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Lead

From Simple English Wikipedia, the free encyclopedia
Lead, 00Pb
A small gray metal cube surrounded by three gray metal nuggets in front of a light gray background
Lead
Pronunciation/ˈlɛd/ (led)
Appearancemetallic gray
Standard atomic weightAr°(Pb)
[206.14207.94][1]
Lead in theperiodic table
HydrogenHelium
LithiumBerylliumBoronCarbonNitrogenOxygenFluorineNeon
SodiumMagnesiumAluminiumSiliconPhosphorusSulfurChlorineArgon
PotassiumCalciumScandiumTitaniumVanadiumChromiumManganeseIronCobaltNickelCopperZincGalliumGermaniumArsenicSeleniumBromineKrypton
RubidiumStrontiumYttriumZirconiumNiobiumMolybdenumTechnetiumRutheniumRhodiumPalladiumSilverCadmiumIndiumTinAntimonyTelluriumIodineXenon
CaesiumBariumLanthanumCeriumPraseodymiumNeodymiumPromethiumSamariumEuropiumGadoliniumTerbiumDysprosiumHolmiumErbiumThuliumYtterbiumLutetiumHafniumTantalumTungstenRheniumOsmiumIridiumPlatinumGoldMercury (element)ThalliumLeadBismuthPoloniumAstatineRadon
FranciumRadiumActiniumThoriumProtactiniumUraniumNeptuniumPlutoniumAmericiumCuriumBerkeliumCaliforniumEinsteiniumFermiumMendeleviumNobeliumLawrenciumRutherfordiumDubniumSeaborgiumBohriumHassiumMeitneriumDarmstadtiumRoentgeniumCoperniciumNihoniumFleroviumMoscoviumLivermoriumTennessineOganesson
Sn

Pb

Fl
thalliumleadbismuth
Groupgroup 14 (carbon group)
Periodperiod 6
Block p-block
Electron configuration[Xe] 4f14 5d10 6s2 6p2
Electrons per shell2, 8, 18, 32, 18, 4
Physical properties
Phaseat STPsolid
Melting point600.61 K ​(327.46 °C, ​621.43 °F)
Boiling point2022 K ​(1749 °C, ​3180 °F)
Density (near r.t.)11.34 g/cm3
when liquid (at m.p.)10.66 g/cm3
Heat of fusion4.77 kJ/mol
Heat of vaporization179.5 kJ/mol
Molar heat capacity26.650 J/(mol·K)
Vapor pressure
P (Pa)1101001 k10 k100 k
at T (K)97810881229141216602027
Atomic properties
Oxidation states−4, −2, −1, 0,[2] +1,+2, +3,+4 (an amphoteric oxide)
ElectronegativityPauling scale: 1.87 (+2)
Ionization energies
  • 1st: 715.6 kJ/mol
  • 2nd: 1450.5 kJ/mol
  • 3rd: 3081.5 kJ/mol
Atomic radiusempirical: 175 pm
Covalent radius146±5 pm
Van der Waals radius202 pm
Color lines in a spectral range
Spectral lines of lead
Other properties
Natural occurrenceprimordial
Crystal structureface-centered cubic (fcc)
Face-centered cubic crystal structure for lead
Speed of sound thin rod1190 m/s (at r.t.) (annealed)
Thermal expansion28.9 µm/(m⋅K) (at 25 °C)
Thermal conductivity35.3 W/(m⋅K)
Electrical resistivity208 nΩ⋅m (at 20 °C)
Magnetic orderingdiamagnetic
Molar magnetic susceptibility−23.0×10−6 cm3/mol (at 298 K)[3]
Young's modulus16 GPa
Shear modulus5.6 GPa
Bulk modulus46 GPa
Poisson ratio0.44
Mohs hardness1.5
Brinell hardness38–50 MPa
CAS Number7439-92-1
History
Discoveryin theMiddle East (7000 BCE)
Symbol"Pb": from Latinplumbum
Isotopes of lead
Main isotopes[4]Decay
abun­dancehalf-life(t1/2)modepro­duct
202Pbsynth5.25×104 yε202Tl
204Pb1.40%stable
205Pbtrace1.73×107 yε205Tl
206Pb24.1%stable
207Pb22.1%stable
208Pb52.4%stable
209Pbtrace3.253 hβ209Bi
210Pbtrace22.20 yβ210Bi
211Pbtrace36.1 minβ211Bi
212Pbtrace10.64 hβ212Bi
214Pbtrace26.8 minβ214Bi
Isotopic abundances vary greatly by sample[5]
 Category: Lead
| references
Lead

Lead (pronounce: "/'lɛd/") is achemical element. Itschemical symbol isPb, which comes fromplumbum, theLatin word for lead.[6] Itsatomic number is 82,atomic mass is 207.2 and has a melting point of 327.8°C. It is a verypoisonous and heavymetal, and is also the ending element to thestable elements, although the next element, bismuth, is so weakly radioactive that it can be considered stable for practical purposes.[7]

Properties

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Physical properties

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Lead powder burning

Lead is a shiny, gray-bluepoor metal. It getstarnished easily to a dull gray color. It is soft andmalleable. It is very shiny when it is melted. It is very heavy. It is verycorrosion-resistant. It is made stronger by addingantimony orcalcium. It can form an alloy withsodium. It is toxic to people and animals when swallowed.

Chemical properties

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Flame test for lead
Flame test for lead

Lead burns in air with a grayish-white flame, making toxic fumes oflead(II) oxide. Only the surface is corroded by air. It dissolves innitric acid to makelead(II) nitrate. It does not dissolve insulfuric orhydrochloric acid. It reacts withsodium nitrate to make lead(II) oxide andsodium nitrite. It reacts withchlorine to makelead(II) chloride. Lead(II) oxide reacts withlead sulfide to make lead metal andsulfur dioxide.

Chemical compounds

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Lead makeschemical compounds in two mainoxidation states: +2 and +4. +2 compounds, also known as lead(II) compounds or plumbous compounds, are weakoxidizing agents. +4 compounds, also known as lead(IV) compounds or plumbic compounds, are strong oxidizing agents. Lead compounds are toxic just like the element. The leadhalides do not dissolve in water.Lead(IV) oxide is the most common lead(IV) compound. It is a black solid. The lead oxides are all colored, while the other salts are white or colorless.Lead nitrate andlead(II) acetate are thesoluble compounds of lead.

+2 compounds

This state is more common than the +4 state. These are weakoxidizing agents. All but the oxides are colorless or white.

Mixed oxidation state compounds

Mixed oxidation state compounds contain lead in the +2 and +4 oxidation state.

+4 compounds

These are less common. They are strongoxidizing agents.

  • Lead(II) chloride
    Lead(II) chloride
  • Lead(II) nitrate
    Lead(II) nitrate
  • Lead(IV) oxide
    Lead(IV) oxide
  • Lead(II,IV) oxide
    Lead(II,IV) oxide
  • Lead(II) oxide
    Lead(II) oxide

Occurrence

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  • Lead found in the ground
    Lead found in the ground
  • Galena
    Galena

Lead is found very rarely in the earth's crust as a metal. Normally, lead is in themineralgalena. Galena islead sulfide. Galena is the main lead ore.

History

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Lead was used for thousands of years because it is easy to get from the ground and easy to shape and work with. The Romans used lead very commonly. They used it for pipes, drinking vessels, andfasteners.

Preparation

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Lead is made from galena. Galena is made pure byfroth flotation to get all the impurities out. Then the lead sulfide is roasted in a furnace to makelead(II) oxide. The lead(II) oxide is heated withcoke to make liquid lead metal.

Uses

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As an element

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The dark bricks are made of lead. They are meant to keep people safe from the radioactive material inside.

Lead is used in theballast ofsailboats. It is also used in weight belts forscuba diving. It is also used to makeshotgun pellets andbullets forsmall arms. Someprinting presses use lead type because it can be easily shaped. It can be used outside because it does not corrode in water.

Most lead is used inlead acid batteries, though. The lead isoxidized, makingelectricity. Sheets of lead are used to block sound in some places. Lead is used in radiation shielding. Molten lead can be used as acoolant innuclear reactors. It used to be mixed withtin to make the pipes inpipe organs. Different amounts of lead make different sounds. In addition, lead has found its usage insolder.

It is used in some solder. It is used in covering for wires that carry high voltage. Sometennis rackets have lead in them to make them heavier. It is used to balance wheels of cars, to make statues, and to make decorative looks in buildings.

As chemical compounds

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Many lead compounds are used to make coloredglazes inceramics. Lead can be used inPVC pipes. Lead compounds are added tocandles to make them burn better.Lead glass has lead(II) oxide in it. Lead compounds are still used aspigments in some places. Lead compounds were added to gasoline, but are now outlawed. Some lead compounds aresemiconductors and are used inphotodetectors.

Old uses

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Lead was used in many red, yellow, and white pigments in paints. Lead was also used inpesticides. Lead used to be used in pipes carrying water, but now it is not because lead can leach into the water.

Safety

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Although it can be safely touched, exposure to lead should be avoided – it is verytoxic to humans and otheranimals when swallowed, and its use is restricted in manycountries.

If someone is exposed to lead for a long time, it ruins theirkidneys and gives themabdominal pains. Lead also ruins thenervous system. Lead paint was being eaten by children and they were gettinglead poisoning.

The best way to understand lead and its properties is to read itsMSDS.

Related pages

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References

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  1. "Standard Atomic Weights: Lead".CIAAW. 1969.
  2. Pb(0) carbonyls have been observered in reaction between lead atoms andcarbon monoxide; seeLing, Jiang; Qiang, Xu (2005)."Observation of the lead carbonyls PbnCO (n=1–4): Reactions of lead atoms and small clusters with carbon monoxide in solid argon".The Journal of Chemical Physics. 122 (3): 034505.122 (3): 34505.Bibcode:2005JChPh.122c4505J.doi:10.1063/1.1834915.ISSN 0021-9606.PMID 15740207.
  3. Weast, Astle & Beyer 1983, p. E110. sfn error: no target: CITEREFWeastAstleBeyer1983 (help)
  4. Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021)."The NUBASE2020 evaluation of nuclear properties"(PDF).Chinese Physics C.45 (3): 030001.doi:10.1088/1674-1137/abddae.
  5. 5.05.1Meija et al. 2016. sfn error: no target: CITEREFMeijaCoplenBerglundBrand2016 (help)
  6. "Discovering Roman Technology". BBC. Archived fromthe original on 2009-02-16. Retrieved2009-10-03.
  7. "Is Bismuth Radioactive? Setting the Record Straight".The Bismuth Smith. The Bismuth Smith Inc. Retrieved8 March 2024.
H He
LiBe BCNOFNe
NaMg AlSiPSClAr
KCa ScTiVCrMnFeCoNiCuZnGaGeAsSeBrKr
RbSr YZrNbMoTcRuRhPdAgCdInSnSbTeIXe
CsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRn
FrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
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