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Barium chloride fluoride

From Wikipedia, the free encyclopedia
Barium chloride fluoride
Names
Other names
Barium chlorofluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.033.874Edit this at Wikidata
EC Number
  • 237-277-4
  • InChI=1S/Ba.ClH.FH/h;2*1H/q+2;;/p-2
    Key: RBRFDGCVTRKUEW-UHFFFAOYSA-L
  • [F-].[Cl-].[Ba+2]
Properties
BaClF
Molar mass191.78 g·mol−1
Appearancewhite crystals
Densityg/cm3
Poorly soluble
Structure
Tetragonal
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Barium chloride fluoride is aninorganic chemical compound ofbarium,chlorine, andfluorine.[1] Its chemical formula isBaClF.[2][3] The compound naturally occurs aszhangpeishanite mineral of thematlockite group.[4] One of the deposits where the mineral is mined isBayan Obo in China.[5]

Synthesis

[edit]

Barium fluoride can be prepared by precipitatingbarium chloride andammonium fluoride in a solution.

Physical properties

[edit]

Barium chloride fluoride forms white crystals.[6] The crystal structure of BaClF is a tetragonal distortion of that of fluoride typeBaF
2
.[7]

The compound is poorly soluble in water.[8]

References

[edit]
  1. ^Hagemann, H.; D’Anna, V.; Lawson Daku, M.; Kubel, F. (7 March 2012)."Crystal Chemistry in the Barium Fluoride Chloride System".Crystal Growth & Design.12 (3):1124–1131.doi:10.1021/cg201588s.ISSN 1528-7483. Retrieved26 March 2023.
  2. ^"System of Registries | US EPA".United States Environmental Protection Agency. Retrieved26 March 2023.
  3. ^"CAS 13718-55-3 Barium chloride fluoride - Alfa Chemistry". Alfa Chemistry. Retrieved26 March 2023.
  4. ^英彦, 島崎; 律郎, 宮脇; 一己, 横山; 聰, 松原; 主明, 楊 (2007)."中国内モンゴル白雲鄂博産の新鉱物,張培善石".日本鉱物科学会年会講演要旨集.2007: 198.doi:10.14824/jakoka.2007.0.198.0. Retrieved27 March 2023.
  5. ^"Zhangpeishanite". mindat.org. Retrieved27 March 2023.
  6. ^Lide, David R. (19 June 2003).1998 Freshman Achievement Award.CRC Press. pp. 4–49.ISBN 978-0-8493-0594-8. Retrieved26 March 2023.
  7. ^Marcus, Philippe; Maurice, Vincent (25 May 2006).Passivation of Metals and Semiconductors, and Properties of Thin Oxide Layers: A Selection of Papers from the 9th International Symposium, Paris, France, 27 June - 1 July 2005.Elsevier. p. 150.ISBN 978-0-08-046152-6. Retrieved26 March 2023.
  8. ^Comey, Arthur Messinger (1896).A Dictionary of chemical solubilities. Macmillan and Company. p. 47. Retrieved26 March 2023.
Salts and covalent derivatives of thefluoride ion
HF?HeF2
LiFBeF2BF
BF3
B2F4
+BO3
CF4
CxFy
+CO3
NF3
FN3
N2F2
NF
N2F4
NF2
?NF5
+N
+NO3
OF2
O2F2
OF
O3F2
O4F2
?OF4
F2Ne
NaFMgF2AlF
AlF3
SiF4P2F4
PF3
PF5
+PO4
S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4
ClF
ClF3
ClF5
?ArF2
?ArF4
KFCaF
CaF2
ScF3TiF2
TiF3
TiF4
VF2
VF3
VF4
VF5
CrF2
CrF3
CrF4
CrF5
?CrF6
MnF2
MnF3
MnF4
?MnF5
FeF2
FeF3
FeF4
CoF2
CoF3
CoF4
NiF2
NiF3
NiF4
CuF
CuF2
?CuF3
ZnF2GaF2
GaF3
GeF2
GeF4
AsF3
AsF5
Se2F2
SeF4
SeF6
+SeO3
BrF
BrF3
BrF5
KrF2
?KrF4
?KrF6
RbFSrF
SrF2
YF3ZrF2
ZrF3
ZrF4
NbF4
NbF5
MoF4
MoF5
MoF6
TcF4
TcF
5

TcF6
RuF3
RuF
4

RuF5
RuF6
RhF3
RhF4
RhF5
RhF6
PdF2
Pd[PdF6]
PdF4
?PdF6
Ag2F
AgF
AgF2
AgF3
CdF2InF
InF3
SnF2
SnF4
SbF3
SbF5
TeF4
?Te2F10
TeF6
+TeO3
IF
IF3
IF5
IF7
+IO3
XeF2
XeF4
XeF6
?XeF8
CsFBaF2 LuF3HfF4TaF5WF4
WF5
WF6
ReF4
ReF5
ReF6
ReF7
OsF4
OsF5
OsF6
?OsF
7

?OsF
8
IrF2
IrF3
IrF4
IrF5
IrF6
PtF2
Pt[PtF6]
PtF4
PtF5
PtF6
AuF
AuF3
Au2F10
?AuF6
AuF5•F2
Hg2F2
HgF2
?HgF4
TlF
TlF3
PbF2
PbF4
BiF3
BiF5
?PoF2
PoF4
PoF6
AtF
?AtF3
?AtF5
RnF2
?RnF
4

?RnF
6
FrFRaF2 LrF3RfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
LaF3CeF3
CeF4
PrF3
PrF4
NdF2
NdF3
NdF4
PmF3SmF
SmF2
SmF3
EuF2
EuF3
GdF3TbF3
TbF4
DyF2
DyF3
DyF4
HoF3ErF3TmF2
TmF3
YbF2
YbF3
AcF3ThF3
ThF4
PaF4
PaF5
UF3
UF4
UF5
UF6
NpF3
NpF4
NpF5
NpF6
PuF3
PuF4
PuF5
PuF6
AmF2
AmF3
AmF4
?AmF6
CmF3
CmF4
 ?CmF6
BkF3
BkF
4
CfF3
CfF4
EsF3
EsF4
?EsF6
FmMdNo
PF6,AsF6,SbF6 compounds
AlF2−5,AlF3−6 compounds
chlorides, bromides, iodides
and pseudohalogenides
SiF2−6,GeF2−6 compounds
Oxyfluorides
Organofluorides
with transition metal,
lanthanide, actinide, ammonium
nitric acids
bifluorides
thionyl, phosphoryl,
and iodosyl
Chlorides andacids
Chlorine fluorides
Chlorine oxides
Chlorineoxyfluorides
Chlorine(I) derivatives


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