doi: 10.1039/c9ra04636d. eCollection 2019 Aug 23.
Low temperature synthesis and characterization of single phase multi-component fluorite oxide nanoparticle sols
Affiliations
- PMID:35528557
- PMCID: PMC9070433
- DOI: 10.1039/c9ra04636d
Item in Clipboard
Low temperature synthesis and characterization of single phase multi-component fluorite oxide nanoparticle sols
Mariappan Anandkumar et al. RSC Adv..
Display options
Format
Display options
Format
Abstract
We report for the first time a simple, scalable approach for the synthesis of single-phase multi-component fluorite oxide nanoparticle sols: Gd0.2La0.2Y0.2Hf0.2Zr0.2O2 (GLYHZ) and Gd0.2La0.2Ce0.2Hf0.2Zr0.2O2 (GLCHZ) using chemical co-precipitation followed by peptization in acidic medium under mild conditions (≤80 °C). High resolution transmission electron microscopy (HRTEM) along with selected area electron diffraction (SAED) studies confirm fully crystalline single-phase cubic fluorite nanoparticles having a particle size of about 2-3 nm with a narrow size distribution was obtained. The powder X-ray diffraction (XRD) and Rietveld refinement studies of samples calcined at 500 °C for 4 hours confirm a single phase solid solution and a lack of secondary phases.
This journal is © The Royal Society of Chemistry.
Conflict of interest statement
There are no conflicts to declare.
Figures
Similar articles
- Entropy-Stabilized Oxides owning Fluorite Structure obtained by Hydrothermal Treatment.Spiridigliozzi L, Ferone C, Cioffi R, Accardo G, Frattini D, Dell'Agli G.Spiridigliozzi L, et al.Materials (Basel). 2020 Jan 24;13(3):558. doi: 10.3390/ma13030558.Materials (Basel). 2020.PMID:31991550Free PMC article.
- Synthesis of La2Ce2O7 nanoparticles by co-precipitation method and its characterization.Tinwala H, Shah DV, Menghani J, Pati R.Tinwala H, et al.J Nanosci Nanotechnol. 2014 Aug;14(8):6072-6. doi: 10.1166/jnn.2014.8834.J Nanosci Nanotechnol. 2014.PMID:25936060
- Multigram scale synthesis and characterization of monodisperse tetragonal zirconia nanocrystals.Joo J, Yu T, Kim YW, Park HM, Wu F, Zhang JZ, Hyeon T.Joo J, et al.J Am Chem Soc. 2003 May 28;125(21):6553-7. doi: 10.1021/ja034258b.J Am Chem Soc. 2003.PMID:12785795
- Structural characterization of CeO(2)-ZrO(2)/TiO(2) and V(2)O(5)/CeO(2)-ZrO(2)/TiO(2) mixed oxide catalysts by XRD, Raman spectroscopy, HREM, and other techniques.Reddy BM, Lakshmanan P, Khan A, López-Cartes C, Rojas TC, Fernandez A.Reddy BM, et al.J Phys Chem B. 2005 Feb 10;109(5):1781-7. doi: 10.1021/jp045723+.J Phys Chem B. 2005.PMID:16851158
- High-Entropy Perovskites as Multifunctional Metal Oxide Semiconductors: Synthesis and Characterization of (Gd0.2Nd0.2La0.2Sm0.2Y0.2)CoO3.Krawczyk PA, Jurczyszyn M, Pawlak J, Salamon W, Baran P, Kmita A, Gondek Ł, Sikora M, Kapusta C, Strączek T, Wyrwa J, Żywczak A.Krawczyk PA, et al.ACS Appl Electron Mater. 2020 Oct 27;2(10):3211-3220. doi: 10.1021/acsaelm.0c00559. Epub 2020 Sep 18.ACS Appl Electron Mater. 2020.PMID:33196046Free PMC article.
Cited by
- Ultrasound-mediated synthesis of nanoporous fluorite-structured high-entropy oxides toward noble metal stabilization.Okejiri F, Fan J, Huang Z, Siniard KM, Chi M, Polo-Garzon F, Yang Z, Dai S.Okejiri F, et al.iScience. 2022 Apr 6;25(5):104214. doi: 10.1016/j.isci.2022.104214. eCollection 2022 May 20.iScience. 2022.PMID:35494219Free PMC article.
- Effective band gap engineering in multi-principal oxides (CeGdLa-Zr/Hf)Ox by temperature-induced oxygen vacancies.Hu Y, Anandkumar M, Joardar J, Wang X, Deshpande AS, Reddy KM.Hu Y, et al.Sci Rep. 2023 Feb 9;13(1):2362. doi: 10.1038/s41598-023-29477-0.Sci Rep. 2023.PMID:36759551Free PMC article.
References
- Tsai C.-W. Lai S.-W. Cheng K.-H. Tsai M.-H. Davison A. Tsau C.-H. Yeh J.-W. Thin Solid Films. 2012;520:2613–2618. doi: 10.1016/j.tsf.2011.11.025. - DOI
- Pogrebnjak A. D. Yakushchenko I. V. Abadias G. Chartier P. Bondar O. V. Beresnev V. M. Takeda Y. Sobol' O. V. Oyoshi K. Andreyev A. A. Mukushev B. A. J. Superhard Mater. 2013;35:356–368. doi: 10.3103/S106345761306004X. - DOI
- Pogrebnjak A. D. Bagdasaryan A. A. Yakushchenko I. V. Beresnev V. M. Russ. Chem. Rev. 2014;83:1027–1061. doi: 10.1070/RCR4407. - DOI
- Yan X. Constantin L. Lu Y. Silvain J.-F. Nastasi M. Cui B. J. Am. Ceram. Soc. 2018;101:4486–4491. doi: 10.1111/jace.15779. - DOI
LinkOut - more resources
Full Text Sources
Research Materials
Miscellaneous