonahydrate)
Density1.85 g/cm3 (nonahydrate)
Melting point60.06 °C (140.11 °F; 333.21 K) nonahydrate
Boiling point> 100 °C (212 °F; 373 K) (decomposes)
81 g/100 mL (20 °C)
Hazards
NFPA 704 (fire diamond)
Flash pointNon-flammable
Lethal dose or concentration (LD, LC):
3250 mg/kg (rat, oral, nonahydrate)
110 mg/kg (mouse, oral)[1]
Safety data sheet (SDS)Oxford MSDS
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Chemical compound

Chromium(III) nitrate describes severalinorganic compounds consisting of chromium, nitrate and varying amounts of water. Most common is the dark violet hygroscopic solid. Ananhydrous green form is also known. Chromium(III) nitrate compounds are of a limited commercial importance, finding some applications in the dyeing industry.[2] It is common in academic laboratories for the synthesis of chromiumcoordination complexes.

Structure

[edit]

The relatively complicatedformula - [Cr(H2O)6](NO3)33H2O - betray a simple structure of this material. The chromium centers are bound to sixaquo ligands, and the remaining volume of the solid is occupied by three nitrate anions and threemolecules of water of crystallization.[3]

Properties and preparation

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Theanhydrous salt forms green crystals and is very soluble in water (in contrast to anhydrouschromium(III) chloride which dissolves very slowly except under special conditions). At 100 °C it decomposes. The red-violet hydrate is highly soluble in water. Chromium nitrate is used in the production ofalkali metal-freecatalysts and inpickling.

Chromium nitrate can be prepared by dissolvingchromium oxide innitric acid.[2]

References

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  1. ^"Chromium(III) compounds [as Cr(III)]".Immediately Dangerous to Life or Health Concentrations (IDLH).National Institute for Occupational Safety and Health (NIOSH).
  2. ^abAnger, Gerd; Halstenberg, Jost; Hochgeschwender, Klaus; Scherhag, Christoph; Korallus, Ulrich; Knopf, Herbert; Schmidt, Peter; Ohlinger, Manfred (2000). "Chromium Compounds".Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH.doi:10.1002/14356007.a07_067.ISBN 3527306730.
  3. ^Lazar, D.; Ribár, B.; Divjaković, V.; Mészáros, Cs. (1991). "Structure of Hexaaquachromium(III) Nitrate Trihydrate".Acta Crystallographica Section C Crystal Structure Communications.47 (5):1060–1062.doi:10.1107/S0108270190012628.
Chromium(0)
Organochromium(0) compounds
Chromium(I)
Organochromium(I) compounds
Chromium(II)
Organochromium(II) compounds
Chromium(II, III)
Chromium(III)
Chromium(IV)
Chromium(V)
Chromium(VI)
Polyatomic ion
Salts and covalent derivatives of thenitrate ion
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