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Actinium(III) phosphate

From Wikipedia, the free encyclopedia
Actinium(III) phosphate[1]
Names
Other names
Actinium monophosphate
Identifiers
3D model (JSmol)
  • InChI=1S/Ac.H3O4P/c;1-5(2,3)4/h;(H3,1,2,3,4)/q+3;/p-3
    Key: PVLPTTWSKILMQQ-UHFFFAOYSA-K
  • [O-]P(=O)([O-])[O-].[Ac+3]
Properties
AcPO4
Molar mass321.9714 g/mol
AppearanceWhite solid
Density5.48 g/cm3
Structure
hexagonal[2]
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Actinium(III) phosphate is a white-colored chemical compound of the radioactive elementactinium. This compound was created by reactingactinium(III) chloride withmonosodium phosphate in aqueous hydrochloric acid. This resulted in the hemihydrate AcPO4·1/2H2O, whose structure was confirmed by x-ray diffraction to match that of lanthanum phosphate. To become anhydrous, it was heated to 700 °C, which resulted in a solid that was black (presumably due to the presence of impurities), and whose specific X-ray structure did not match that of other known correspond to otheractinide phosphates.[1]

References

[edit]
  1. ^abthe University of Michigan (1948).The Preparation of Actinium Compounds. U.S. Atomic Energy Commission, Technical Information Division. p. 4. Retrieved16 April 2021.
  2. ^Zachariasen, W. H. (1948)."Crystal chemical studies of the 5f-series of elements. I. New structure types".Acta Crystallographica.1 (5):265–268.Bibcode:1948AcCry...1..265Z.doi:10.1107/S0365110X48000703.
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