Movatterモバイル変換


[0]ホーム

URL:


Jump to content
WikipediaThe Free Encyclopedia
Search

Ammonium cyanate

From Wikipedia, the free encyclopedia
Ionic chemical compound with formula [NH4]+ [OCN]-
Ammonium cyanate
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/CHNO.H3N/c2-1-3;/h3H;1H3
    Key: QYTOONVFPBUIJG-UHFFFAOYSA-N
  • C(#N)[O-].[NH4+]
Properties
[NH4][OCN]
Molar mass60.056 g·mol−1
AppearanceColorless crystals
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Ammoniumcyanate is aninorganic compound with the formula[NH4]+[OCN]. It is a colorless, solidsalt.

Structure and reactions

[edit]

The structure of this salt was verified byX-ray crystallography. The respective C–O and C–N distances are 1.174(8) and 1.192(7) Å, consistent with theO=C=N description.Ammoniumcation[NH4]+ formshydrogen bonds with cyanateanionO=C=N, but to N, not to O.[1]

The compound is notable as the precursor in theWöhler synthesis ofurea, anorganic compound, from inorganic reactants.[2] This contributed to the discarding of theVital force theory, suggested earlier byBerzelius.

NH+4 + OCN → (NH2)2CO[3]

References

[edit]
  1. ^MacLean, Elizabeth J.; Harris, Kenneth D. M.; Kariuki, Benson M.; Kitchin, Simon J.; Tykwinski, Rik R.; Swainson, Ian P.;Dunitz; Jack D. (2003). "Ammonium cyanate shows N-H···N hydrogen bonding, not N-H···O".Journal of the American Chemical Society.125 (47):14449–14451.doi:10.1021/ja021156x.PMID 14624593.
  2. ^Friedrich Wöhler (1828)."Ueber künstliche Bildung des Harnstoffs".Annalen der Physik und Chemie.88 (2):253–256.Bibcode:1828AnP....88..253W.doi:10.1002/andp.18280880206.
  3. ^Shorter, J. (1978). "The conversion of ammonium cyanate into urea. A saga on Reaction mechanisms".Chemical Society Reviews.7:1–14.doi:10.1039/CS9780700001.
Ammonium salts
Inorganic salts
monatomic anions
oxyanions
other anions
Organic salts
Salts and covalent derivatives of thecyanate ion
HNCOHe
LiOCNBeBCNH4OCNOCN
-NCO
O(CN)2
FNe
NaOCNMg(OCN)2AlSi(OCN)4PSClAr
KOCNCa(OCN)2ScTiVCrMnFeCo(OCN)2NiCuOCNZnGaGeAsSeBrKr
RbOCNSr(OCN)2YZrNbMoTcRuRhPdAgOCNCdInSnSbTeIXe
CsOCNBa(OCN)2*LuHfTaWReOsIrPtAuHgTlOCNPb(OCN)2BiPoAtRn
FrRa**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*LaCePrNdPmSmEu(OCN)2GdTbDyHoErTmYb
**AcThPaUNpPuAmCmBkCfEsFmMdNo


Stub icon

Thisinorganiccompound–related article is astub. You can help Wikipedia byexpanding it.

Retrieved from "https://en.wikipedia.org/w/index.php?title=Ammonium_cyanate&oldid=1280637309"
Categories:
Hidden categories:

[8]ページ先頭

©2009-2025 Movatter.jp