本申请属于净水装置技术领域，更具体地说，是涉及一种具有净化和杀菌作用的具有掺硼金刚石阳极的净化水杯。The present application belongs to the technical field of water purification devices, and more specifically, to a water purification cup with a boron-doped diamond anode having purification and sterilization functions.
在野外生存中，如何取得干净、安全的饮用水是值得关注的问题，野外的水源的污染物常有大颗粒的杂质(落叶、泥沙等)、重金属和农药污染、寄生虫、细菌和病毒等。如何生产一种集过滤、消毒于一体同时具有便携性的设备具有广袤的市场前景。When surviving in the wild, how to obtain clean and safe drinking water is a problem worthy of attention. Pollutants in wild water sources often include large particles of impurities (fallen leaves, mud, etc.), heavy metal and pesticide pollution, parasites, bacteria and viruses, etc. How to produce a device that integrates filtration and disinfection and is also portable has broad market prospects.
市场上已出现一种净化水杯，用于净化和消毒饮用水，现有的净化水杯目前使用的电极有：金属电极(铂电极)、石墨电极、金属氧化物(铂、钛等金属氧化物)阳极等，其中，金属电极和金属氧化物电极的化学稳定性较差，存在诸如可能会在反应过程中失去电子形成金属阳离子，进入溶液造成阳极的损耗，同时会在水中引入金属杂质的问题；在反应过程中这些电极可能会发生其他反应引入新的杂质，造成二次污染影响饮用者的身体健康。A water purification cup has appeared on the market for purifying and disinfecting drinking water. The electrodes currently used in the existing water purification cups include: metal electrodes (platinum electrodes), graphite electrodes, metal oxide (platinum, titanium and other metal oxides) anodes, etc. Among them, the chemical stability of metal electrodes and metal oxide electrodes is poor, and there are problems such as the possibility of losing electrons in the reaction process to form metal cations, which enter the solution to cause anode loss, and introduce metal impurities into the water; in the reaction process, these electrodes may undergo other reactions to introduce new impurities, causing secondary pollution and affecting the health of the drinker.
基于此，本申请的目的在于提供一种具有掺硼金刚石阳极的净化水杯，以解决现有技术中存在的现有具有掺硼金刚石阳极的净化水杯常用的电极化学稳定性差，容易失去电子，形成金属离子污染水的技术问题。Based on this, the purpose of this application is to provide a purified water cup with a boron-doped diamond anode to solve the technical problem that the electrodes commonly used in the existing purified water cups with boron-doped diamond anodes in the prior art have poor chemical stability and are easy to lose electrons, forming metal ions to pollute the water.
为实现上述目的，本申请采用的技术方案是：To achieve the above purpose, the technical solution adopted in this application is:
提供一种具有掺硼金刚石阳极的净化水杯，用于对水或水溶液进行净化和消毒，具有掺硼金刚石阳极的净化水杯包括：Provided is a water purification cup with a boron-doped diamond anode, which is used for purifying and disinfecting water or aqueous solution. The water purification cup with a boron-doped diamond anode comprises:
杯体，杯体设有腔室；A cup body, wherein the cup body is provided with a chamber;
电源模块，电源模块安装于杯体上；以及A power module, the power module is installed on the cup body; and
电极组件，电极组件包括阳极和阴极，阳极和阴极安装于腔室内，并且阳极和阴极分别电连接电源模块的正极和负极；阳极包括极芯和掺硼金刚石膜，掺硼金刚石膜包覆于极芯的表面。The electrode assembly includes an anode and a cathode, which are installed in the chamber and are electrically connected to the positive and negative electrodes of the power module respectively; the anode includes an electrode core and a boron-doped diamond film, and the boron-doped diamond film is coated on the surface of the electrode core.
可选地，极芯为钛网或钛片；Optionally, the pole core is a titanium mesh or a titanium sheet;
和/或，阴极为纯钛片或者带孔钛片或者不锈钢片。And/or, the cathode is a pure titanium sheet or a perforated titanium sheet or a stainless steel sheet.
可选地，掺硼金刚石膜中，掺硼的浓度为1600ppm-5800ppm。Optionally, in the boron-doped diamond film, the concentration of boron is 1600 ppm-5800 ppm.
可选地，电极组件还包括第一电极夹和第二电极夹，第一电极夹和第二电极夹均安装于腔室内，第一电极夹用于可拆卸地夹紧阳极，第二电极夹用于可拆卸地夹紧阴极。Optionally, the electrode assembly further includes a first electrode clamp and a second electrode clamp, both of which are installed in the chamber, the first electrode clamp is used to detachably clamp the anode, and the second electrode clamp is used to detachably clamp the cathode.
可选地，第一电极夹包括第一绝缘套和第一导体，第一绝缘套包裹于第一导体的外周，第一导体的两端分别裸露于第一绝缘套的外部，第一导体的一端与电源模块的正极电连接，第一导体的另一端用于在第一绝缘套夹紧阳极时与掺硼金刚石膜电连接；Optionally, the first electrode clamp includes a first insulating sleeve and a first conductor, the first insulating sleeve is wrapped around the outer circumference of the first conductor, two ends of the first conductor are respectively exposed outside the first insulating sleeve, one end of the first conductor is electrically connected to the positive electrode of the power module, and the other end of the first conductor is used to be electrically connected to the boron-doped diamond film when the first insulating sleeve clamps the anode;
和/或，第二电极夹包括第二绝缘套和第二导体，第二绝缘套包裹于第二导体的外周，第二导体的两端分别裸露于第二绝缘套的外部，第二导体的一端与电源模块的负极电连接，第二导体的另一端用于在第二绝缘套夹紧阴极时与阴极电连接。And/or, the second electrode clamp includes a second insulating sleeve and a second conductor, the second insulating sleeve is wrapped around the outer circumference of the second conductor, the two ends of the second conductor are respectively exposed outside the second insulating sleeve, one end of the second conductor is electrically connected to the negative pole of the power module, and the other end of the second conductor is used to be electrically connected to the cathode when the second insulating sleeve clamps the cathode.
可选地，电源模块包括电池和控制电路，电池与控制电路电连接，阳极与电池的正极电连接，阴极与电池的负极电连接；控制电路用于控制电池的开启和关闭，和/或，控制电路用于控制电池向阳极和阴极输入的电压和电流。Optionally, the power module includes a battery and a control circuit, the battery is electrically connected to the control circuit, the anode is electrically connected to the positive electrode of the battery, and the cathode is electrically connected to the negative electrode of the battery; the control circuit is used to control the opening and closing of the battery, and/or the control circuit is used to control the voltage and current input by the battery to the anode and cathode.
可选地，电源模块包括光伏发电板，光伏发电板安装于杯体的外表面；光伏发电板的正极与阳极电连接，光伏发电板的负极与阴极电连接；或者，电池为充电电池，光伏发电板的正极与电池的正极连接，光伏发电板的负极与电池的负极电连接，阳极与电池的正极电连接，阴极与电池的负极电连接。Optionally, the power module includes a photovoltaic power generation panel, which is installed on the outer surface of the cup body; the positive pole of the photovoltaic power generation panel is electrically connected to the anode, and the negative pole of the photovoltaic power generation panel is electrically connected to the cathode; or, the battery is a rechargeable battery, the positive pole of the photovoltaic power generation panel is connected to the positive pole of the battery, the negative pole of the photovoltaic power generation panel is electrically connected to the negative pole of the battery, the anode is electrically connected to the positive pole of the battery, and the cathode is electrically connected to the negative pole of the battery.
可选地，杯体包括杯座、杯身和杯盖，杯身包括底部和杯口，杯座连接于底部，杯盖可拆卸连接于杯口，杯座和杯身连接后共同构成腔室；杯座开设有容纳空间；电源模块包括电池和控制电路，电池与控制电路电连接，阳极与电池的正极电连接，阴极与电池的负极电连接；电池和控制电路安装于容纳空间中，杯体还包括底盖，底盖与杯座远离杯身的一端可拆卸连接，底盖用于封盖容纳空间。Optionally, the cup body includes a cup seat, a cup body and a cup cover, the cup body includes a bottom and a cup mouth, the cup seat is connected to the bottom, the cup cover is detachably connected to the cup mouth, and the cup seat and the cup body together form a chamber after being connected; the cup seat has a storage space; the power module includes a battery and a control circuit, the battery is electrically connected to the control circuit, the anode is electrically connected to the positive electrode of the battery, and the cathode is electrically connected to the negative electrode of the battery; the battery and the control circuit are installed in the storage space, and the cup body also includes a bottom cover, which is detachably connected to the end of the cup seat away from the cup body, and the bottom cover is used to seal the storage space.
可选地，电极组件还包括加热电极，加热电极安装于腔室内，加热电极的一端电连接电源模块的正极，加热电极的另一端电连接电源模块的负极。Optionally, the electrode assembly further includes a heating electrode, which is installed in the chamber, one end of the heating electrode is electrically connected to the positive electrode of the power module, and the other end of the heating electrode is electrically connected to the negative electrode of the power module.
可选地，具有掺硼金刚石阳极的净化水杯还包括过滤器；杯体包括杯身，杯身具有与腔室连通的杯口，过滤器内设于杯口处。Optionally, the purified water cup with a boron-doped diamond anode further includes a filter; the cup body includes a cup body, the cup body has a cup mouth connected to the chamber, and the filter is arranged at the cup mouth.
本申请提供的具有掺硼金刚石阳极的净化水杯的有益效果在于：杯体的腔室用于装水或水溶液，水或水溶液装入腔室后，阳极和阴极浸末于水或水溶液中，应用时，电源模块向阳极和阴极通电，电解水或水溶液中的有机污染物，并杀死其中的细菌；与现有技术相比，本申请中的具有掺硼金刚石阳极的净化水杯采用掺硼金刚石膜作为电解反应的阳极，掺硼金刚石具有析氢、析氧窗口大，能够使用更大电压的样品来对污水进行处理的特点，掺硼金刚石的化学稳定性强，在水或水溶液中不会和溶质发生反应；而且掺硼金刚石膜具有吸附惰性，与其他的电极材料相比，掺硼金刚石膜对生成的羟基自由基吸附性不强，反应过程中溶液中的自由基不会聚集到掺硼金刚石膜表面，不会影响有机物的电解氧化。The beneficial effect of the purified water cup with a boron-doped diamond anode provided by the present application is that: the chamber of the cup body is used to hold water or an aqueous solution. After the water or aqueous solution is loaded into the chamber, the anode and the cathode are immersed in the water or aqueous solution. When used, the power module energizes the anode and the cathode to electrolyze organic pollutants in the water or aqueous solution and kill bacteria therein; compared with the prior art, the purified water cup with a boron-doped diamond anode in the present application uses a boron-doped diamond film as the anode of the electrolytic reaction. The boron-doped diamond has a large hydrogen and oxygen evolution window and can use a sample with a larger voltage to treat sewage. The boron-doped diamond has strong chemical stability and will not react with solutes in water or aqueous solutions; and the boron-doped diamond film has adsorption inertia. Compared with other electrode materials, the boron-doped diamond film does not have strong adsorption to the generated hydroxyl radicals. During the reaction, the free radicals in the solution will not gather on the surface of the boron-doped diamond film, and will not affect the electrolytic oxidation of organic matter.
为了更清楚地说明本申请实施例中的技术方案，下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍，显而易见地，下面描述中的附图仅仅是本申请的一些实施例，对于本领域普通技术人员来讲，在不付出创造性劳动性的前提下，还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present application, the drawings required for use in the embodiments or the description of the prior art will be briefly introduced below. Obviously, the drawings described below are only some embodiments of the present application. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying any creative labor.
图1为本申请实施例提供的具有掺硼金刚石阳极的净化水杯的结构示意图；FIG1 is a schematic structural diagram of a water purification cup with a boron-doped diamond anode provided in an embodiment of the present application;
图2为图1具有掺硼金刚石阳极的净化水杯的爆炸结构示意图；FIG2 is a schematic diagram of the explosion structure of the purified water cup with a boron-doped diamond anode in FIG1 ;
图3为图1具有掺硼金刚石阳极的净化水杯省略杯盖后的结构示意图；FIG3 is a schematic structural diagram of the purified water cup with a boron-doped diamond anode in FIG1 with the cup cover omitted;
图4为图3沿A-A方向的剖视图；Fig. 4 is a cross-sectional view along the A-A direction of Fig. 3;
图5为图2具有掺硼金刚石阳极的净化水杯中的第一电极夹和阳极的连接结构示意图；FIG5 is a schematic diagram of the connection structure of the first electrode clamp and the anode in the purified water cup with the boron-doped diamond anode in FIG2;
图6为阳极的截面图。FIG6 is a cross-sectional view of the anode.
其中，图中各附图标记：Among them, the reference numerals in the figure are:
1、具有掺硼金刚石阳极的净化水杯；1. Purified water cup with boron-doped diamond anode;
10、杯体；11、腔室；12、杯座；121、容纳空间；122、充电孔；13、杯身；14、杯盖；16、底盖；10. cup body; 11. chamber; 12. cup holder; 121. storage space; 122. charging port; 13. cup body; 14. cup cover; 16. bottom cover;
20、电源模块；21、电池；22、控制电路；23、光伏发电板；20. Power module; 21. Battery; 22. Control circuit; 23. Photovoltaic power generation panel;
31、阳极；311、掺硼金刚石膜；312、极芯；32、阴极；33、第一电极夹；34、第二电极夹；35、加热电极；31. anode; 311. boron-doped diamond film; 312. pole core; 32. cathode; 33. first electrode clamp; 34. second electrode clamp; 35. heating electrode;
40、过滤器；41、主体；42、顶盖；43、滤芯。40. filter; 41. main body; 42. top cover; 43. filter element.
为了使本申请所要解决的技术问题、技术方案及有益效果更加清楚明白，以下结合附图及实施例，对本申请进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本申请，并不用于限定本申请。In order to make the technical problems, technical solutions and beneficial effects to be solved by this application more clearly understood, this application is further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are only used to explain this application and are not used to limit this application.
需要说明的是，当元件被称为“固定于”或“设置于”另一个元件，它可以直接在另一个元件上或者间接在该另一个元件上。当一个元件被称为是“连接于”另一个元件，它可以是直接连接到另一个元件或间接连接至该另一个元件上。It should be noted that when an element is referred to as being "fixed to" or "disposed on" another element, it can be directly on the other element or indirectly on the other element. When an element is referred to as being "connected to" another element, it can be directly connected to the other element or indirectly connected to the other element.
需要理解的是，术语“长度”、“宽度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系，仅是为了便于描述本申请和简化描述，而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作，因此不能理解为对本申请的限制。It should be understood that the terms "length", "width", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inside", "outside", etc., indicating the orientation or position relationship, are based on the orientation or position relationship shown in the drawings, and are only for the convenience of describing the present application and simplifying the description, and do not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be understood as a limitation on the present application.
此外，术语“第一”、“第二”仅用于描述目的，而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此，限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本申请的描述中，“多个”的含义是两个或两个以上，除非另有明确具体的限定。In addition, the terms "first" and "second" are used for descriptive purposes only and should not be understood as indicating or implying relative importance or implicitly indicating the number of the indicated technical features. Therefore, a feature defined as "first" or "second" may explicitly or implicitly include one or more of the features. In the description of this application, the meaning of "plurality" is two or more, unless otherwise clearly and specifically defined.
请一并参阅图1至图6，现对本申请实施例提供的具有掺硼金刚石阳极的净化水杯1进行说明。该具有掺硼金刚石阳极的净化水杯1用于对水或水溶液进行净化和消毒。Please refer to Figures 1 to 6 together, and now the purified water cup 1 with a boron-doped diamond anode provided in the embodiment of the present application will be described. The purified water cup 1 with a boron-doped diamond anode is used to purify and disinfect water or aqueous solution.
具有掺硼金刚石阳极的净化水杯1包括杯体10、电源模块20以及电极组件。The purified water cup 1 with a boron-doped diamond anode comprises a cup body 10, a power module 20 and an electrode assembly.
杯体10设有腔室11，腔室11用于装载水或水溶液。The cup body 10 is provided with a chamber 11 for containing water or an aqueous solution.
电源模块20安装于杯体10上，电源模块20用于为电极组件供电。The power module 20 is installed on the cup body 10, and the power module 20 is used to supply power to the electrode assembly.
电极组件包括阳极31和阴极32，阳极31和阴极32安装于腔室11内，并且阳极31和阴极32分别电连接电源模块20的正极和负极；阳极31包括极芯312和掺硼金刚石膜311，如图6所示，掺硼金刚石膜311包覆于极芯312的表面。The electrode assembly includes an anode 31 and a cathode 32, which are installed in the chamber 11, and the anode 31 and the cathode 32 are electrically connected to the positive and negative electrodes of the power module 20 respectively; the anode 31 includes a pole core 312 and a boron-doped diamond film 311, as shown in Figure 6, the boron-doped diamond film 311 is coated on the surface of the pole core 312.
本申请实施例提供的具有掺硼金刚石阳极的净化水杯1，杯体10的腔室11用于装水或水溶液，水或水溶液装入腔室11后，阳极31和阴极32浸末于水或水溶液中。应用时，电源模块20向阳极31和阴极32通电，电解水或水溶液中的有机污染物，并杀死其中的细菌。In the purified water cup 1 with a boron-doped diamond anode provided in the embodiment of the present application, the chamber 11 of the cup body 10 is used to hold water or an aqueous solution. After the water or the aqueous solution is loaded into the chamber 11, the anode 31 and the cathode 32 are immersed in the water or the aqueous solution. When in use, the power module 20 energizes the anode 31 and the cathode 32 to electrolyze organic pollutants in the water or the aqueous solution and kill bacteria therein.
与现有技术相比，本申请中的具有掺硼金刚石阳极的净化水杯1采用掺硼金刚石膜311作为电解反应的阳极，掺硼金刚石具有析氢、析氧窗口大，能够使用更大电压的样品来对污水进行处理的特点，减少在净化过程中电解水造成的额外功耗浪费；掺硼金刚石的化学稳定性强，在水或水溶液中不会和溶质发生反应；而且掺硼金刚石膜311具有吸附惰性，与其他的电极材料相比，掺硼金刚石膜311对生成的羟基自由基吸附性不强，反应过程中溶液中的自由基不会聚集到掺硼金刚石膜311表面，不会影响有机物的电解氧化。Compared with the prior art, the purified water cup 1 with a boron-doped diamond anode in the present application adopts a boron-doped diamond film 311 as the anode of the electrolytic reaction. Boron-doped diamond has a large hydrogen and oxygen evolution window and can use a sample with a larger voltage to treat sewage, thereby reducing the extra power consumption waste caused by electrolysis of water during the purification process. Boron-doped diamond has strong chemical stability and will not react with solutes in water or aqueous solutions. Moreover, the boron-doped diamond film 311 has adsorption inertness. Compared with other electrode materials, the boron-doped diamond film 311 does not have strong adsorption to the generated hydroxyl radicals. During the reaction, the free radicals in the solution will not gather on the surface of the boron-doped diamond film 311, and will not affect the electrolytic oxidation of organic matter.
在本申请一个实施例中，请参阅图2至4，杯体10包括杯座12、杯身13和杯盖14，杯身13具有与腔室11连通的杯口，杯座12连接于底部，杯盖14可拆卸连接于杯口的外周，杯座12和杯身13连接后共同构成腔室11。杯座12用于支撑杯身13，在一些实施例中，杯座12还为阳极31和阴极32提供安装场所，水和水溶液装入腔室11后，自然流动到杯身13的底部，被杯座12阻挡于腔室11内，阳极31和阴极32安装于杯座12上，即位于杯身13的底部，便于净化液位不高的水和水溶液，提高具有掺硼金刚石阳极的净化水杯1的实用性。In one embodiment of the present application, please refer to Figures 2 to 4. The cup body 10 includes a cup seat 12, a cup body 13 and a cup cover 14. The cup body 13 has a cup mouth communicating with the chamber 11. The cup seat 12 is connected to the bottom. The cup cover 14 is detachably connected to the outer periphery of the cup mouth. The cup seat 12 and the cup body 13 are connected to form the chamber 11 together. The cup seat 12 is used to support the cup body 13. In some embodiments, the cup seat 12 also provides an installation place for the anode 31 and the cathode 32. After water and aqueous solution are loaded into the chamber 11, they naturally flow to the bottom of the cup body 13 and are blocked in the chamber 11 by the cup seat 12. The anode 31 and the cathode 32 are installed on the cup seat 12, that is, located at the bottom of the cup body 13, which is convenient for purifying water and aqueous solution with low liquid level, and improving the practicality of the water purification cup 1 with boron-doped diamond anode.
可选地，杯身13和杯盖14通过螺接的方式可拆卸连接，便于装入水和水溶液。当然杯身13和杯盖14还可以用其它连接方式连接，只要能打开杯盖14，露出杯口，装入液体即可。Optionally, the cup body 13 and the cup cover 14 are detachably connected by screw connection, which is convenient for filling water and aqueous solution. Of course, the cup body 13 and the cup cover 14 can also be connected by other connection methods, as long as the cup cover 14 can be opened to expose the cup mouth and fill the liquid.
杯座12可以与杯身13固定连接，也可以与杯身13可拆卸连接，杯座12均能支撑杯身13，并且与杯身13连接后共同构成腔室11。可以理解地，杯座12与杯身13可拆卸连接更便于拆卸维修和清洗。The cup holder 12 can be fixedly connected to the cup body 13 or detachably connected to the cup body 13. The cup holder 12 can support the cup body 13 and together with the cup body 13 form the chamber 11. It can be understood that the detachable connection between the cup holder 12 and the cup body 13 is more convenient for disassembly, maintenance and cleaning.
一个实施例中，如图2所示，杯座12靠近杯身13的一端设有外螺纹，杯身13的底部设有与杯座12外螺纹相匹配的内螺纹，杯座12与杯身13通过外螺纹与内螺纹的配合实现可拆卸连接，且连接牢靠，不易漏液。In one embodiment, as shown in FIG. 2 , an end of the cup holder 12 close to the cup body 13 is provided with an external thread, and the bottom of the cup body 13 is provided with an internal thread matching the external thread of the cup holder 12 . The cup holder 12 and the cup body 13 are detachably connected through the cooperation of the external thread and the internal thread, and the connection is firm and not prone to leakage.
可选地，杯座12开设有容纳空间121，用于安装电源模块20中的一些部件，一方面，该些部件安装于杯座12中，与腔室11相隔，防止了该些部件与液体相接触，导致损坏的问题；另一方面，电源模块20的一些部件安装于杯座12可以增加具有掺硼金刚石阳极的净化水杯1底部的重量，使重心下移，不易倾倒。Optionally, the cup holder 12 is provided with a receiving space 121 for installing some components in the power module 20. On the one hand, these components are installed in the cup holder 12 and separated from the chamber 11, thereby preventing these components from contacting with the liquid and causing damage. On the other hand, some components of the power module 20 are installed in the cup holder 12 to increase the weight of the bottom of the purified water cup 1 with a boron-doped diamond anode, thereby lowering the center of gravity and preventing it from tipping over.
可选地，杯体10还包括底盖16，底盖16与杯座12远离杯身13的一端可拆卸连接，底盖16用于封盖容纳空间121，底盖16与杯座12可拆卸连接便于安装电源模块20中的部件，也便于检查维修和更换部件。Optionally, the cup body 10 also includes a bottom cover 16, which is detachably connected to an end of the cup holder 12 away from the cup body 13. The bottom cover 16 is used to seal the accommodating space 121. The detachable connection between the bottom cover 16 and the cup holder 12 facilitates the installation of components in the power module 20, and is also convenient for inspection, maintenance and replacement of components.
可选地，底盖16与杯座12对应的位置分别设有螺纹孔，通过紧固件与螺纹孔的配合将底盖16与杯座12进行连接。Optionally, threaded holes are respectively provided at corresponding positions of the bottom cover 16 and the cup holder 12 , and the bottom cover 16 and the cup holder 12 are connected by the cooperation of fasteners and the threaded holes.
可以理解地，杯体10均采用绝缘材料制成，如聚四氟乙烯等，或其它食品级的绝缘材料，避免使用过程中漏电，造成人体伤害或损坏电路的问题。It can be understood that the cup body 10 is made of insulating materials, such as polytetrafluoroethylene, or other food-grade insulating materials to avoid leakage during use, causing human harm or damage to the circuit.
电源模块20中的电源可以是外接电源，也可以是电池21，当用于户外活动时，为提高具有掺硼金刚石阳极的净化水杯1的便携性，电源可选用电池21。The power source in the power module 20 can be an external power source or a battery 21. When used for outdoor activities, in order to improve the portability of the purified water cup 1 with a boron-doped diamond anode, the power source can be a battery 21.
一个实施例中，如图4所示，电源模块20包括电池21和控制电路22，电池21和控制电路22安装于容纳空间121中，电池21与控制电路22电连接，阳极31与电池21的正极电连接，阴极32与电池21的负极电连接，控制电路22用于控制电池21的开启和关闭，和/或，控制电路22用于控制电池21向阳极31和阴极32输入的电压和电流。In one embodiment, as shown in Figure 4, the power module 20 includes a battery 21 and a control circuit 22, the battery 21 and the control circuit 22 are installed in the accommodating space 121, the battery 21 is electrically connected to the control circuit 22, the anode 31 is electrically connected to the positive electrode of the battery 21, and the cathode 32 is electrically connected to the negative electrode of the battery 21. The control circuit 22 is used to control the opening and closing of the battery 21, and/or the control circuit 22 is used to control the voltage and current input by the battery 21 to the anode 31 and the cathode 32.
可以理解地，电池21可以是非充电电池也可以是充电电池。It can be understood that the battery 21 can be a non-rechargeable battery or a rechargeable battery.
但电池21为充电电池时，控制电路22包括充电单元和开关单元，充电单元和开关单元分别电连接电池21，开关单元用于控制电源的开和关，杯座12上设有充电孔122，充电孔122，外接电源可以通过充电孔122连接充电单元对电池21进行充电。However, when the battery 21 is a rechargeable battery, the control circuit 22 includes a charging unit and a switch unit, which are electrically connected to the battery 21 respectively. The switch unit is used to control the on and off of the power supply. A charging hole 122 is provided on the cup holder 12. The charging hole 122 can be connected to the charging unit through the charging hole 122 to charge the battery 21.
可选地，电源模块20包括光伏发电板23，光伏发电板23安装于杯体10的外表面；光伏发电板23的正极与阳极31电连接，光伏发电板23的负极与阴极32电连接；或者，电池21为充电电池，光伏发电板23的正极与电池21的正极连接，光伏发电板23的负极与电池21的负极电连接，阳极31与电池21的正极电连接，阴极32与电池21的负极电连接。采用光伏发电板23可通过将光能转化为电能，便于户外活动无法连接外接电源时进行充电，避免电池21断电，无法正常工作的问题。Optionally, the power module 20 includes a photovoltaic panel 23, which is mounted on the outer surface of the cup body 10; the positive electrode of the photovoltaic panel 23 is electrically connected to the anode 31, and the negative electrode of the photovoltaic panel 23 is electrically connected to the cathode 32; or, the battery 21 is a rechargeable battery, the positive electrode of the photovoltaic panel 23 is connected to the positive electrode of the battery 21, the negative electrode of the photovoltaic panel 23 is electrically connected to the negative electrode of the battery 21, the anode 31 is electrically connected to the positive electrode of the battery 21, and the cathode 32 is electrically connected to the negative electrode of the battery 21. The photovoltaic panel 23 can be used to convert light energy into electrical energy, so that it is convenient to charge when an external power source cannot be connected during outdoor activities, thereby avoiding the problem that the battery 21 is powered off and cannot work normally.
光伏发电板23为柔性光伏发电板，可根据杯身13的形状安装于杯身13的外表面，使面积最大化。The photovoltaic power generation panel 23 is a flexible photovoltaic power generation panel, which can be installed on the outer surface of the cup body 13 according to the shape of the cup body 13 to maximize the area.
可选地，光伏功率为3W-300W，电流为0.6-60A，电压为5-36V，在安全使用的范围内，为电极组件提供足够的电量，有效净化水质。Optionally, the photovoltaic power is 3W-300W, the current is 0.6-60A, and the voltage is 5-36V, which is within the range of safe use, providing sufficient power for the electrode assembly to effectively purify the water.
可选地，掺硼金刚石膜311中，掺硼的浓度为1600ppm-5800ppm，此掺硼浓度对金刚石的晶体性能如耐热性、冲击韧性、耐磨性、化学惰性和半导体性能等的改善和提高非常显著，进一步增加掺硼金刚石膜311作为阳极31的适用性。Optionally, in the boron-doped diamond film 311 , the boron concentration is 1600ppm-5800ppm. This boron-doping concentration significantly improves and enhances the crystal properties of diamond such as heat resistance, impact toughness, wear resistance, chemical inertness and semiconductor properties, further increasing the applicability of the boron-doped diamond film 311 as the anode 31.
可以理解地，为提高阳极31的导电性和水的净化效果，极芯312采用导电材料制成。It can be understood that in order to improve the conductivity of the anode 31 and the water purification effect, the pole core 312 is made of conductive material.
在一个实施例中，极芯312为钛网或钛片，钛网和钛片的导电性能和力学性能佳，且掺硼金刚石易于附着于钛网和钛片上，其中，钛网的比表面积大，液体可以从网孔中穿过，增加液体的流动性和分散性，提高净化效果。In one embodiment, the pole core 312 is a titanium mesh or a titanium sheet. The titanium mesh and the titanium sheet have excellent electrical conductivity and mechanical properties, and the boron-doped diamond is easy to adhere to the titanium mesh and the titanium sheet. Among them, the titanium mesh has a large specific surface area, and the liquid can pass through the mesh holes, increasing the fluidity and dispersion of the liquid and improving the purification effect.
可选地，钛网的规格为10-300目，尺寸为1cm×1cm-5cm×5cm；钛片可以为带孔钛片和普通钛片，钛片牌号可以是TC4、TA1、TA2，该些规格的钛网或钛片不占用过多杯体10内过多的体积，并保证阳极31的工作面积，确保电解净化的效果。Optionally, the titanium mesh has a mesh size of 10-300 and a size of 1cm×1cm-5cm×5cm; the titanium sheet can be a perforated titanium sheet or an ordinary titanium sheet, and the titanium sheet brand can be TC4, TA1, or TA2. Titanium meshes or titanium sheets of these specifications do not occupy too much volume in the cup body 10, and ensure the working area of the anode 31, thereby ensuring the effect of electrolytic purification.
在一些实施例中，极芯312还可以为不锈钢片，不锈钢的牌号可以是304、201；钛片和不锈钢片的尺寸大小为1cm×1cm-5cm×5cm。In some embodiments, the pole core 312 may also be a stainless steel sheet, and the grade of the stainless steel may be 304 or 201; the size of the titanium sheet and the stainless steel sheet is 1 cm×1 cm-5 cm×5 cm.
可选地，阴极32为纯钛片或者带孔钛片或者不锈钢片，纯钛片或者带孔钛片或者不锈钢片均具有很好的导电性能，化学性质较稳定，作为阴极材料，不易氧化分离出金属阳离子。Optionally, the cathode 32 is a pure titanium sheet or a perforated titanium sheet or a stainless steel sheet. The pure titanium sheet or the perforated titanium sheet or the stainless steel sheet has good electrical conductivity and relatively stable chemical properties. As cathode materials, they are not easily oxidized to separate metal cations.
一个实施例中，图2和图4所示，阳极31和阴极32呈相对设置，且阳极31和阴极32之间的距离为1-8cm。阳极31和阴极32之间的间距范围在1cm-8cm，主要用于控制电解程度和电流密度大小，阳极31和阴极32之间的距离大于8cm时，可能会导致电流密度大幅降低，降低净化效果；阳极31和阴极32之间的距离小于1cm时，可能会产生击穿的问题。In one embodiment, as shown in FIG. 2 and FIG. 4 , the anode 31 and the cathode 32 are arranged opposite to each other, and the distance between the anode 31 and the cathode 32 is 1-8 cm. The distance between the anode 31 and the cathode 32 is in the range of 1 cm-8 cm, which is mainly used to control the electrolysis degree and the current density. When the distance between the anode 31 and the cathode 32 is greater than 8 cm, the current density may be greatly reduced, thereby reducing the purification effect; when the distance between the anode 31 and the cathode 32 is less than 1 cm, a breakdown problem may occur.
一些实施例中，当具有掺硼金刚石阳极的净化水杯1用于进行水处理时，阳极31的工作功率范围为0.05W-60W，极片的电流密度范围为0.01-10A/cm2。In some embodiments, when the purified water cup 1 with a boron-doped diamond anode is used for water treatment, the operating power range of the anode 31 is 0.05W-60W, and the current density range of the pole piece is 0.01-10A/cm2.
可选地，请一并参阅图2至图5，电极组件还包括第一电极夹33和第二电极夹34，第一电极夹33和第二电极夹34均安装于腔室11内，第一电极夹33用于可拆卸地夹紧阳极31，第二电极夹34用于可拆卸地夹紧阴极32。通过第一电极夹33和第二电极夹34实现阳极31和阴极32的可拆卸安装，便于清洗、更换和维修。Optionally, please refer to Figures 2 to 5 together, the electrode assembly further includes a first electrode clamp 33 and a second electrode clamp 34, both of which are installed in the chamber 11, the first electrode clamp 33 is used to detachably clamp the anode 31, and the second electrode clamp 34 is used to detachably clamp the cathode 32. The detachable installation of the anode 31 and the cathode 32 is achieved by the first electrode clamp 33 and the second electrode clamp 34, which is convenient for cleaning, replacement and maintenance.
可以理解地，为了方便阳极31与电源的正极连接，以及阴极32与电源的负极连接，第一电极夹33和第二电极夹34分别安装于靠近电源的正极和负极的位置。一个实施例中，第一电极夹33和第二电极夹34分别安装于杯座12，阳极31和阴极32随着第一电极夹33和第二电极夹34安装于杯座12，即位于杯身13的底部，可以净化液位较低的水，提高具有掺硼金刚石阳极的净化水杯1的实用性。It can be understood that in order to facilitate the connection of the anode 31 with the positive electrode of the power supply and the cathode 32 with the negative electrode of the power supply, the first electrode clamp 33 and the second electrode clamp 34 are respectively installed at positions close to the positive electrode and the negative electrode of the power supply. In one embodiment, the first electrode clamp 33 and the second electrode clamp 34 are respectively installed on the cup holder 12, and the anode 31 and the cathode 32 are installed on the cup holder 12 along with the first electrode clamp 33 and the second electrode clamp 34, that is, located at the bottom of the cup body 13, which can purify water with a lower liquid level and improve the practicality of the purified water cup 1 with a boron-doped diamond anode.
可选地，第一电极夹33包括第一绝缘套和第一导体，第一绝缘套包裹于第一导体的外周，第一导体的两端分别裸露于第一绝缘套的外部，第一导体的一端与电源模块20的正极电连接，第一导体的另一端用于在第一绝缘套夹紧阳极31时与掺硼金刚石膜311电连接。Optionally, the first electrode clamp 33 includes a first insulating sleeve and a first conductor, the first insulating sleeve is wrapped around the outer circumference of the first conductor, both ends of the first conductor are respectively exposed outside the first insulating sleeve, one end of the first conductor is electrically connected to the positive pole of the power module 20, and the other end of the first conductor is used to electrically connect to the boron-doped diamond film 311 when the first insulating sleeve clamps the anode 31.
可选地，第二电极夹34包括第二绝缘套和第二导体，第二绝缘套包裹于第二导体的外周，第二导体的两端分别裸露于第二绝缘套的外部，第二导体的一端与电源模块20的负极电连接，第二导体的另一端用于在第二绝缘套夹紧阴极32时与阴极32电连接。Optionally, the second electrode clamp 34 includes a second insulating sleeve and a second conductor, the second insulating sleeve is wrapped around the outer circumference of the second conductor, both ends of the second conductor are respectively exposed outside the second insulating sleeve, one end of the second conductor is electrically connected to the negative pole of the power module 20, and the other end of the second conductor is used to be electrically connected to the cathode 32 when the second insulating sleeve clamps the cathode 32.
工作时，电源正极、第一导体、阳极31、液体、阴极32、第二导体、电源负极形成一个回路。During operation, the positive electrode of the power supply, the first conductor, the anode 31, the liquid, the cathode 32, the second conductor, and the negative electrode of the power supply form a loop.
第一导体和第二导体分别采用第一绝缘套和第二绝缘套进行包裹，避免电流从第一电极夹33和第二电极夹34的其它部位流出，增加了电源的损耗，也影响了阳极31的工作效率。The first conductor and the second conductor are respectively wrapped with the first insulating sleeve and the second insulating sleeve to prevent the current from flowing out from other parts of the first electrode clamp 33 and the second electrode clamp 34 , which increases the power loss and affects the working efficiency of the anode 31 .
一个实施例中，第一绝缘套和第二绝缘套分别构成第一夹体和第二夹体，第一夹体用于夹紧阳极31，第二夹体用于夹紧阴极32。In one embodiment, the first insulating sleeve and the second insulating sleeve constitute a first clamp and a second clamp respectively. The first clamp is used to clamp the anode 31 , and the second clamp is used to clamp the cathode 32 .
一个实施例中，如图2所示，电极组件还包括加热电极35，加热电极35安装于腔室11内，加热电极35的一端电连接电源模块20的正极，加热电极35的另一端电连接电源模块20的负极。加热电极35用于加热水，将水从常温升温至适宜饮用的温度，或者加热至沸点，进一步杀菌。In one embodiment, as shown in FIG2 , the electrode assembly further includes a heating electrode 35, which is installed in the chamber 11, one end of the heating electrode 35 is electrically connected to the positive electrode of the power module 20, and the other end of the heating electrode 35 is electrically connected to the negative electrode of the power module 20. The heating electrode 35 is used to heat water, raising the temperature of the water from room temperature to a temperature suitable for drinking, or heating it to boiling point for further sterilization.
一个实施例中，加热电极35的功率范围为50W-400W，电流范围5A-50A，能够在3-20min内将水从常温升至所需温度，并且使用安全，避免触电的问题。In one embodiment, the power range of the heating electrode 35 is 50W-400W, and the current range is 5A-50A. It can heat water from room temperature to the required temperature within 3-20 minutes, and is safe to use and avoids electric shock.
可选地，具有掺硼金刚石阳极的净化水杯1还包括过滤器40，过滤器40内设于杯口处，装入液体中，液体先通过过滤器40，然后再进入腔室11内，以去除液体中的颗粒杂质，如泥沙、落叶等。Optionally, the purified water cup 1 with a boron-doped diamond anode further includes a filter 40, which is disposed at the mouth of the cup and filled with liquid. The liquid first passes through the filter 40 and then enters the chamber 11 to remove particulate impurities in the liquid, such as mud, fallen leaves, etc.
可选地，过滤器40包括主体41和顶盖42，主体41中开设有置物腔，置物腔用于装载滤芯43，滤芯43如滤网、活性炭、无纺布等。较优地，主体41与顶盖42为可拆卸连接，便于装载和更换过滤材料。主体41与顶盖42可以通过卡扣的方式进行可拆卸连接，连接牢固，且拆卸方便。Optionally, the filter 40 includes a main body 41 and a top cover 42. The main body 41 is provided with a storage cavity for loading a filter element 43, such as a filter screen, activated carbon, non-woven fabric, etc. Preferably, the main body 41 and the top cover 42 are detachably connected to facilitate loading and replacement of filter materials. The main body 41 and the top cover 42 can be detachably connected by snapping, which is firmly connected and easy to disassemble.
本申请实施例的具有掺硼金刚石阳极的净化水杯1可以将过滤、电解有机物、杀菌和加热集合于一体，通过过滤器40和含有掺硼金刚石膜311的阳极31的双重作用将水处理成饮用水的标准，同时可以通过加热电极35的作用将水加热，当电池21电量不足时，可以通过光伏发电板23对电池21进行充电，对污水的过滤和净化效果良好，而且方便携带，实用性强。The purified water cup 1 with a boron-doped diamond anode in the embodiment of the present application can integrate filtration, electrolysis of organic matter, sterilization and heating into one, and treat water to the standard of drinking water through the dual effects of the filter 40 and the anode 31 containing the boron-doped diamond film 311. At the same time, the water can be heated by the heating electrode 35. When the battery 21 is low on power, the battery 21 can be charged by the photovoltaic panel 23. It has a good effect on filtering and purifying sewage, is easy to carry, and has strong practicality.
实施例1Example 1
如图1所示，本实施例的具有掺硼金刚石阳极的净化水杯1包括杯体10、电源模块20、电极组件及过滤器40。As shown in FIG. 1 , the purified water cup 1 with a boron-doped diamond anode of this embodiment includes a cup body 10 , a power module 20 , an electrode assembly and a filter 40 .
杯体10设有腔室11，杯体10包括底盖16、杯座12、杯身13和杯盖14；底盖16与杯座12通过螺丝连接，杯座12开设有容纳空间121；杯身13包括底部和杯口，杯座12螺接于杯身13的底部，杯盖14螺接于杯口的外周，杯座12和杯身13连接后共同构成腔室11。The cup body 10 is provided with a chamber 11, and the cup body 10 includes a bottom cover 16, a cup seat 12, a cup body 13 and a cup cover 14; the bottom cover 16 is connected to the cup seat 12 by screws, and the cup seat 12 is provided with a receiving space 121; the cup body 13 includes a bottom and a cup mouth, the cup seat 12 is screwed to the bottom of the cup body 13, and the cup cover 14 is screwed to the outer periphery of the cup mouth, and the cup seat 12 and the cup body 13 are connected to form a chamber 11 together.
电源模块20包括电池21、控制电路22和光伏发电板23，电池21和控制电路22安装于容纳空间121中，电池21与控制电路22电连接，光伏发电板23安装于杯身13的外表面；光伏功率为3W-300W，电流为0.6-60A，电压为5-36V。The power module 20 includes a battery 21, a control circuit 22 and a photovoltaic panel 23. The battery 21 and the control circuit 22 are installed in the accommodating space 121. The battery 21 is electrically connected to the control circuit 22. The photovoltaic panel 23 is installed on the outer surface of the cup body 13. The photovoltaic power is 3W-300W, the current is 0.6-60A, and the voltage is 5-36V.
电极组件包括阳极31、阴极32、第一电极夹33、第二电极夹34和加热电极35，阳极31和阴极32分别通过第一电极夹33和第二电极夹34安装于腔室11内，阳极31和阴极32相对设置，并且两者之间的距离为1-8cm；阳极31和阴极32分别与电池21的正极和负极电连接。The electrode assembly includes an anode 31, a cathode 32, a first electrode clamp 33, a second electrode clamp 34 and a heating electrode 35. The anode 31 and the cathode 32 are respectively installed in the chamber 11 through the first electrode clamp 33 and the second electrode clamp 34. The anode 31 and the cathode 32 are arranged opposite to each other, and the distance between the two is 1-8cm; the anode 31 and the cathode 32 are respectively electrically connected to the positive and negative electrodes of the battery 21.
阳极31包括极芯312和掺硼金刚石膜311，掺硼金刚石膜311包覆于极芯312的表面。极芯312为1-25cm2、10-300目的钛网，掺硼金刚石膜311中硼的掺杂量为1600-5800ppm。The anode 31 includes a core 312 and a boron-doped diamond film 311, and the boron-doped diamond film 311 is coated on the surface of the core 312. The core 312 is a titanium mesh of 1-25 cm2 and 10-300 meshes, and the boron doping amount in the boron-doped diamond film 311 is 1600-5800 ppm.
阴极32为1-25cm2纯钛片或不锈钢片。The cathode 32 is a 1-25 cm2 pure titanium sheet or a stainless steel sheet.
过滤器40包括主体41、顶盖42和滤芯43，主体41中开设有置物腔，顶盖42与主体41通过卡扣的方式连接，滤芯43装载于置物腔中，滤芯43为三层活性炭无纺布。过滤器40内设于杯口处，杯盖14连接杯身13后，杯盖14将过滤器40遮盖于杯口内。The filter 40 includes a main body 41, a top cover 42 and a filter element 43. The main body 41 is provided with a storage cavity. The top cover 42 is connected to the main body 41 by a buckle. The filter element 43 is loaded in the storage cavity. The filter element 43 is a three-layer activated carbon non-woven fabric. The filter 40 is arranged at the mouth of the cup. After the cup cover 14 is connected to the cup body 13, the cup cover 14 covers the filter 40 in the mouth of the cup.
实验1Experiment 1
本实验方法包括以下步骤：This experimental method includes the following steps:
S01：取水样100ml，将水样通过过滤器40进行过滤，进入具有掺硼金刚石阳极的净化水杯1的腔室11中。S01: Take 100 ml of water sample, filter the water sample through the filter 40, and let the water sample enter the chamber 11 of the purified water cup 1 with the boron-doped diamond anode.
S02：将阳极31裁成15cm2大小，掺硼金刚石膜311中硼的掺杂量为1600ppm，阴极32为不锈钢电极，阳极31和阴极32相对设置，阳极31与电池21的正极连接，阴极32与电池21的负极连接，工作电流密度为10-100mA/cm2。S02: The anode 31 is cut into a size of 15 cm2. The boron doping amount in the boron-doped diamond film 311 is 1600 ppm. The cathode 32 is a stainless steel electrode. The anode 31 and the cathode 32 are arranged opposite to each other. The anode 31 is connected to the positive electrode of the battery 21, and the cathode 32 is connected to the negative electrode of the battery 21. The working current density is 10-100 mA/cm2.
经过1小时的处理，水样的COD值（ChemicalOxygen Demand，化学需氧量）变化如表1所示。After 1 hour of treatment, the COD value (Chemical Oxygen Demand) of the water sample changed as shown in Table 1.
表1Table 1
经过本申请实施例具有掺硼金刚石阳极的净化水杯1的处理，水样的COD值从40降到约10，水质得到明显改善。After being treated by the purified water cup 1 with a boron-doped diamond anode according to the embodiment of the present application, the COD value of the water sample dropped from 40 to about 10, and the water quality was significantly improved.
实验2Experiment 2
本实验方法包括以下步骤：This experimental method includes the following steps:
S01：取饮用水300ml，将饮用水经过滤器进行过滤，倒入杯体的腔室中。S01: Take 300 ml of drinking water, filter the drinking water through a filter, and pour the drinking water into the chamber of the cup body.
S02：阳极的尺寸为1cm2，阴极为1cm2的不锈钢片，阳极和阴极相对设置，然后阳极和阴极分别与电池的正极和负极电连接，工作电流密度为50mA/cm2。S02: The size of the anode is 1 cm2 , and the cathode is a 1 cm2 stainless steel sheet. The anode and cathode are arranged opposite to each other, and then the anode and cathode are electrically connected to the positive and negative electrodes of the battery respectively. The working current density is 50 mA/cm2 .
实验结果为：1分钟之内杀菌率可以达到100%。The experimental results are: the sterilization rate can reach 100% within 1 minute.
实验3Experiment 3
本实验方法包括以下步骤：This experimental method includes the following steps:
S01：取重污染污水，将重污染污水经过滤器进行过滤，倒入杯体的腔室中；S01: Take the heavily polluted sewage, filter it through a filter, and pour it into the chamber of the cup;
S02：阳极为表面包覆掺硼金刚石镀膜的钛网，掺硼金刚石膜中硼的掺杂量为5800ppm，阴极为不锈钢，阳极和阴极相对设置，阳极和阴极分别与电池的正极和负极电连接，工作电流密度为30mA/cm2。S02: The anode is a titanium mesh coated with a boron-doped diamond film, the boron doping amount in the boron-doped diamond film is 5800ppm, the cathode is stainless steel, the anode and cathode are arranged oppositely, the anode and cathode are electrically connected to the positive and negative electrodes of the battery respectively, and the working current density is 30mA/cm2 .
经过1个小时的处理，水样的COD值的变化如表2所示。After 1 hour of treatment, the changes in COD values of the water samples are shown in Table 2.
表2Table 2
经过本申请实施例具有掺硼金刚石阳极的净化水杯1的处理，水样的COD值从1285mg/l降到100 mg/l附近，水质得到很大程度改善。After being treated by the purified water cup 1 with a boron-doped diamond anode according to the embodiment of the present application, the COD value of the water sample dropped from 1285 mg/l to around 100 mg/l, and the water quality was greatly improved.
实验3Experiment 3
本实验方法包括以下步骤：This experimental method includes the following steps:
S01：取水样100ml，将水样经过滤器进行过滤，倒入杯体的腔室中；S01: Take 100 ml of water sample, filter it through the filter, and pour it into the chamber of the cup;
S02：阳极为表面包覆掺硼金刚石镀膜的钛网，10cm2，掺硼金刚石膜中硼的掺杂量为3200ppm，阴极为不锈钢，阳极和阴极相对设置，阳极和阴极分别与电池的正极和负极电连接，工作电流密度为10-100mA/cm2。S02: The anode is a titanium mesh coated with boron-doped diamond film, 10 cm2 , the boron doping amount in the boron-doped diamond film is 3200ppm, the cathode is stainless steel, the anode and cathode are arranged opposite to each other, the anode and cathode are electrically connected to the positive and negative electrodes of the battery respectively, and the working current density is 10-100mA/cm2 .
经过1个小时的处理，水样的COD值的变化如表3所示。After 1 hour of treatment, the changes in COD values of the water samples are shown in Table 3.
表3table 3
经过本申请实施例具有掺硼金刚石阳极的净化水杯1的净化处理，水样的COD值从40降到10附近，水质得到明显改善。After being purified by the purified water cup 1 having a boron-doped diamond anode according to the embodiment of the present application, the COD value of the water sample dropped from 40 to around 10, and the water quality was significantly improved.
以上所述仅为本申请的较佳实施例而已，并不用以限制本申请，凡在本申请的精神和原则之内所作的任何修改、等同替换和改进等，均应包含在本申请的保护范围之内。The above description is only a preferred embodiment of the present application and is not intended to limit the present application. Any modifications, equivalent substitutions and improvements made within the spirit and principles of the present application should be included in the protection scope of the present application.
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211211729.4ACN115611375A (en) | 2022-09-30 | 2022-09-30 | Purified water cup with boron-doped diamond anode |
| CN202211211729.4 | 2022-09-30 |
| Publication Number | Publication Date |
|---|---|
| WO2024066046A1true WO2024066046A1 (en) | 2024-04-04 |
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN2022/137076CeasedWO2024066046A1 (en) | 2022-09-30 | 2022-12-06 | Purification water bottle having boron-doped diamond anode |
| Country | Link |
|---|---|
| CN (1) | CN115611375A (en) |
| WO (1) | WO2024066046A1 (en) |
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