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Phosgene

From Simple English Wikipedia, the free encyclopedia
Not to be confused withphosgene oxime.
A phosgene tank.
Chemical note

Phosgene is thechemical compound with theformula COCl2. This gas has no color. The gas was used as aweapon duringWorld War I. It is responsible for most of the deaths related to poison gas during the war. Today, phosgene is used as a tool. It is used fororganic synthesis. When there is a small amount in the air, the smell is similar to that of freshly cut hay or grass. Some soldiers during the First World War have stated that it smelled a little likeMay Blossom. When somecompounds ofchlorine andcarbon burn or break down, small amounts of phosgene are given off.[1]

Uses

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Today, most phosgene is used to produceisocyanates. The most important isocanates in this context aretoluene diisocyanate (TDI) andmethylene diphenyl diisocyanate (MDI). Both areprecursors topolyurethanes. Large amounts are also used to producepolycarbonates. Polycarbonate is produced from its reaction withbisphenol A.[1] Polycarbonates are an important class of engineeringthermoplastic. They can be found in lenses in eyeglasses.

Safety

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Phosgene is a strongpoison. Its smell may not be noticed. Signs of exposure may sometimes be detected slowly.[2]Phosgene can be seen at 0.4parts per million. This amount is four times thesafe amount. Its high ability to poison doesn't come from the hydrogen chloride released bya process. It comes from the action of the phosgene on the proteins in the pulmonarysac of the lungs. Thesacs are where the oxygen goes into the body. Their damage makes it hard for the blood and air move oxygen and carbon. This will make breathing very hard. Badges are worn by those at risk of exposure.[1]

Sodium bicarbonate may be used to make spills of phosgene harmless. Gas spills may be made harmless witha special liquid spray.[3]

Other websites

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References

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  1. 1.01.11.2Wolfgang Schneider and Werner Diller "Phosgene" in Ullmann's Encyclopedia of Industrial Chemistry Wiley-VCH, Weinheim, 2002. DOI: 10.1002/14356007.a19_411. Article Online Posting Date: June 15, 2000
  2. Borak J., Diller W. F. (2001)."Phosgene exposure: mechanisms of injury and treatment strategies".Journal of Occupational and Environmental Medicine.43 (2):110–9.doi:10.1097/00043764-200102000-00008.PMID 11227628.S2CID 41169682.
  3. "Phosgene: Health and Safety Guide".International Programme on Chemical Safety. 1998.
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