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Bromodifluoromethane

From Wikipedia, the free encyclopedia
Bromodifluoromethane
Names
Preferred IUPAC name
Bromo(difluoro)methane
Other names
  • Bromodifluoromethane
  • Difluorobromomethane
  • Halon 1201
  • HBFC-22B1
  • FC-22B1
  • R-22B1
  • FM-100
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.014.681Edit this at Wikidata
EC Number
  • 216-149-1
UNII
  • InChI=1S/CHBrF2/c2-1(3)4/h1H checkY
    Key: GRCDJFHYVYUNHM-UHFFFAOYSA-N checkY
  • InChI=1/CHBrF2/c2-1(3)4/h1H
  • C(F)(F)Br
  • BrC(F)F
Properties
CHBrF2
Molar mass130.92 g/mol
AppearanceGas
Density1.55 g/cm3 at 16 °C
Melting point−145 °C (−229 °F; 128 K)
Boiling point−14.6 °C (5.7 °F; 258.5 K)
Insoluble
SolubilityAlcohol,diethyl ether
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Chemical compound

Bromodifluoromethane orHalon 1201 orFC-22B1 is agaseoustrihalomethane or a hydrobromofluorocarbon.

Synthesis

[edit]

It can be prepared through the reaction ofhydrogen anddibromodifluoromethane at temperature in range 400–600 °C.[1]

Critical point data:Tc = 138.83 °C (411.98 K); pc = 5.2 MPa (51.32 bar);Vc = 0.275 dm3·mol−1.

Applications

[edit]

Bromodifluoromethane was used as arefrigerant and infire extinguishers. It is a class Iozone depleting substance withozone depletion potential ODP = 0.74, and a greenhouse gas withglobal warming potential over 100 years of 398, which is nonetheless much smaller than other fluorinated gases due to its relatively shortatmospheric lifetime of 5.2 years.[2] It was banned by theMontreal Protocol in 1996.

References

[edit]
  1. ^"Method for the production of bromodifluoromethane". Archived fromthe original on 2007-10-14. Retrieved2007-05-24.
  2. ^Hodnebrog Ø, Aamaas B, Fuglestvedt JS, Marston G, Myhre G, Nielsen CJ, Sandstad M, Shine KP, Wallington TJ (September 2020)."Updated Global Warming Potentials and Radiative Efficiencies of Halocarbons and Other Weak Atmospheric Absorbers".Reviews of Geophysics.58 (3): e2019RG000691.Bibcode:2020RvGeo..5800691H.doi:10.1029/2019RG000691.PMC 7518032.PMID 33015672.

External links

[edit]
Unsubstituted
Monosubstituted
Disubstituted
Trisubstituted
Tetrasubstituted
*Chiral compound.
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