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Caesium cadmium chloride

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Caesium cadmium chloride
Names
IUPAC name Caesium cadmium chloride
Other names Caesium trichlorocadmate Caesium chlorocadmate Caesium trichlorocadmate(II)
Identifiers
CAS Number	13845-08-4
3D model (JSmol)	Interactive image
PubChem CID	159356594
InChI InChI=1S/Cd.3ClH.Cs/h;3*1H;/q+2;;;;+1/p-3 Key: LHZPOBUPLFKLBV-UHFFFAOYSA-K
SMILES [Cd+2]([Cl-])([Cl-])[Cl-].[Cs+] [Cs+].[Cl-][Cd+2]([Cl-])[Cl-]
Properties
Chemical formula	Cs Cd Cl₃
Molar mass	351.675 g/mol
Appearance	White or colourless solid
Structure
Crystal structure	hexagonal
Space group	P6₃/mmc
Lattice constant	a = 7.403,c = 18.406
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa). Y verify (what is ^YN ?) Infobox references

Chemical compound

Caesium cadmium chloride (CsCdCl₃) is a synthetic crystalline material. It belongs to the AMX₃ group (where A=alkali metal, M=bivalent metal, X=halogen ions). It crystallizes in ahexagonal space groupP6₃/mmc with unit cell lengthsa = 7.403Å andc = 18.406 Å, with one cadmium ion havingD_3d symmetry and the other havingC_3v symmetry.^[1]

It is formed when anaqueous solution ofhydrochloric acid containing anequimolar solution ofcaesium chloride andcadmium chloride.^[2]

References

[edit]

^Chang, Jin Rong.; McPherson, Gary L.; Atwood, Jerry L. (December 1975). "Electron paramagnetic resonance spectra of vanadium(II) and nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride".Inorganic Chemistry.14 (12):3079–3085.doi:10.1021/ic50154a044.
^Electron paramagnetic spectrum of manganese(II)-manganese(II)pairs in single crystals of cesium cadmium chloride.Electronic structure of the nonachlorodimanganate(5-) dimerGary L. McPherson, and Jin Rong Chang,Inorg. Chem., 1976, 15 (5), 1018-1022.doi:10.1021/ic50159a006

v t e Cadmium compounds
Cadmium(I)	Cd₂(AlCl₄)₂
Cadmium(II)	Cd(BF₄)₂ CdF₂ CdCl₂ CdBr₂ CdI₂ Cd(CN)₂ CdH₂ CdO CdS CdSe CdTe Cd(OH)₂ Cd₃N₂ Cd(NO₃)₂ CdSO₄ CdSeO₄ CdCrO₄ CdWO₄ CdTeO₃ Cd(C₃H₅O₃)₂ Cd₃As₂ Cd₃P₂ CsCdCl₃ CsCdBr₃ Cd(CH₃CO₂)₂ Cd(O₂CC₁₇H₃₅)₂

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