doi: 10.1039/b314744d. Epub 2004 Jan 28.
A novel synthesis of chiral rotaxanes via covalent bond formation
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- PMID:14765261
- DOI: 10.1039/b314744d
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A novel synthesis of chiral rotaxanes via covalent bond formation
Naohiro Kameta et al. Chem Commun (Camb)..
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Abstract
Chiral rotaxanes composed of the asymmetric crownophane incorporating two hydroxy groups as a rotor moiety and the asymmetric axis were effectively synthesized via covalent bond formation, i.e. tandem Claisen rearrangement, esterification, and aminolysis.
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