doi: 10.1021/ja110332r. Epub 2011 Feb 28.
Borinic acid-catalyzed regioselective acylation of carbohydrate derivatives
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- PMID:21355584
- DOI: 10.1021/ja110332r
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Borinic acid-catalyzed regioselective acylation of carbohydrate derivatives
Doris Lee et al. J Am Chem Soc..
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Abstract
Reversible covalent interactions of organoboron compounds are exploited as the basis for regioselective borinic acid-catalyzed acylations of polyols. This catalytic protocol enables differentiation of the secondary OH groups of a wide range of carbohydrate derivatives with diverse acid chloride and chloroformate reagents, using a structurally simple diarylborinic acid-derived catalyst.
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