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.2013 Jun;49(2):250-6.
doi: 10.1080/10256016.2013.766610. Epub 2013 Mar 6.

On the conversion of tritium units to mass fractions for hydrologic applications

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Free PMC article

On the conversion of tritium units to mass fractions for hydrologic applications

David A Stonestrom et al. Isotopes Environ Health Stud.2013 Jun.
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Abstract

We develop a general equation for converting laboratory-reported tritium levels, expressed either as concentrations (tritium isotope number fractions) or mass-based specific activities, to mass fractions in aqueous systems. Assuming that all tritium is in the form of monotritiated water simplifies the derivation and is shown to be reasonable for most environmental settings encountered in practice. The general equation is nonlinear. For tritium concentrations c less than 4.5 × 10(12) tritium units (TU) - i.e. specific tritium activities<5.3 × 10(11) Bq kg(-1) - the mass fraction w of tritiated water is approximated to within 1 part per million by w ≈ c × 2.22293 × 10(-18), i.e. the conversion is linear for all practical purposes. Terrestrial abundances serve as a proxy for non-tritium isotopes in the absence of sample-specific data. Variation in the relative abundances of non-tritium isotopes in the terrestrial hydrosphere produces a minimum range for the mantissa of the conversion factor of [2.22287; 2.22300].

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References

    1. Clark I.D., Fritz P. Environmental Isotopes in Hydrogeology. Boca Raton, FL: Lewis Publishers; 1997.
    1. Kendall C., McDonnell J.J., editors. Isotope Tracers in Catchment Hydrology. New York, NY: Elsevier; 1998.
    1. Khatiwala S., Visbeck M., Schlosser P. Age Tracers in an Ocean GCM, Deep Sea Res. Part I. Oceanographic Res. Papers. 2001;48:1423.
    1. Solomon D.K., Cook PG. In: 3H and 3He, in Environmental Tracers in Subsurface Hydrology. Cook PG., Herczeg A.L., editors. Boston, MA: Kluwer Academic Publishers; 2000. pp. 397–424.
    1. Libby W.F. Atmospheric Helium Three and Radiocarbon from Cosmic Radiation. Phys. Rev. 1946;69:671.

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