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TheComposition C family is a family of related US-specifiedplastic explosives consisting primarily ofRDX. All can be moulded by hand for use in demolition work and packed by hand intoshaped-charge devices. Variants have different proportions and plasticisers and include Composition C-1, Composition C-2, Composition C-3, andComposition C-4.[1]
The termComposition is used for any explosive material compounded from several ingredients. In particular, in the 1940s the format "Composition <letter>" was used for various compositions of the (relatively) novel explosive RDX, such asComposition B and other variants.
The original material was developed by the British duringWorld War II, and was used in theGammon bomb. It was standardised as Composition C when introduced to US service. This material consisted of 88.3% RDX and a mineral oil-based plasticiser andphlegmatiser. It suffered from a relatively limited range of serviceable temperatures, and was replaced by Composition C-2 around 1943, which would later be redeveloped around 1944 as Composition C-3. Research on a replacement for C-3 was begun prior to 1950, but the new generation of Composition C (C-4) did not begin pilot production until 1956.
Composition C-1 contained a slightly smaller proportion of RDX, but used an explosive plasticiser, which containedtetryl,nitrocellulose and a mixture of nitroaromatics produced during the manufacture of TNT (containingtrinitrotoluene,dinitrotoluene, andmononitrotoluene), and a trace of solvent.
Composition C-3 was very similar to Composition C-1, but removed the solvent and varied the exact proportions of plasticisers to improve high temperature storage. It is a yellow, putty-like material. It remained a service item through theKorean War, but had marginal plasticity at the very low temperatures encountered in Korean winters, and was significantly toxic, including by vapour and skin absorption.[2] While Composition C-3 had a much wider serviceable temperature range than Composition C-1, it could not be stored at elevated temperatures. Consequently, it would eventually be replaced by Composition C-4. Thevelocity of detonation is about 7600 m/s (25,000 feet per second).
Composition C-3 consists of 77%–85% cyclonite (RDX) and 15%–23% gel made out of liquid nitro compounds (e.g. liquidDNT and small amount ofNT) and nitrocellulose or butyl phthalate and nitrocellulose.[3]
One of the first reported and tested compositions of C-3 was very similar to earlier Composition C-2 and contained 77%RDX, 3%tetryl, 4%TNT, 1%NC, 5%NT, and 10%DNT.[4] The last two compounds (they are very poor explosives) are oily liquids and plasticise the mixture. The most important later innovation of C-3 introduced the non-explosiveplasticiser butyl phthalate instead of this mixture of nitro compounds. This reduced the toxicity while increasing the concentration ofRDX and improving safety of use and storage. It also opened the way to begin study of new non-explosive low-toxicity plasticisers (esters of dicarboxylic acid) and binder (branchedpolymers).
Since 1960 the mixture ofC-4 has contained:
It is less volatile than C-3 and has less tendency to harden at low temperature. It has a density 1.48–1.60 g/ml, does not become hard even at −55 °C (−67 °F), and does not exude at +77 °C (171 °F). C-4 has a detonation velocity of 8092 m/s (26550 ft/s) at high density and velocity of 7550 m/s (24770 ft/s) at low density 1.48 g/ml. It is so successful that it remains inarmy service up to the current time without any significant changes.
The detainee was trained to use theKalashnikov rifle,rocket propelled grenades,hand grenades,land mines, Composition-3 (C-3) and Composition-4 (C-4) explosives.
Composition-3 (C-3) and Composition-4 (C-4) explosives, Semtex.
