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Cerium phosphide

From Wikipedia, the free encyclopedia
Cerium phosphide
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 246-783-4
  • InChI=1S/Ce.P
    Key: SMKQIOCKGHFKQZ-UHFFFAOYSA-N
  • [Ce+3].[P-3]
Properties
CeP
Molar mass171.090 g·mol−1
Appearancegrey crystals[1]
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Cerium phosphide is aninorganic compound with the chemical formula CeP. It is one of thephosphides ofcerium. It can be obtained by reactingcerium dioxide andphosphine at 1300 °C in the presence of hydrogen,[2] or by reactingsodium phosphide andcerium chloride at 700~800 °C.[1] It will be oxidized to monoclinic CePO4 in air above 900 °C.[2] It reacts withiodine in aquartz ampoule to obtain CeSiP3.[3]

References

[edit]
  1. ^abRowley, Adrian T.; Parkin, Ivan P. (1993). "Convenient synthesis of lanthanide and mixed lanthanide phosphides by solid-state routes involving sodium phosphide".Journal of Materials Chemistry.3 (7). Royal Society of Chemistry (RSC): 689.doi:10.1039/jm9930300689.ISSN 0959-9428.
  2. ^abVasil'eva, I. G.; Mironov, K. E.; Mironov, Yu. I. Properties of cerium monophosphide(in Russian).Redkozemel. Metal. Ikh Soedin., Mater. Vses. Simp., 1970: 160-165.CODEN 26HIAV.
  3. ^Mironov, K. E.; Abdullin, R. V. Formation and chemical transfer of cerium silicon phosphide (CeSiP3)(in Russian).Zhurnal Neorganicheskoi Khimii, 1980. 25 (8): 2062-2066.

External reading

[edit]
Cerium(II)
Cerium(III)
Organocerium(III)
Cerium(III,IV)
Cerium(IV)
Binary phosphides
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
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