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Tin

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Tin, 00Sn
Tin
Allotropessilvery-white, β (beta);gray, α (alpha)
Appearancesilvery-white (beta, β) or gray (alpha, α)
Standard atomic weightAr°(Sn)
118.710(7)[1]
Tin in theperiodic table
HydrogenHelium
LithiumBerylliumBoronCarbonNitrogenOxygenFluorineNeon
SodiumMagnesiumAluminiumSiliconPhosphorusSulfurChlorineArgon
PotassiumCalciumScandiumTitaniumVanadiumChromiumManganeseIronCobaltNickelCopperZincGalliumGermaniumArsenicSeleniumBromineKrypton
RubidiumStrontiumYttriumZirconiumNiobiumMolybdenumTechnetiumRutheniumRhodiumPalladiumSilverCadmiumIndiumTinAntimonyTelluriumIodineXenon
CaesiumBariumLanthanumCeriumPraseodymiumNeodymiumPromethiumSamariumEuropiumGadoliniumTerbiumDysprosiumHolmiumErbiumThuliumYtterbiumLutetiumHafniumTantalumTungstenRheniumOsmiumIridiumPlatinumGoldMercury (element)ThalliumLeadBismuthPoloniumAstatineRadon
FranciumRadiumActiniumThoriumProtactiniumUraniumNeptuniumPlutoniumAmericiumCuriumBerkeliumCaliforniumEinsteiniumFermiumMendeleviumNobeliumLawrenciumRutherfordiumDubniumSeaborgiumBohriumHassiumMeitneriumDarmstadtiumRoentgeniumCoperniciumNihoniumFleroviumMoscoviumLivermoriumTennessineOganesson
Ge

Sn

Pb
indiumtinantimony
Groupgroup 14 (carbon group)
Periodperiod 5
Block p-block
Electron configuration[Kr] 4d10 5s2 5p2
Electrons per shell2, 8, 18, 18, 4
Physical properties
Phaseat STPsolid
Melting point505.08 K(231.93 °C,449.47 °F)
Boiling point2875 K(2602 °C,4716 °F)
Density(near r.t.)white, β: 7.265 g/cm3
gray, α: 5.769 g/cm3
when liquid (at m.p.)6.99 g/cm3
Heat of fusionwhite, β: 7.03 kJ/mol
Heat of vaporizationwhite, β: 296.1 kJ/mol
Molar heat capacitywhite, β: 27.112 J/(mol·K)
Vapor pressure
P (Pa)1101001 k10 k100 k
at T (K)149716571855210724382893
Atomic properties
Oxidation states−4, −3, −2, −1, 0,[2] +1,[3]+2, +3,[4]+4 (an amphoteric oxide)
ElectronegativityPauling scale: 1.96
Ionization energies
  • 1st: 708.6 kJ/mol
  • 2nd: 1411.8 kJ/mol
  • 3rd: 2943.0 kJ/mol
Atomic radiusempirical:140 pm
Covalent radius139±4 pm
Van der Waals radius217 pm
Color lines in a spectral range
Spectral lines of tin
Other properties
Natural occurrenceprimordial
Crystal structuretetragonal
Tetragonal crystal structure for tin

white (β)
Crystal structureface-centered diamond-cubic
Diamond cubic crystal structure for tin

gray (α)
Speed of soundthin rod2730 m/s(at r.t.)(rolled)
Thermal expansion22.0 µm/(m⋅K)(at 25 °C)
Thermal conductivity66.8 W/(m⋅K)
Electrical resistivity115 nΩ⋅m(at 0 °C)
Magnetic orderinggray:diamagnetic[5]
white (β):paramagnetic
Molar magnetic susceptibility(white) +3.1·10−6 cm3/mol(298 K)[6]
Young's modulus50 GPa
Shear modulus18 GPa
Bulk modulus58 GPa
Poisson ratio0.36
Brinell hardness50–440 MPa
CAS Number7440-31-5
History
Discoveryaround3500 BC
Symbol"Sn": from Latinstannum
Isotopes of tin
Main isotopes[7]Decay
abun­dancehalf-life(t1/2)modepro­duct
112Sn0.970%stable
114Sn0.66%stable
115Sn0.34%stable
116Sn14.5%stable
117Sn7.68%stable
118Sn24.2%stable
119Sn8.59%stable
120Sn32.6%stable
122Sn4.63%stable
124Sn5.79%stable
126Sntrace2.3×105 yβ126Sb
 Category: Tin
|references
Tin

Tin is achemical element with symbol Sn (forLatin:stannum) andatomic number 50. It is inGroup 14 on the periodic table. It has ten isotopes that are notradioactive, which is more than any other element.

Properties

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Physical properties

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Alpha(α) and beta(β) forms of tin

Tin is a silver, somewhat softmetal. It is apost-transition metal. Its melting point is 231.93°C and its boiling point is 2602 °C. It can melt easily in a flame. It ismalleable. It makes a crackling sound called tin cry when a piece of it is bent. Tin has more non-radioactiveisotopes than any other element.

Tin is found in twoallotropes: alpha-tin and beta-tin. Alpha-tin is a brittle, dull, powdery,semimetallic form of tin. It is made when very pure tin is cooled. Beta-tin is the normal shiny, soft,conductive, metallic form. It is made at higher temperatures. The decay of tin by turning from beta-tin to alpha-tin is calledtin pest. Alpha-tin is not wanted in many places. When small amounts of other elements likeantimony are added, the tin cannot change into alpha-tin. When alpha-tin is heated, it changes into beta-tin.

Tin can be hardened by adding antimony orcopper, as well as some other elements. These also make it resistant to tin pest. Tin can also be made very shiny. Tin can make analloy withcopper calledbronze.

Chemical properties

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Tin resists manycorrosive substances and is often used to protect other metals. Salt water and fresh water do not affect tin. It dissolves in strong acids to make tin salts. It reacts with some strong bases.

Chemical compounds

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Tin formschemical compounds in twooxidation states: +2 and +4. +2 compounds are reducing agents. Some of them are colorless while others are colored. +4 compounds are more unreactive and act morecovalent.

Tin burns in air to maketin(IV) oxide, which is white. Tin(IV) oxide dissolves inacids to make other tin(IV) compounds.Tin(IV) chloride is a colorless fuming liquid whenanhydrous and a white solid whenhydrated. It easily reacts with water to make tin(IV) oxide and an acid again.

Tin reacts withhydrohalic acids to make tin(II)halides. For example,tin(II) chloride is made when tin dissolves inhydrochloric acid. Tin(IV) halides are made when tin reacts with thehalogens.Tin(IV) chloride is made when tin reacts withchlorine.Tin(II) sulfate is different as it does not oxidize to tin(IV) sulfate.Tin(II) oxide is a blue-black solid that burns in air to make tin(IV) oxide.

+2 compounds

+2 compounds arereducing agents. They are about as common as +4 compounds. Some are colorless, while others are colored.

+4 compounds

+4 compounds are unreactive. Some are colorless.

  • Tin(II) chloride
    Tin(II) chloride
  • Hydrated tin(IV) chloride
    Hydrated tin(IV) chloride
  • Anhydrous tin(IV) chloride
    Anhydrous tin(IV) chloride
  • Tin(IV) iodide
    Tin(IV) iodide
  • Tin(IV) oxide
    Tin(IV) oxide
  • Tin(II) oxide
    Tin(II) oxide

Occurrence

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Cassiterite

Tin is not found as a metal in the ground. It is normally in the form ofcassiterite. Cassiterite is amineral containgtin(IV) oxide. The cassiterite is normally found downstream of the cassiterite deposit when it is by a stream or river. Tin is also found in some complicatedsulfide minerals.

Tin does not have any major job in the human body.

Preparation

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Tin is made by heating cassiterite withcarbon in a furnace.China is the biggest maker of tin.

History

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People discovered tin long ago and used it with other metals. Whencopper and tin are mixed together,bronze is made. Bronze was important in the past, because it was one of the strongest metals available, which meant it was useful in weapons and tools. Bronze changed the world when it was first invented, starting theBronze Age. People organized themselves more, because making tools from bronze was harder than making them from rock and wood like they did before.

Uses

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Pewter plate
Tin solder without lead

Tin is used insolder. Solder used to contain a mixture of lead and tin. Now the lead is removed because of itstoxicity.

Tin is also used to makepewter, which is mainly tin mixed with a small amount of copper and other metals.Babbitt metal also has tin in it. Tin is used to coat several metals, like lead and steel. Tin plated steel containers are used to store foods. The pipes on apipe organ are made of tin.Tin foil was used beforealuminium foil. Tin was one of the firstsuperconductors to be found. Organotin compounds are more common than almost any otherorganometal compound. They are used in somePVC pipes to stop them from decaying. Organotin compounds are toxic, though.

Safety

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Tin is not toxic, but tin compounds are very toxic tomarine life. They are a little toxic to humans.

Sources

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  1. "Standard Atomic Weights: Tin".CIAAW. 1983.
  2. "New Type of Zero-Valent Tin Compound".Chemistry Europe. 27 August 2016.
  3. "HSn".NIST Chemistry WebBook. National Institute of Standards and Technology. Retrieved23 January 2013.
  4. "SnH3".NIST Chemistry WebBook. National Institure of Standards and Technology. Retrieved23 January 2013.
  5. Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds".CRC Handbook of Chemistry and Physics(PDF) (86th ed.). Boca Raton (FL): CRC Press.ISBN 0-8493-0486-5.
  6. Weast, Robert (1984).CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110.ISBN 0-8493-0464-4.
  7. Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021)."The NUBASE2020 evaluation of nuclear properties"(PDF).Chinese Physics C.45 (3): 030001.doi:10.1088/1674-1137/abddae.
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