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Calcium polonide

From Wikipedia, the free encyclopedia
Calcium polonide
Names
Preferred IUPAC name
Calcium polonide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Ca.Po/q+2;-2
    Key: NWHIVWOERKOURT-UHFFFAOYSA-N
  • [Ca+2].[Po-2]
Properties
CaPo
Molar mass249 g·mol−1
Density6.0 g/cm3
Structure[1]
Rock Salt (cubic)
Fm3m (No. 225)
a = 0.6514 nm
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Calcium polonide is anintermetallic compound with thechemical formulaCaPo. It is made up ofcalcium andpolonium. Rather than being found in nature, the compound is entirelysynthetic, and difficult to study, due to polonium's high vapor pressure, radioactivity, and easy oxidation in air.

Structure

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At atmospheric pressure, it crystalizes in the cubicrock salt crystal structure.[1] At a high pressure of around 16.7 GPa, the structure is predicted to transform to thecaesium chloride-type crystal structure.[2]

Electronic properties

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Based on theoretical calculations, calcium polonide is predicted to be asemiconductor.[3]

See also

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References

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  1. ^abWitteman, W. G.; Giorgi, A. L.; Vier, D. T. (1960). "The Preparation and Identification of Some Intermetallic Compounds of Polonium".The Journal of Physical Chemistry.64 (4). American Chemical Society (ACS):434–440.doi:10.1021/j100833a014.ISSN 0022-3654.
  2. ^Shi, Liwei; Wu, Ling; Duan, Yifeng; Hao, Lanzhong; Hu, Jing; Yang, Xianqing; Tang, Gang (2012). "Band structure, phase transition, phonon and elastic instabilities in calcium polonide under pressure: A first-principles study".Solid State Communications.152 (22). Elsevier BV:2058–2062.Bibcode:2012SSCom.152.2058S.doi:10.1016/j.ssc.2012.08.028.ISSN 0038-1098.
  3. ^Bhardwaj, Purvee; Singh, Sadhna (2015-06-09). "Phase transition and bulk properties of some polonide compounds: a comparative study".Phase Transitions.88 (9). Informa UK Limited:859–876.Bibcode:2015PhaTr..88..859B.doi:10.1080/01411594.2015.1020312.ISSN 0141-1594.S2CID 93331676.
Polonium(−II)
Polonium(II)
Polonium(IV)
Polonium(VI)
Hydrogen & halogens
Chalcogens
Pnictogens
Group 13 & 14
Trans metals
Organics
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