Movatterモバイル変換


[0]ホーム

URL:


USRE40347E1 - Acceleration sensor and process for the production thereof - Google Patents

Acceleration sensor and process for the production thereof
Download PDF

Info

Publication number
USRE40347E1
USRE40347E1US10/123,220US12322002AUSRE40347EUS RE40347 E1USRE40347 E1US RE40347E1US 12322002 AUS12322002 AUS 12322002AUS RE40347 EUSRE40347 EUS RE40347E
Authority
US
United States
Prior art keywords
substrate
silicon substrate
layer
acceleration sensor
stationary
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US10/123,220
Inventor
Tetsuo Fujii
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denso Corp
Original Assignee
Denso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filedlitigationCriticalhttps://patents.darts-ip.com/?family=14473945&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=USRE40347(E1)"Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Denso CorpfiledCriticalDenso Corp
Priority to US10/123,220priorityCriticalpatent/USRE40347E1/en
Priority to US10/315,861prioritypatent/USRE40561E1/en
Priority to US10/315,859prioritypatent/USRE41213E1/en
Priority to US10/315,827prioritypatent/USRE42083E1/en
Priority to US10/315,566prioritypatent/USRE41047E1/en
Application grantedgrantedCritical
Publication of USRE40347E1publicationCriticalpatent/USRE40347E1/en
Anticipated expirationlegal-statusCritical
Expired - Lifetimelegal-statusCriticalCurrent

Links

Images

Classifications

Definitions

Landscapes

Abstract

A single crystal silicon substrate (1) is bonded through an SiO2film (9) to a single crystal silicon substrate (8), and the single crystal silicon substrate (1) is made into a thin film. A cantilever (13) is formed on the single crystal silicon substrate (1), and the thickness of the cantilever (13) in a direction parallel to the surface of the single crystal silicon substrate (1) is made smaller than the thickness of the cantilever in the direction of the depth of the single crystal silicon substrate (1), and movable in a direction parallel to the substrate surface. In addition, the surface of the cantilever (13) and the part of the single crystal silicon substrate (1), opposing the cantilever (13), are respectively, coated with an SiO2film (5), so that an electrode short circuit is prevented in a capacity-type sensor. In addition, a signal-processing circuit (10) is formed on the single crystal silicon substrate (1), so that signal processing is performed as the cantilever (13) moves.

Description

This application is a Re-Issue Application of U.S. Pat. No.6,227,049.
Notice: More than one reissue application has been filed for reissue of U.S. Pat. No.6,227,049. The reissue applications are application Ser. Nos.10/123,220 (the present application),10/315,566,10/315,859,10/315,827,10/315,861, all of which are Divisional reissues of U.S. Pat. No.6,227,049.
This is a continuation of application Ser. No. 08/167,976, filed on May 11, 1994, now abandoned.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to an acceleration sensor, and more specifically, a semiconductor type acceleration sensor suitable for a air-bag system, a suspension control system, or the like, for automobiles.
2. Description of the Related Art
In producing a semiconductor type acceleration sensor, the movable part thereof has hitherto been prepared in such a way that it penetrates a single crystal silicon wafer. Accordingly, the movable part must be sized so as to penetrate through the thickness of a wafer, and therefore, it has been difficult to miniaturize the acceleration sensor. In addition, in order to incorporate this sensor into a package, a relaxation part, have been required such as a pedestal, in order to release the stress caused by the difference in coefficients of thermal expansion or the like.
However, in Nikkei Electronics, Nov. 11, 1991 (No. 540), pp 223 to 231, there is illustrated an acceleration sensor produced by use of a surface micro-machining technique. According to this technique, a thin polysilicon film is laminated on a silicon substrate, and this polysilicon film is etched, whereby a beam movable parallel to the surface of the substrate is formed, so as to form a differential capacity type acceleration sensor. However, when a beam structure is formed by use of polysilicon, if a signal processing circuit is formed around the formed beam structure, the sensor characteristics become unstable. This is because the beam structure is formed of a polycrystalline and amorphous material, resulting in noticeable variation for every production lot. Accordingly, it is still desirable to form an acceleration sensor by surface micro-machining single crystal silicon.
Under such circumstances, the purpose of the present invention is to provide an acceleration sensor having a novel structure, by which high precision and high reliability can be realized.
In addition, another purpose of the present invention is to produce this acceleration sensor with a good yield rate during the production process thereof.
SUMMARY OF THE INVENTION
The gist of a first embodiment of the present invention resides in an acceleration sensor, comprising a second single crystal silicon substrate bonded onto a first single crystal silicon substrate with an insulating film interposed therebetween, the second single crystal silicon substrate being made of a thin film, a beam formed on at least either of said first and second single crystal silicon substrates and movable in a direction parallel to the surface thereof, and a signal-processing circuit formed on at least one of said first and second single crystal silicon substrates for performing processing of signals produced by a movement of beam, caused by an acceleration.
In addition, the gist of a second embodiment of the present invention resides in a process for producing an acceleration sensor, comprising: a first step of forming, on a main surface of a first single crystal silicon substrate, a groove with a predetermined depth for formulation of a beam; a second step of forming, on the main surface of said first single crystal silicon substrate, a film of a polycrystaline silicon, an amorphous silicon or a mixture thereof so as to fill said groove with said silicon film; a third step of bonding the main surface of said first single crystal silicon substrate to a second single crystal silicon substrate with an insulating film formed thereon, said insulating film being interposed between said first and second single crystal silicon substrates; a fourth step of polishing the reverse side of said first single crystal silicon substrate to a predetermined degree, so as to make said first single crystal silicon substrate a thin film; and a fifth step of forming a signal-processing circuit on at least either of said first and second single crystal silicon substrates, and thereafter, removing by etching said silicon film of a polycrystal silicon, an amorphous silicon or a mixture thereof from said reverse side of said first single crystal silicon substrates, to form a beam.
In addition, the gist of a third embodiment of the present invention residues in a process for producing an acceleration sensor, comprising: a first step of bonding a main surface of a first single crystal silicon substrate to a second single crystal silicon substrate with an insulating film formed thereon, said insulating film being interposed therebetween; a second step of polishing the reverse side of said first single crystal silicon substrate to a predetermined degree, so as to make the first single crystal silicon substrate a thin film; a third step of forming a groove with a predetermined depth for formulation of a beam; a fourth step of forming, on the reverse side of said first single crystal silicon substrate, a film of a polycrystal silicon, an amorphous silicon or a mixture thereof, so as to fill said groove with said silicon film, and smoothing the surface of said silicon film; and a fifth step of forming a signal-processing circuit on at least one of said first and second single crystal silicon substrates, and thereafter, removing by etching said film of polycrystal silicon, amorphous silicon or a mixture thereof from the reverse side of the first single crystal silicon substrate, to form a beam.
In the first embodiment, when an acceleration is applied in a direction parallel to the surface of the bonded single crystal silicon substrates, the beam formed on the first or second single crystal silicon substrate moves. As this beam moves, signal processing is performed in the signal-processing circuit formed on the first or second single crystal silicon substrate.
In the second embodiment, as a first step, a groove of a predetermined depth for formation of a beam is formed on the main surface of the first single crystal silicon substrate, and as a second step, a film of a polycrystalline silicon, an amorphous silicon or a mixture thereof is formed on the main surface of the first single crystal silicon substrate, whereby the groove is filled with the silicon film, and the surface of this silicon film is flattened. Subsequently, as a third step, the main surface of the first single crystal silicon substrate is bonded to a second single crystal silicon substrate having an insulating film formed thereon, said insulating film being interposed between the first and second single crystal substrates, and, as a fourth step, the reverse side of the first single crystal silicon substrate is polished to a predetermined degree, whereby the first single crystal silicon substrate is made into a thin film. Subsequently, as a fifth step, a signal-processing circuit is formed on the first or second single crystal silicon substrate, thereafter the polycrystalline, amorphous or mixed silicon film is removed by etching from the reverse side of the first single crystal silicon substrate, and a beam is formed. As a result, an acceleration sensor according to the first invention is produced.
In the third embodiment, as a first step, the main surface of a first single crystal substrate is bonded to a second single crystal silicon substrate with an insulating film formed thereon, said insulating film being interposed between the first and second substrates, and as a second step, the reverse side of the first single crystal silicon substrate is polished to a predetermined degree, so that the first single crystal silicon substrate is made into a thin film. Subsequently, as a third step, a groove of a predetermined depth for formation of a beam is formed on the reverse side of the first single crystal silicon substrate, and as a fourth step, a film of polycrystalline silicon, an amorphous silicon or a mixture thereof is formed on the reverse side of the first single crystal silicon substrate, whereupon the groove is filled with the silicon film, and the surface of the silicon film is flattened. Subsequently, as a fifth step, a signal-processing circuit is formed on the first or second single crystal silicon substrate, whereafter the polycrystalline, amorphous or mixed silicon film is removed by etching from the reverse side of the first single crystal silicon substrate, and a beam is formed. As a result, an acceleration sensor according to the first embodiment is produced.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a plan of an acceleration sensor according to the first embodiment of the present invention;
FIG. 2 is a cross section taken alongline22 inFIG. 1;
FIGS. 3 to10 are illustrations for explanation of the manufacturing process of the first embodiment, and, respectively, a sectional view for each production stage;
FIG. 11 is a plan illustrating an application example of the first embodiment;
FIG. 12 is a sectional view taken along theline1212 inFIG. 11;
FIGS. 13 to21 are illustrations for explanation of the manufacturing process of the second embodiment, and, respectively, a sectional view for each production stage;
FIGS. 22 to28 are illustrations for explanation of the manufacturing process of the third embodiment, and, respectively, a sectional view for each production stage;
FIGS. 29 to31 are illustrations for explanation of the manufacturing process of the fourth embodiment, and, respectively, a sectional view for each production stage;
FIGS. 32 to34 are illustrations for explanation of the manufacturing process examples to which the fourth embodiment is applied, and, respectively, a sectional view for each production stage;
FIG. 35 is a plan illustrating an example of a sensor tip formed by an acceleration sensor according to the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS OF THE INVENTION
In the following, the embodiments and realizations of the present invention, will be explained with reference to the attached drawings.
First Embodiment
FIG. 1 is a plain view plan of an acceleration sensor produced by the first embodiment of the present invention, andFIG. 2 is a sectional view taken alongline22 in part and the signal-processing circuit are formed of the same single crystal silicon substrate.
The present acceleration sensor is a capacity type acceleration sensor. As illustrated inFIG. 2, there is bonded onto a single crystal silicon substrate8 a singlecrystal silicon substrate1 through an SiO2film9, and in the singlecrystal silicon substrate1, there is formed acantilever13 by atrench3 penetrating saidsubstrate1. As illustrated inFIG. 1, thiscantilever13 has a structure such that an end side thereof is branched into two parts. Thecantilever13 can be moved in a direction parallel to the surface of the single crystal silicon substrate1 (the arrow direction C in FIG.1). In addition, in the singlecrystal silicon substrate1, a signal-processing circuit10 is formed and is electrically insulated from thecantilever13 by apolysilicon film6 and an SiO2film5.
In the following, the production precess of the first embodiment of the present invention, which is suitable for the production of the aforesaid structure, will be explained with reference toFIGS. 3 to10.
First, as illustrated inFIG. 3, an n-type (100) singlecrystal silicon substrate1 with a resistance of 1 to 20Ω-cm is provided, and on the main surface thereof, there is formed an SiO2film2 with a thickness of about 1 μm by thermal oxidation, and the SiO2film2 is formed into a predetermined pattern by a photolithographic method. This pattern is a pattern exposing, on the main surface of the silicon substrate, an area to be formed as a groove separating at least an area to be formed as a movable electrode (cantilever) from the substrate, and in the present embodiment, this pattern is formed as a pattern exposing also the main surface of the silicon substrate in an area for transversely insulating and separating the signal-processing circuit. Subsequently, on the main surface side of the singlecrystal silicon substrate1, there is formed atrench3 having a perpendicular wall with a predetermined depth, e.g. ranging from about 0.2 to about 30 μm. In the present embodiment, explanation will be made with respect to the case where the wall thickness is about 3 μm.
Substantially, after the SiO2film2 has been removed, as illustrated inFIG. 4, an n+ diffusedlayer4 formed using phosphorus, arsenic or the like is formed on the main surface of the singlecrystal silicon substrate1, including the internal wall of thetrench3, and further, an SiO2film5 with a thickness ranging from 0.1 to 1 μm is formed by thermal oxidation or the like. In this case, in order to prevent damage by etching, there may be conducted the so-called “sacrifice oxidation” in which SiO2is formed by thermal oxidation and removed before formulation of the n+ diffusedlayer4.
Substantially, as illustrated inFIG. 5, apolysilicon film6 is formed on the main surface of the singlecrystal silicon substrate1, and thetrench3 is filled with thepolysilicon film6. In addition, in the case where an impurity is introduced into thepolysilicon film6 in order to use thepolysilicon film6 as a conductive path, forming a thin polysilicon layer and diffusing phosphorus or the like in a high concentration before formation of thepolysilicon film6, allows the impurity to be introduced into thepolysilicon film6.
Next, as illustrated inFIG. 6, the surface of thepolysilicon film6 is mirror finished, so as to make the thickness of the polysilicon film6 a predetermined value. Subsequently, boron ions or other impurity are implanted into thepolysilicon film6 to form p+ diffusedlayers7 in predetermined areas.
On the other hand, as illustrated inFIG. 7, another (100) singlecrystal silicon substrate8 is provided, and an SiO2film9 with a thickness ranging from 0.1 to 1.0 μm is formed on the main surface of thesilicon substrate8.
Subsequently, the singlecrystal silicon substrate1 and the singlecrystal silicon substrate8 are dipped into e.g. an aqueous mixed solution of aqueous hydrogen peroxide and sulfuric acid, so as to subject these substrates to a hydrophilicity-imparting treatment. Thereafter, these substrates are dried, and as illustrated inFIG. 8, the main surface of the singlecrystal silicon substrate1 and that of the singlecrystal silicon substrate8 are put together at room temperature, and these substrates are introduced into a furnace at 400 to 1100° C. for a period of time ranging from 0.5 to 2 hours, so as to strongly bond them.
Subsequently, as illustrated inFIG. 9, by use of an aqueous solution of an alkali type, e.g. an aqueous KOH solution or the like, the reverse side of the singlecrystal silicon substrate1 is subjected to selective polishing. The polishing is continued until the SiO2film5 is exposed. As a result, the thickness of the singlecrystal silicon substrate1 reaches a value which is approximately determined by the depth of the trench, e.g. about 3 μm, so that thesubstrate1 is made thin.
Subsequently, as illustrated inFIG. 10, in a predetermined area of the singlecrystal silicon substrate1, there is formed a signal-processing circuit10 (IC circuit portion) by use of an ordinary CMOS process, bipolar process or the like. In addition, a diffused layer for connecting to wiring and a metallic electrode film composed of an aluminum film or the like are formed, and wiring at the sensor part, wiring at the circuit part, and connection of the sensor part to the circuit part are performed. In FIG.1 andFIG. 10, a MOS transistor alone is illustrated as a part of the signal-processing circuit10.
Further, on the upper surface of the signal-processing circuit10, there is formed, as apassivation film11, a plasma SiN film (P-SiN) e.g. by a plasma CD method. Subsequently, at the sensor part side,windows12 are opened at predetermined areas of thepassivation film11; and thepolysilicon film6 filled in thetrench3 is exposed from the surface. By this window opening procedure, the single crystal portions where a cantilever or fixed electrodes are to be formed are demarcated from the polycrystal portions embedded in the trench, on the surface of the substrate.
Subsequently, as illustrated inFIG. 2, by use of a 20% solution of TMAH (tetramethylammonium hydroxide) (CH3)4NOH, thepolysilicon film6 is removed by etching through thewindows12 of thepassivation film11, from the reverse side (the upper side inFIG. 2) of the singlecrystalline silicon substrate1. In this case, the passivation film11 (P-SiN), SiO2film5, aluminum wiring layer and p+ diffused layer (p+ polysilicon film)7 are hardly etched by the selective etching. Accordingly, the bonding of the single crystal silicon substrate to the lower singlecrystal silicon substrate8 is secured through the p+ diffused layer (p+ polysilicon film)7.
In addition, iftrenches3 are preliminary formed also in the wide area of thecantilever13 inFIG. 1, and etching windows48 are provided simultaneously with the formulation of thewindows12, in such a way that the etching windows48 communicate with saidtrenches3, thepolysilicon film6 below the movable part (cantilever13) of the sensor can be more securely removed by etching through this etching window48 when thepolysilicon film6 is removed by etching.
By the aforesaid procedures, thecantilever13 is formed. In this case, thecantilever13 becomes, as illustrated inFIG. 2, smaller in the thickness L2 in a direction parallel to the surface of the singlecrystal silicon substrate1 than in the thickness L1 in a direction along the depth of the singlecrystal silicon substrate1.
In a capacity type acceleration sensor, the end portions (bifurcated portions) of thecantilever13 are formed as movable electrodes, and as illustrated inFIG. 1, the parts of the singlecrystal silicon substrate1, opposing the end portions of thecantilever13, are formed as fixedelectrodes14,15,16, and17, respectively. In addition, as illustrated inFIG. 1, fixedelectrode14 and fixedelectrode16 are derived through analuminum wiring layer18a, fixedelectrode15 and fixedelectrode17 are derived through analuminum wiring layer18b, and the cantilever13 (movable electrode) is derived through analuminum wiring layer18c. Thesealuminum wiring layers18a,18b, and18c are connected to the signal-processing circuit10, and by this signal-processing circuit10, signal processing is conducted as the cantilever (movable electrode)13 is displaced owning to an acceleration. In addition, by the n+ diffused layers4 (seeFIG. 2) disposed on the cantilevers13 (movable electrodes) and fixedelectrodes14,15,16, and17, the electric potential is maintained at a constant value.
Although a capacity type acceleration sensor is made in the present embodiment, if a piezo resistance layer is formed at the surface of the root portion of thecantilever13, a piezo resistance type acceleration sensor can be formed. As a matter of course, if these two types of sensors are formed in a one and same substrate, the precision and reliability of the acceleration sensor can further be improved.
In the acceleration sensor thus produced, the singlecrystal silicon substrate1 is bonded through an SiO2film to the singlecrystal silicon substrate8, so as to form an SOI structure. In addition, in thecantilever13, its thickness L2 in a direction parallel to the surface of the singlecrystal silicon substrate1 is smaller than the thickness L1 in a direction of the depth of the singlecrystal silicon substrate1. Accordingly, thecantilever13 becomes movable, on the surface of the singlecrystal silicon substrate1, in a direction parallel to the surface, whereby an acceleration to a direction parallel to the substrate surface is detected.
As mentioned in the foregoing, in the present embodiment, on the main surface of the singlecrystal silicon surface1, there is formed a trench (groove)3 of a predetermined depth for formulation of the cantilever13 (the first step), and thepolysilicon film6 is formed on the main surface of the singlecrystal silicon substrate1, so as to fill thetrench3 with saidpolysilicon film6, and the surface of thepolysilicon film6 is flattened (smoothed) (the second step). Subsequently, the main surface of the singlecrystal silicon substrate1 is bonded to the singlecrystal silicon substrate8 with an SiO2film9 (insulating film) formed thereon, through said SiO2film9 being interposed between thesubstrates1 and8 (the third step), whereafter the reverse side of the singlecrystal silicon substrate1 is polished to a predetermined degree, so as to make the single crystalline silicon substrate into a thin film (the fourth step). Subsequently, the signal-processing circuit10 is formed on the surface of the single crystal silicon substrate, whereafter thepolysilicon film6 is removed by etching from the reverse side of the single crystal silicon substrate, so as to form the cantilever13 (the fifth step).
Accordingly, during the process for the formation of the signal-processing circuit10, in the course of the wafer process, thetrench3 in the surface portion of the single crystal silicon substrate, is filled with thepolysilicon film6, whereby contamination of the IC elements, contamination of production equipment, and degradation or deterioration of electrical properties accompanied therewith can be prevented. That is, in the wafer process, by contriving to prevent the surface structures such as concave portions or penetration holes from appearing on the wafer surface in the heat treatment, photolithographic treatment and the like, in the course of the process, it is possible to prevent contamination and the like, and to thereby stably provide acceleration sensors of high precision.
The thus produced acceleration sensor comprises the singlecrystal silicon substrate1, which is bonded through an SiO2film (insulating film) to the singlecrystal silicon substrate8, and which is made a thin film; thecantilever13, which is formed on said singlecrystal silicon substrate1 and which is movable in a direction parallel to the surface of the substrate; and the signal-processing circuit10, which is also formed on the singlecrystal silicon substrate1 and which performs signal processing as thecantilever13 moves owing to an acceleration. When an acceleration is applied in a direction parallel to the surface of the singlecrystal silicon substrate1, the cantilever formed on the singlecrystal silicon substrate1 moves. As thecantilever13 moves, signal-processing is performed by the signal-processing circuit10 formed on the singlecrystal silicon substrate1. In such a way as above, by a micro-machining technique using single crystal silicon, an acceleration sensor is formed, by the novel structure of which high precision and high reliability can be realized.
In addition, since the surface of theaforesaid cantilever13 and the part of the singlecrystal silicon substrate1, opposing saidcantilever13, are coated with the SiO2film (insulator)5, electrode short-circuit in the capacity type acceleration sensor can previously be prevented. In addition, it suffices if at least either of the surface of thecantilever13 or the part of the singlecrystal silicon substrate1 opposing thecantilever13 is coated with the SiO2film (insulator)5.
Further, as an application of the present embodiment, as illustrated inFIGS. 11 and 12, the cantilever may be separated from the signal-processing circuit (IC circuit portion)10 and an air bridge wiring is formed, in order to reduce parasitic capacity. In addition, the fixedelectrodes14,15,16, and17 may be formed so as to have the same structure as above. This can be realized by forming a p+type polysilicon film7 at the minimum position necessary for bonding the fixed electrodes to the lower substrate.
In addition, although an aluminum wiring layer is used in the aforesaid embodiment, the wiring part may be formed by use of a polysilicon layer. Further, although two movable electrodes are formed at the end of the beam and simultaneously, four fixedelectrodes14,15,16, and17 are formed, in the aforesaid embodiment, the movable and fixed electrodes may be formed like the teeth of a comb in order to further improve the sensitivity of the sensor.
In addition, an oxide film may selectively be formed, instead of the formulation of the p+ polysilicon film7.
Second Embodiment
Next, there will be made explanations about the production process of the second embodiment, emphasizing the points that are different from those in the first embodiment. In addition, in the second embodiment to be hereafter explained, explanations will be made by way of an example of a case where a sensor having a structure according to the structure illustrated inFIGS. 1 and 2, as explained in the aforesaid first embodiment, and there will be illustrated a sectional view corresponding to the22 section of FIG.1.
In the aforesaid first embodiment, in order to form thecantilever13, the p+ diffused layer (p+ polysilicon film)7 is formed for the purpose of separating the cantilever portion from the single crystal silicon substrate at a predetermined distance, but in second present embodiment, a concave portion is formed before formation of a trench, for the purpose of separating the cantilever from the substrate at a predetermined distance.
InFIGS. 13 to21, the production process is illustrated.
First, as illustrated inFIG. 13, an n type (100) singlecrystal silicon substrate20 is provided, and on the main surface of the provided singlecrystal silicon substrate20, there is formed aconcave portion21 with a predetermined depth e.g. ranging from 0.1 to 5 μm. Subsequently, as illustrated inFIG. 14, on the main surface of the singlecrystal silicon substrate20, there is formed an SiO2film22, and a pattern is formed by a photolithographic means, in the same way as in the aforesaid first embodiment. Subsequently, on the main surface of the singlecrystal silicon substrate20 including the bottom of theconcave portion21, there is formed a trench with a depth ranging from about 0.1 to about 30 μm (3 μm in the present embodiment) by dry etching or the like.
Subsequently, as illustrated inFIG. 15, on the main surface of the singlecrystal silicon substrate20 including the internal wall of thetrench23, there is formed an n+ diffusedlayer24, and an SiO2film25 is formed by thermal oxidation. Thereafter, as illustrated inFIG. 16, apolysilicon film26 is deposited in thetrench23 by the LPCVD method.
Subsequently, as illustrated inFIG. 17, the surface of thepolysilicon film26 is polished by use of the SiO2film as an etching stopper, so as to smooth the surface. In the above case, although it is desirable that the surfaces of thepolysilicon film26 and the SiO2film25 become smooth, even if thepolysilicon film26 is rather indented, so long as the surface of the SiO2film is made smooth, no inconvenience is caused in the subsequent wafer cementing.
On the other hand, as illustrated inFIG. 18, another (100) singlecrystal silicon substrate27 is provided, and, on the main surface of thesubstrate27, there is formed an SiO2film with a thickness ranging from 0.1 to 1.0 μm by thermal oxidation of the substrate. Subsequently, singlecrystal silicon substrates20 and27 are dipped in e.g. a solution of an aqueous hydrogen per oxide and sulfuric acid, so as to subject them to a hydrophilicity-imparting treatment. Subsequently, the substrates are dried, and thereafter, the main surfaces of the two singlecrystal silicon substrates20 and27 are put together at room temperature, and introduced into a furnace at 400 to 1100° C. for a period of time ranging from 0.5 and 2 hours, so as to strongly bond the two surfaces.
Subsequently, as illustrated inFIG. 19, the reverse side of the singlecrystal silicon substrate20 is subjected to selective polishing by use of an aqueous solution of alkali type, e.g. an aqueous KOH solution. The selective polishing is performed until the SiO2film25 appears on the surface. As a result, the thickness of the singlecrystal silicon substrate20 becomes e.g. about 3 μm, so as to be made a thin film.
Subsequently, as illustrated inFIG. 20, a signal-processing circuit (IC circuit portion)10 is formed through an ordinary CMOS process, bipolar process, or the like. Further, on the upper surface of the signal-processing circuit10, there is formed, as apassivation film11, a plasma SiN film (P-SiN film) by e.g. plasma CVD method. Subsequently,windows12 are opened at predetermined areas of thepassivation film11, and thepolysilicon film20 is exposed to the surface at the sensor portion.
Subsequently, as illustrated inFIG. 21, by use of a 20% solution of TMAH (tetramethylammonium hydroxide) (CH3)4NOH, thepolysilicon film26 is removed by etching from the reverse side of the singlecrystal silicon substrate20 through thewindows12 on thepassivation film11. In the above case, the passivation film11 (P-SiN), SiO2film, and aluminum wiring layer are hardly etched by the selective etching.
As a result, acantilever13 is formed.
Also by the present embodiment, there is obtained the same effect as in the aforesaid first embodiment.
Third Embodiment
Next, there will be made explanations about the production process in the third embodiment, laying stress on the differential points between the first and third embodiments.
Although, in the aforesaid first and second embodiments, the trench is filled with polysilicon before the bonding of the wafers, in the present embodiment, the trench is filled with polysilicon after the bonding of wafers, and in the final stage, the thus filled polysilicon is removed, so as to produce an acceleration sensor.
InFIGS. 22 to28, the production process is illustrated.
First, as illustrated inFIG. 22, an n-type (100) singlecrystal silicon substrate30 is provided, and on the main surface of the provided singlecrystal silicon substrate30, there is formed aconcave portion31 in a depth ranging from 0.1 to 5 μm, in the same way as in the aforesaid second embodiment. On the other hand, as illustrated inFIG. 23, a singlecrystal silicon substrate32 is provided, and an SiO2film is formed by thermal oxidation on the main surface of the singlecrystal silicon substrate31. Thereafter, the main surface of the singlecrystal silicon substrate30 is bonded to the main surface of a singlecrystal silicon substrate32.
Subsequently, as illustrated inFIG. 24, the reverse side of the singlecrystal silicon substrate30 is subjected to mirror polishing to a predetermined thickness (0.1 to 30 μm). Thereafter, as illustrated inFIG. 25, there is formed an SiO2film34 to a thickness ranging from 0.1 to 2 μm, following which the SiO2film is subjected to patterning, and atrench35 is formed by etching. Thereby, acantilever13 and a transversal insulatedly separated area of the processing circuit portion are formed.
Next, by thermal diffusion or the like, there is introduced an N type impurity of arsenic or phosphorus in a high concentration, and a highly concentrated n+ layer36 is formed in the silicon area which is not covered with SiO2films33 and34.
Subsequently, as illustrated inFIG. 26, a thermal oxidation film is formed on the side wall of thetrench35 and the like, whereafter apolysilicon film37 is formed on the surface of the singlecrystal silicon substrate30, and thetrench35 is filled with thepolysilicon film37. Thereafter, as illustrated inFIG. 27, the surface of thepolysilicon film37 is selectively polished and smoothed until the SiO2film34 appears on the surface. Further, as illustrated inFIG. 28, a signal-processing circuit10 is formed, and finally, thepolysilicon film37 is removed by etching from the reverse side (upper surface side) of the singlecrystal silicon substrate30, so as to again separate thecantilever13 from the substrate to allow it to move.
As described above, in the present third embodiment, the main surface of the singlecrystal silicon substrate30 is bonded to the singlecrystal silicon substrate32 with the SiO2film (insulating film)33 formed thereon, through said SiO2film33 being interposed between thesubstrate30 and32 (first step), and the reverse side of the single crystal silicon substrate is polished to a predetermined degree, so as to make the single crystal silicon substrate30 a thin film (second step). Subsequently, on the reverse side of the singlecrystal silicon substrate30, there is formed a trench (groove)35 with a predetermined depth for formation of a cantilever13 (third step), and thetrench35 is filled with thepolysilicon film37, and the surface of thepolysilicon film37 is smoothed (fourth step). Subsequently, a signal-processing circuit is formed on the singlecrystal silicon substrate30, whereafter thepolysilicon film37 is removed, by etching, from the reverse side of the singlecrystal silicon substrate30, so as to form a cantilever13 (fifth step).
Therefore, in the process of formation of the signal-processing circuit10 in the wafer, thetrench35 is filled with thepolysilicon film37 in the upper surface part of the singlecrystal silicon substrate30, whereby contamination of the IC elements, contamination of the production apparatus, and degradation or deterioration of electrical properties attended therewith can be prevented. That is, by contriving not to make a surface structure such as a concave portion or a perforation of the like appear on the wafer surface in the heat treatment, the photolithographical treatment or the like in the course of the wafer process, contamination and the like can be prevented, so as to stabilize the wafer process, and a stable supply of acceleration sensors, of high precision, can be produced.
Fourth Embodiment
In the following, there will be made explanations about the production process of the fourth embodiment, laying stress on the differences between the present embodiment and the third embodiment.
The present embodiment is intended to produce an acceleration sensor at a lower cost than the production process of the third embodiment.
InFIGS. 29 to31, the production process is illustrated.
First, as illustrated inFIG. 29, an SiO2film with a thickness ranging from 0.1 to 2 μm is formed on the main surface of a singlecrystal silicon substrate40, and a singlecrystal silicon substrate42 is bonded to thesubstrate40 so as to interpose the SiO2film41 between thesubstrates40 and42. Subsequently, as illustrated inFIG. 30, the upper surface of the singlecrystal silicon substrate42 is polished so as to make the thickness of the single crystal silicon substrate a predetermined value. That is, the thickness of the singlecrystal silicon substrate42 is reduced to e.g. about 3 μm. Thereafter, a highly concentrated n+ diffusedlayer43 is formed on the upper surface of the singlecrystal silicon substrate42, and further, an SiO2film44 is formed thereon. It suffices if this highly concentrated n+ diffusedlayer43 is formed corresponding to the parts of the sensor which will be formed as movable electrodes and fixed electrodes.
Subsequently, as illustrated inFIG. 31, patterning is applied to an SiO2film, as in the third embodiment, and atrench45 is formed on the singlecrystal silicon substrate42. Thereafter, theSiO2 film41 below thistrench45 is partly removed by etching with an aqueous hydrofluoric acid solution. In this case, a part of SiO2film41, below the part to be formed as acantilever13, is completely removed, and another part of the SiO2film41, below the part to be formed as solid electrodes and signal-processing circuit portion, is left. Because the lower portion of the part is to be formed as thecantilever13 it is narrower than with the other part. In addition, in the above case, the highly concentrated n+ diffusedlayer43 is separated into thecantilever13 and fixed electrodes.
Subsequently, through the same processes as illustrated inFIGS. 26 to28, there is produced a capacity type acceleration sensor.
In the following, there will be explained application examples of the fourth embodiment with reference toFIGS. 32 to34.
First, as illustrated inFIG. 32, an SiO2film with a thickness ranging from 0.1 to 2 μm is formed on the main surface of the singlecrystal silicon substrate40, and aconcave portion47 with a depth ranging from 0.1 to 3 μm is formed at the area of the main surface of the singlecrystal silicon substrate42, on which area a cantilever is to be formed. Subsequently, the main surface of the singlecrystal silicon substrate42 is bonded to the main surface of the singlecrystal silicon substrate40, the SiO2film41 being put therebetween. Further, as illustrated inFIG. 33, the upper surface of the singlecrystal silicon substrate42 is polished so as to give the single crystal silicon substrate42 a predetermined thickness. That is, the thickness of the singlecrystal silicon substrate42 is made thin to a value of about 3 μm. Subsequently, the aforesaid highly concentrated diffusedlayer43 is formed on the upper surface of the singlecrystal silicon substrate42, and an SiO2film44 is formed thereon.
Subsequently, as illustrated inFIG. 34, onto the singlecrystal silicon substrate42, there are formedtrenches45 extending to theconcave portions47, and cantilevers13 are formed.
Thereafter, a capacity type acceleration sensor is produced through the same processes as illustrated inFIGS. 26 to28.
By conducting the aforesaid procedures, electrical insulation can be made more securely as compared with the case where the SiO2film41 is partly removed by etching. In addition, the mechanical strength of the sensor can be improved.
In addition, the present invention is not restricted to the aforesaid embodiments, and is applicable to a twin-lever spring or a polyever spring embodiment, in addition to a cantilever spring embodiment.
In addition, as illustrated inFIG. 35, it is possible to form twoacceleration sensors13a and13b onto a singlecrystal silicon substrate50, for detecting the acceleration in the direction X by theacceleration sensor13a, and the acceleration in the direction Y by theacceleration sensor13b. Further, it is possible to form an acceleration sensor capable of detecting the acceleration in a direction surface perpendicular to these X and Ydirection acceleration sensors13a and13b, on the same substrate, so as to detect an acceleration in three-dimensionals. In addition, when the present acceleration sensor is used as a capacity type acceleration sensor, it is possible to further stabilize the properties by forming the present acceleration sensor into a so-called “servo type” sensor (with a closed-loop circuit).
In addition, in the aforesaid embodiments, the trenches (grooves)3,23, and35 are filled withpolysilicon films6,26, and37, respectively, but there may be used a film of polysilicon, amorphous silicon or a mixed silicon containing polysilicon and amorphous silicon.
In addition, in the aforesaid embodiments, a sensor portion and a signal-processing portion are formed in the single crystal silicon substrate to be formed as the upper side, but the present acceleration sensor is not restricted to such a structure, and it is possible to utilize also a single crystal silicon substrate formed as a base, and form a sensor portion and a signal-processing portion on the lower substrate.
As described in detail in the foregoing, according to the present invention, high precision and high reliability can be realized by formatting a novel structure. In addition, when a signal-processing circuit is provided on the same chip as a movable beam, since there is produced neither a hollow part nor a groove during the production process, it is possible to make the processing stable. In addition, it is at the final step that the movable beam is made movable with respect to the substrate, whereby, in the case of the movable beam being bonded to the lower substrate to be formed as a pedestal or in the case of a circuit being formed, or the like, minute beams can be prevented from being broken, and the yield thereof can be made higher. In addition, since it is a micro-machining technique which determines the shape of the present acceleration sensor, the present acceleration sensor can be produced with high precision.
[Industrial Availability]
As described in the foregoing, the present invention is useful for the production of a semi-conductor acceleration sensor having minute movable parts, and the present acceleration sensor is suitable as an acceleration sensor to be used for air bag system, suspension control system and the like of automobiles. In addition, the present invention can be applied to a capacity type acceleration sensor for detecting acceleration in multiple directions.

Claims (33)

1. An acceleration sensor comprising:
a first substrate formed of a silicon material which is used as a conductive material;
a second substrate provided on the lower side of said first substrate and electrically insulated from the first substrate;
said first substrate including:
a support beam having a mass portion forming capacitive electrodes for displacement in a parallel direction to a surface of said second substrate according to the degree of acceleration, a fixed portion for fixing said support beam to said second substrate and a support portion for intermediately supporting said mass portion to said fixed portion,
an insulating groove extending through a thickness of said first substrate around the entire periphery of said support beam, and stationary blocks forming capacitive electrodes defined by said insulating groove on the outer sides of said support beam separately across said insulating groove and fixed to said second substrate; and
gap means forming a gap space in order to space said mass portion and said supporting portion from a surface of said second substrate; and
said second substrate being separated from said first substrate by an insulating layer which is at least provided on the lower side of said fixed portion and stationary blocks.
8. An acceleration sensor comprising:
a substrate which is selected from the group consisting of an insulating material and oxidized semiconductor material;
a support beam which includes a mass portion forming a predetermined mass and first capacitive electrodes on side surfaces of said mass portion, a fixed portion for fixing said support beam to said substrate and thin support portion for intermediately connecting between said mass portion and said fixed portion;
a pair of stationary blocks arranged on both sides of said support beam separately across an air gap and fixed to said substrate, said stationary blocks provided with second capacitive electrodes on the opposite sides of first capacitive electrodes of said mass portion;
gap means forming a gap space in order to space said mass portion and thin support portion from a surface of said substrate; and
said mass portion being displace in a parallel direction to the surface of said substrate according to the degree of acceleration and said support beam and stationary blocks formed of a silicon material which is used as a conductive material and electrically insulated from said substrate.
14. An acceleration sensor comprising:
A. a first single crystalline silicon substrate having a first surface and a second surface opposite said first surface;
B. a second single crystalline silicon substrate connected to a side of said first surface of said first single crystalline silicon substrate with an insulating layer interposed therebetween:
C. said first single crystalline silicon substrate including:
i. a movable beam defined by a trench which is disposed to surround said movable beam and extend from said second surface to said first surface, said movable beam being supported by said second single crystalline silicon substrate through said insulating layer to be displaceable in a direction parallel to said first surface of said first single crystalline silicon substrate,
ii. a stationary block disposed to be spaced apart from said movable beam via said trench, facing said movable beam to form a pair of capacitive electrodes with said movable beam, and fixed to said second single crystalline silicon substrate; and
D. a signal-processing circuit element for carrying out a processing operation based on a change of a capacitance between said capacitive electrodes.
20. An acceleration sensor comprising:
A. a first single crystalline silicon substrate having a first surface and a second surface opposite said first surface;
B. a second single crystalline silicon substrate connected to a side of said first surface of said first single crystalline silicon substrate with an insulating layer interposed therebetween:
C. said first single crystalline silicon substrate being divided by a trench extending from said second surface to said first surface;
i. a movable beam portion surrounded by said trench, said movable beam portion being supported by said second single crystalline silicon substrate through said insulating layer to be displaceable in a direction parallel to said first surface of said first single crystalline silicon substrate, said movable beam portion having a movable electrode,
ii. a stationary portion disposed to be spaced apart from said movable beam via said trench, having a stationary electrode which faces said movable beam via said trench to form a pair of capacitive electrodes with said movable electrode, and fixed to said second single crystalline silicon substrate; and
D. an insulator covering at least one of a surface of said movable electrode and a surface of said stationary electrode.
22. A semiconductor capacitor-type sensor comprising:
a first layer formed of a silicon material which is used as a conductive material, a second layer provided under said first layer;
said first layer including:
a support beam having a mass portion forming capacitive electrodes for displacement in a substantially parallel direction to a surface of said second layer according to the degree of mechanical force, a fixed portion for fixing said support beam to said second layer and a support portion for intermediately supporting said mass portion to said fixed portion;
an insulating groove extending through a thickness of said first layer around said support beam;
a stationary block forming capacitive electrodes defined by said insulating groove and fixed to said second layer; and
wiring layers formed on said stationary block and said support beam; wherein
said second layer is separated from said first layer by an insulating layer; and
said wiring layers have an air bridge structure over said insulating groove.
33. A semiconductor capacitor-type sensor comprising:
a first layer formed of a silicon material which is used as a conductive material, a second layer provided under said first layer;
said first layer including:
a support beam having a mass portion forming capacitive electrodes for displacement in a substantially parallel direction to a surface of said second layer according to the degree of mechanical force, a fixed portion for fixing said support beam to said second layer and a support portion for intermediately supporting said mass portion to said fixed portion;
an insulating groove extending through a thickness of said first layer around said support beam;
a stationary block forming capacitive electrodes defined by said insulating groove and fixed to said second layer; and
wiring layers formed from said stationary block and said support beam; wherein
said second layer being separated from said first layer by an insulating layer; and
said wiring layers have an air bridge structure over said insulating groove.
US10/123,2201992-04-272002-04-17Acceleration sensor and process for the production thereofExpired - LifetimeUSRE40347E1 (en)

Priority Applications (5)

Application NumberPriority DateFiling DateTitle
US10/123,220USRE40347E1 (en)1992-04-272002-04-17Acceleration sensor and process for the production thereof
US10/315,861USRE40561E1 (en)1992-04-272002-12-10Acceleration sensor and process for the production thereof
US10/315,859USRE41213E1 (en)1992-04-272002-12-10Dynamic amount sensor and process for the production thereof
US10/315,827USRE42083E1 (en)1992-04-272002-12-10Acceleration sensor and process for the production thereof
US10/315,566USRE41047E1 (en)1992-04-272002-12-10Acceleration sensor and process for the production thereof

Applications Claiming Priority (5)

Application NumberPriority DateFiling DateTitle
JP10802092AJP3367113B2 (en)1992-04-271992-04-27 Acceleration sensor
PCT/JP1993/000535WO1993022690A1 (en)1992-04-271993-04-23Acceleration sensor and its manufacture
US16797694A1994-05-111994-05-11
US08/566,600US6227049B1 (en)1992-04-271995-12-04Acceleration sensor and process for the production thereof
US10/123,220USRE40347E1 (en)1992-04-272002-04-17Acceleration sensor and process for the production thereof

Related Parent Applications (2)

Application NumberTitlePriority DateFiling Date
US16797694AContinuation1992-04-271994-05-11
US08/566,600ReissueUS6227049B1 (en)1992-04-271995-12-04Acceleration sensor and process for the production thereof

Related Child Applications (1)

Application NumberTitlePriority DateFiling Date
US08/566,600DivisionUS6227049B1 (en)1992-04-271995-12-04Acceleration sensor and process for the production thereof

Publications (1)

Publication NumberPublication Date
USRE40347E1true USRE40347E1 (en)2008-06-03

Family

ID=14473945

Family Applications (9)

Application NumberTitlePriority DateFiling Date
US08/566,600CeasedUS6227049B1 (en)1992-04-271995-12-04Acceleration sensor and process for the production thereof
US09/457,349Expired - LifetimeUS6171881B1 (en)1992-04-271999-12-09Acceleration sensor and process for the production thereof
US09/457,350Expired - LifetimeUS6244112B1 (en)1992-04-271999-12-09Acceleration sensor and process for the production thereof
US09/883,203AbandonedUS20010032509A1 (en)1992-04-272001-06-19Acceleration sensor and process for the production thereof
US10/123,220Expired - LifetimeUSRE40347E1 (en)1992-04-272002-04-17Acceleration sensor and process for the production thereof
US10/315,827Expired - LifetimeUSRE42083E1 (en)1992-04-272002-12-10Acceleration sensor and process for the production thereof
US10/315,861Expired - LifetimeUSRE40561E1 (en)1992-04-272002-12-10Acceleration sensor and process for the production thereof
US10/315,566Expired - LifetimeUSRE41047E1 (en)1992-04-272002-12-10Acceleration sensor and process for the production thereof
US10/315,859Expired - LifetimeUSRE41213E1 (en)1992-04-272002-12-10Dynamic amount sensor and process for the production thereof

Family Applications Before (4)

Application NumberTitlePriority DateFiling Date
US08/566,600CeasedUS6227049B1 (en)1992-04-271995-12-04Acceleration sensor and process for the production thereof
US09/457,349Expired - LifetimeUS6171881B1 (en)1992-04-271999-12-09Acceleration sensor and process for the production thereof
US09/457,350Expired - LifetimeUS6244112B1 (en)1992-04-271999-12-09Acceleration sensor and process for the production thereof
US09/883,203AbandonedUS20010032509A1 (en)1992-04-272001-06-19Acceleration sensor and process for the production thereof

Family Applications After (4)

Application NumberTitlePriority DateFiling Date
US10/315,827Expired - LifetimeUSRE42083E1 (en)1992-04-272002-12-10Acceleration sensor and process for the production thereof
US10/315,861Expired - LifetimeUSRE40561E1 (en)1992-04-272002-12-10Acceleration sensor and process for the production thereof
US10/315,566Expired - LifetimeUSRE41047E1 (en)1992-04-272002-12-10Acceleration sensor and process for the production thereof
US10/315,859Expired - LifetimeUSRE41213E1 (en)1992-04-272002-12-10Dynamic amount sensor and process for the production thereof

Country Status (5)

CountryLink
US (9)US6227049B1 (en)
EP (1)EP0591554B1 (en)
JP (1)JP3367113B2 (en)
DE (1)DE69305955T2 (en)
WO (1)WO1993022690A1 (en)

Families Citing this family (69)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
US5461916A (en)1992-08-211995-10-31Nippondenso Co., Ltd.Mechanical force sensing semiconductor device
DE4332057A1 (en)*1993-09-211995-03-30Siemens Ag Integrated micromechanical sensor device and method for its production
DE4332843C2 (en)*1993-09-271997-04-24Siemens Ag Method for producing a micromechanical device and micromechanical device
US5654031A (en)*1994-09-061997-08-05Minnesota Mining And Manufacturing CompanyWeb coating apparatus
DE4439238A1 (en)*1994-11-031996-05-09Telefunken Microelectron Capacitive acceleration sensor
GB2295894A (en)*1994-12-071996-06-12Viper Security LtdShock sensor
US6316796B1 (en)1995-05-242001-11-13Lucas NovasensorSingle crystal silicon sensor with high aspect ratio and curvilinear structures
US6084257A (en)*1995-05-242000-07-04Lucas NovasensorSingle crystal silicon sensor with high aspect ratio and curvilinear structures
JP3430771B2 (en)*1996-02-052003-07-28株式会社デンソー Method of manufacturing semiconductor dynamic quantity sensor
JP3198922B2 (en)*1996-07-032001-08-13株式会社村田製作所 Manufacturing method of capacitance type sensor
DE19630553A1 (en)*1996-07-181998-01-29Reiner Ruehle Acceleration-dependent control for an electric motor
DE69626972T2 (en)1996-07-312004-01-08Stmicroelectronics S.R.L., Agrate Brianza Integrated capacitive semiconductor acceleration sensor and method for its production
DE69729753T2 (en)1996-10-072005-08-04Lucas Novasensor Inc., Fremont 5 micron deep pointed channel cavity by oxidizing fusion bonding of silicon substrates and stop etching
JP2001504994A (en)*1996-11-222001-04-10シーメンス アクチエンゲゼルシヤフト Manufacturing method of micromechanical functional element
US6048774A (en)*1997-06-262000-04-11Denso CorporationMethod of manufacturing dynamic amount semiconductor sensor
DE19732250A1 (en)*1997-07-261999-01-28Bosch Gmbh Robert Process for the production of metallic microstructures
JP3846094B2 (en)1998-03-172006-11-15株式会社デンソー Manufacturing method of semiconductor device
GB9819821D0 (en)1998-09-121998-11-04Secr DefenceImprovements relating to micro-machining
DE69831075D1 (en)*1998-10-212005-09-08St Microelectronics Srl Manufacturing method of integrated devices containing microstructures with electrical floating interconnects
JP2000206142A (en)*1998-11-132000-07-28Denso CorpSemiconductor dynamic quantity sensor and its manufacture
US6417098B1 (en)*1999-12-092002-07-09Intel CorporationEnhanced surface modification of low K carbon-doped oxide
US6946314B2 (en)*2001-01-022005-09-20The Charles Stark Draper Laboratory, Inc.Method for microfabricating structures using silicon-on-insulator material
US7381630B2 (en)*2001-01-022008-06-03The Charles Stark Draper Laboratory, Inc.Method for integrating MEMS device and interposer
MXPA03005993A (en)*2001-01-022004-05-04Draper Lab Charles SMethod for microfabricating structures using silicon-on-insulator material.
JP2002228680A (en)2001-02-022002-08-14Denso CorpCapacity-type mechanical amount sensor
US6461888B1 (en)2001-06-142002-10-08Institute Of MicroelectronicsLateral polysilicon beam process
JP4276176B2 (en)*2003-01-292009-06-10三菱電機株式会社 Manufacturing method of semiconductor device
JP2004271464A (en)2003-03-122004-09-30Denso CorpSemiconductor dynamical quantity sensor
US7243545B2 (en)*2003-03-202007-07-17Denso CorporationPhysical quantity sensor having spring
US7514283B2 (en)*2003-03-202009-04-07Robert Bosch GmbhMethod of fabricating electromechanical device having a controlled atmosphere
US8912174B2 (en)*2003-04-162014-12-16Mylan Pharmaceuticals Inc.Formulations and methods for treating rhinosinusitis
US7075160B2 (en)2003-06-042006-07-11Robert Bosch GmbhMicroelectromechanical systems and devices having thin film encapsulated mechanical structures
US6936491B2 (en)2003-06-042005-08-30Robert Bosch GmbhMethod of fabricating microelectromechanical systems and devices having trench isolated contacts
US6952041B2 (en)*2003-07-252005-10-04Robert Bosch GmbhAnchors for microelectromechanical systems having an SOI substrate, and method of fabricating same
US7068125B2 (en)*2004-03-042006-06-27Robert Bosch GmbhTemperature controlled MEMS resonator and method for controlling resonator frequency
US7102467B2 (en)*2004-04-282006-09-05Robert Bosch GmbhMethod for adjusting the frequency of a MEMS resonator
JP4386002B2 (en)*2004-07-062009-12-16株式会社デンソー Manufacturing method of semiconductor dynamic quantity sensor
FR2875947B1 (en)*2004-09-302007-09-07Tracit Technologies NOVEL STRUCTURE FOR MICROELECTRONICS AND MICROSYSTEMS AND METHOD OF MAKING SAME
US8109149B2 (en)2004-11-172012-02-07Lawrence Livermore National Security, LlcContact stress sensor
US7311009B2 (en)*2004-11-172007-12-25Lawrence Livermore National Security, LlcMicroelectromechanical systems contact stress sensor
JP4633574B2 (en)*2005-08-082011-02-16三菱電機株式会社 Thin film structure and manufacturing method thereof
JP2007111831A (en)*2005-10-212007-05-10Seiko Epson Corp Method for manufacturing MEMS element and MEMS element
CN100422071C (en)*2005-10-272008-10-01中国科学院上海微系统与信息技术研究所Wafer level packaging process for micromechanical accelerometer device
US20070170528A1 (en)*2006-01-202007-07-26Aaron PartridgeWafer encapsulated microelectromechanical structure and method of manufacturing same
JP5092462B2 (en)*2006-06-132012-12-05株式会社デンソー Mechanical quantity sensor
FR2905457B1 (en)*2006-09-012008-10-17Commissariat Energie Atomique MICROSYSTEM, ESPECIALLY MICROGYROMETER, WITH DETECTION ELEMENT WITH CAPACITIVE ELECTRODES.
JP4645656B2 (en)*2008-02-072011-03-09株式会社デンソー Semiconductor dynamic quantity sensor
JP4783914B2 (en)*2008-03-212011-09-28株式会社デンソー Semiconductor dynamic quantity sensor and manufacturing method of semiconductor dynamic quantity sensor
JP4783915B2 (en)*2008-06-042011-09-28株式会社デンソー Semiconductor dynamic quantity sensor
FR2932789B1 (en)*2008-06-232011-04-15Commissariat Energie Atomique METHOD FOR MANUFACTURING AN ELECTROMECHANICAL STRUCTURE COMPRISING AT LEAST ONE MECHANICAL REINFORCING PILLAR
US7943525B2 (en)*2008-12-192011-05-17Freescale Semiconductor, Inc.Method of producing microelectromechanical device with isolated microstructures
DE102009006822B4 (en)*2009-01-292011-09-01Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Microstructure, process for its preparation, device for bonding a microstructure and microsystem
JP5260342B2 (en)*2009-01-302013-08-14ローム株式会社 MEMS sensor
JP5592087B2 (en)*2009-08-062014-09-17ローム株式会社 Semiconductor device and manufacturing method of semiconductor device
WO2012002514A1 (en)*2010-07-012012-01-05ローム株式会社Semiconductor device and method for manufacturing same
JP2012045697A (en)*2010-08-302012-03-08Toyota Motor CorpMethod for manufacturing semiconductor device
JP5750867B2 (en)2010-11-042015-07-22セイコーエプソン株式会社 Functional element, method for manufacturing functional element, physical quantity sensor, and electronic device
JP5790297B2 (en)2011-08-172015-10-07セイコーエプソン株式会社 Physical quantity sensor and electronic equipment
US8991251B1 (en)2011-11-212015-03-31Western Digital (Fremont), LlcHybrid capacitive and piezoelectric motion sensing transducer
JP5983912B2 (en)2012-02-092016-09-06セイコーエプソン株式会社 Electronic device, manufacturing method thereof, and electronic apparatus
JP5999302B2 (en)2012-02-092016-09-28セイコーエプソン株式会社 Electronic device, manufacturing method thereof, and electronic apparatus
JP6056177B2 (en)2012-04-112017-01-11セイコーエプソン株式会社 Gyro sensor, electronic equipment
JP2014021037A (en)2012-07-232014-02-03Seiko Epson CorpMems device, electronic module, electronic apparatus, and moving body
CN105339297A (en)*2013-06-272016-02-17索泰克公司Methods of fabricating semiconductor structures including cavities filled with a sacrifical material
JP6206651B2 (en)2013-07-172017-10-04セイコーエプソン株式会社 Functional element, electronic device, and moving object
JP2016042074A (en)2014-08-132016-03-31セイコーエプソン株式会社 Physical quantity sensor, electronic device and mobile object
CN104891419B (en)*2015-06-292016-11-09歌尔股份有限公司 A MEMS inertial sensor and its manufacturing method
US11742208B2 (en)*2020-03-252023-08-29Texas Instruments IncorporatedMethod of reducing voids and seams in trench structures by forming semi-amorphous polysilicon
DE102023209211A1 (en)*2023-09-212025-03-27Robert Bosch Gesellschaft mit beschränkter Haftung Method for producing a microelectromechanical component structure, microelectromechanical component structure, microelectromechanical device and microelectromechanical loudspeaker

Citations (50)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
JPS5944875A (en)1982-09-061984-03-13Nissan Motor Co Ltd Semiconductor device with beam structure
US4483194A (en)1981-07-021984-11-20Centre Electronique Horloger S.A.Accelerometer
JPS6029629A (en)1983-07-271985-02-15Yokogawa Hokushin Electric Corp Semiconductor capacitive pressure sensor
US4507705A (en)1982-08-271985-03-26Nissan Motor Company, LimitedVibration analyzing device
JPS60244864A (en)1984-05-181985-12-04アライド・コ−ポレ−ションCapacitative transducer
JPS6173071A (en)*1984-09-141986-04-15インタ−ナシヨナル・スタンダ−ド・エレクトリツク・コ−ポレ−シヨン flexible hinge device
US4598585A (en)1984-03-191986-07-08The Charles Stark Draper Laboratory, Inc.Planar inertial sensor
JPS6227666A (en)*1985-07-251987-02-05リットン システムズ インコ−ポレ−テッドAccelerometer
US4653326A (en)1984-01-121987-03-31Commissariat A L'energie AtomiqueDirectional accelerometer and its microlithographic fabrication process
JPS6293668A (en)1985-10-211987-04-30Hitachi Ltd Angular velocity/acceleration detector
JPS62174978A (en)1985-10-081987-07-31Nippon Denso Co LtdDevice for detecting semiconductor vibration and acceleration
JPS62207917A (en)1986-03-101987-09-12Fujitsu LtdVibration and acceleration sensor
JPS62232171A (en)1986-04-021987-10-12Nissan Motor Co Ltd semiconductor acceleration sensor
US4711128A (en)1985-04-161987-12-08Societe Francaise D'equipements Pour La Aerienne (S.F.E.N.A.)Micromachined accelerometer with electrostatic return
JPS6325982A (en)1986-07-181988-02-03Nissan Motor Co LtdPressure transducer and manufacture thereof
JPS63250865A (en)1987-04-081988-10-18Nippon Denso Co LtdPressure detecting element and manufacture thereof
US4783237A (en)1983-12-011988-11-08Harry E. AineSolid state transducer and method of making same
US4896268A (en)1987-11-251990-01-23Sundstrand Data Control, Inc.Apparatus and method for processing the output signals of a coriolis rate sensor
US4951510A (en)1988-07-141990-08-28University Of HawaiiMultidimensional force sensor
JPH02237166A (en)1989-03-101990-09-19Mitsubishi Electric Corp semiconductor pressure sensor
JPH02309259A (en)1989-05-241990-12-25Nissan Motor Co Ltd semiconductor acceleration sensor
US5006487A (en)1989-07-271991-04-09Honeywell Inc.Method of making an electrostatic silicon accelerometer
US5008774A (en)1989-02-281991-04-16United Technologies CorporationCapacitive accelerometer with mid-plane proof mass
JPH0394168A (en)1989-09-071991-04-18Hitachi LtdSemiconductor capacity type acceleration sensor and production thereof
GB2240178A (en)1990-01-151991-07-24Bosch Gmbh RobertAcceleration sensor with etched vibratable tongue
JPH03205565A (en)1990-01-081991-09-09Hitachi Ltd Electrostatic servo acceleration sensor and its manufacturing method
GB2246635A (en)1990-07-141992-02-05Bosch Gmbh RobertAcceleration sensor
US5095349A (en)1988-06-081992-03-10Nippondenso Co., Ltd.Semiconductor pressure sensor and method of manufacturing same
JPH0476956A (en)1990-07-191992-03-11Mitsubishi Electric CorpManufacture of semiconductor acceleration sensor
US5115291A (en)1989-07-271992-05-19Honeywell Inc.Electrostatic silicon accelerometer
JPH04235455A (en)1991-01-101992-08-24Mitsubishi Electric CorpCamera type image scanner
US5233213A (en)1990-07-141993-08-03Robert Bosch GmbhSilicon-mass angular acceleration sensor
US5243861A (en)1990-09-071993-09-14Hitachi, Ltd.Capacitive type semiconductor accelerometer
US5284057A (en)1990-12-111994-02-08Delco Electronics CorporationMicroaccelerometer having low stress bonds and means for preventing excessive Z-axis deflection
US5296730A (en)1992-01-161994-03-22Oki Electric Industry Co., Ltd.Semiconductor pressure sensor for sensing pressure applied thereto
JPH0688837A (en)1992-09-041994-03-29Murata Mfg Co LtdAcceleration sensor
US5314572A (en)1990-08-171994-05-24Analog Devices, Inc.Method for fabricating microstructures
US5313836A (en)1989-07-171994-05-24Nippondenso Co., Ltd.Semiconductor sensor for accelerometer
JPH06173071A (en)1992-12-071994-06-21Japan Energy Corp High speed rhodium plating method
US5331853A (en)1991-02-081994-07-26Alliedsignal Inc.Micromachined rate and acceleration sensor
JPH06227666A (en)1993-01-301994-08-16Hiroshi NishioDistribution device of pallet
US5337606A (en)1992-08-101994-08-16Motorola, Inc.Laterally sensitive accelerometer and method for making
US5345824A (en)1990-08-171994-09-13Analog Devices, Inc.Monolithic accelerometer
US5359893A (en)1991-12-191994-11-01Motorola, Inc.Multi-axes gyroscope
US5417111A (en)1990-08-171995-05-23Analog Devices, Inc.Monolithic chip containing integrated circuitry and suspended microstructure
US5495761A (en)1992-12-281996-03-05Commissariat A L'energie AtomiqueIntegrated accelerometer with a sensitive axis parallel to the substrate
US5511420A (en)1994-12-011996-04-30Analog Devices, Inc.Electric field attraction minimization circuit
US5542295A (en)1994-12-011996-08-06Analog Devices, Inc.Apparatus to minimize stiction in micromachined structures
US5563343A (en)1993-05-261996-10-08Cornell Research Foundation, Inc.Microelectromechanical lateral accelerometer
JPH08510837A (en)1993-05-261996-11-12コーネル・リサーチ・ファウンデーション・インコーポレイテッド Ultra-compact electromechanical lateral accelerometer

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
US4510802A (en)1983-09-021985-04-16Sundstrand Data Control, Inc.Angular rate sensor utilizing two vibrating accelerometers secured to a parallelogram linkage
US5095401A (en)*1989-01-131992-03-10Kopin CorporationSOI diaphragm sensor
US5025346A (en)1989-02-171991-06-18Regents Of The University Of CaliforniaLaterally driven resonant microstructures
US5149673A (en)*1989-02-211992-09-22Cornell Research Foundation, Inc.Selective chemical vapor deposition of tungsten for microdynamic structures
US5228341A (en)*1989-10-181993-07-20Hitachi, Ltd.Capacitive acceleration detector having reduced mass portion
DE4003473A1 (en)1990-02-061991-08-08Bosch Gmbh Robert CRYSTAL-ORIENTED MOTION SENSOR AND METHOD FOR THE PRODUCTION THEREOF
EP0459723B1 (en)*1990-05-301996-01-17Hitachi, Ltd.Semiconductor acceleration sensor and vehicle control system using the same
US5205171A (en)*1991-01-111993-04-27Northrop CorporationMiniature silicon accelerometer and method
JP2804196B2 (en)*1991-10-181998-09-24株式会社日立製作所 Microsensor and control system using the same
US5198390A (en)*1992-01-161993-03-30Cornell Research Foundation, Inc.RIE process for fabricating submicron, silicon electromechanical structures
US5349855A (en)1992-04-071994-09-27The Charles Stark Draper Laboratory, Inc.Comb drive micromechanical tuning fork gyro
US5461916A (en)*1992-08-211995-10-31Nippondenso Co., Ltd.Mechanical force sensing semiconductor device
DE4241045C1 (en)1992-12-051994-05-26Bosch Gmbh Robert Process for anisotropic etching of silicon
FR2700065B1 (en)*1992-12-281995-02-10Commissariat Energie Atomique Method of manufacturing accelerometers using silicon on insulator technology.
CA2154357C (en)*1993-02-042004-03-02Kevin A. ShawMicrostructures and single-mask, single-crystal process for fabrication thereof
US5922212A (en)*1995-06-081999-07-13Nippondenso Co., LtdSemiconductor sensor having suspended thin-film structure and method for fabricating thin-film structure body
JP3555388B2 (en)*1997-06-302004-08-18株式会社デンソー Semiconductor yaw rate sensor

Patent Citations (56)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
US4483194A (en)1981-07-021984-11-20Centre Electronique Horloger S.A.Accelerometer
US4507705A (en)1982-08-271985-03-26Nissan Motor Company, LimitedVibration analyzing device
JPS5944875A (en)1982-09-061984-03-13Nissan Motor Co Ltd Semiconductor device with beam structure
JPS6029629A (en)1983-07-271985-02-15Yokogawa Hokushin Electric Corp Semiconductor capacitive pressure sensor
US4783237A (en)1983-12-011988-11-08Harry E. AineSolid state transducer and method of making same
US4653326A (en)1984-01-121987-03-31Commissariat A L'energie AtomiqueDirectional accelerometer and its microlithographic fabrication process
US4598585A (en)1984-03-191986-07-08The Charles Stark Draper Laboratory, Inc.Planar inertial sensor
JPS60244864A (en)1984-05-181985-12-04アライド・コ−ポレ−ションCapacitative transducer
US4574327A (en)1984-05-181986-03-04Becton, Dickinson And CompanyCapacitive transducer
JPS6173071A (en)*1984-09-141986-04-15インタ−ナシヨナル・スタンダ−ド・エレクトリツク・コ−ポレ−シヨン flexible hinge device
US4711128A (en)1985-04-161987-12-08Societe Francaise D'equipements Pour La Aerienne (S.F.E.N.A.)Micromachined accelerometer with electrostatic return
JPS6227666A (en)*1985-07-251987-02-05リットン システムズ インコ−ポレ−テッドAccelerometer
US4679434A (en)1985-07-251987-07-14Litton Systems, Inc.Integrated force balanced accelerometer
JPS62174978A (en)1985-10-081987-07-31Nippon Denso Co LtdDevice for detecting semiconductor vibration and acceleration
US4891984A (en)1985-10-081990-01-09Nippondenso Co., Ltd.Acceleration detecting apparatus formed by semiconductor
JPS6293668A (en)1985-10-211987-04-30Hitachi Ltd Angular velocity/acceleration detector
JPS62207917A (en)1986-03-101987-09-12Fujitsu LtdVibration and acceleration sensor
JPS62232171A (en)1986-04-021987-10-12Nissan Motor Co Ltd semiconductor acceleration sensor
JPS6325982A (en)1986-07-181988-02-03Nissan Motor Co LtdPressure transducer and manufacture thereof
JPS63250865A (en)1987-04-081988-10-18Nippon Denso Co LtdPressure detecting element and manufacture thereof
US4896268A (en)1987-11-251990-01-23Sundstrand Data Control, Inc.Apparatus and method for processing the output signals of a coriolis rate sensor
US5095349A (en)1988-06-081992-03-10Nippondenso Co., Ltd.Semiconductor pressure sensor and method of manufacturing same
US4951510A (en)1988-07-141990-08-28University Of HawaiiMultidimensional force sensor
US5008774A (en)1989-02-281991-04-16United Technologies CorporationCapacitive accelerometer with mid-plane proof mass
JPH02237166A (en)1989-03-101990-09-19Mitsubishi Electric Corp semiconductor pressure sensor
JPH02309259A (en)1989-05-241990-12-25Nissan Motor Co Ltd semiconductor acceleration sensor
US5313836A (en)1989-07-171994-05-24Nippondenso Co., Ltd.Semiconductor sensor for accelerometer
US5006487A (en)1989-07-271991-04-09Honeywell Inc.Method of making an electrostatic silicon accelerometer
US5115291A (en)1989-07-271992-05-19Honeywell Inc.Electrostatic silicon accelerometer
JPH0394168A (en)1989-09-071991-04-18Hitachi LtdSemiconductor capacity type acceleration sensor and production thereof
JPH03205565A (en)1990-01-081991-09-09Hitachi Ltd Electrostatic servo acceleration sensor and its manufacturing method
GB2240178A (en)1990-01-151991-07-24Bosch Gmbh RobertAcceleration sensor with etched vibratable tongue
US5151763A (en)1990-01-151992-09-29Robert Bosch GmbhAcceleration and vibration sensor and method of making the same
GB2246635A (en)1990-07-141992-02-05Bosch Gmbh RobertAcceleration sensor
US5233213A (en)1990-07-141993-08-03Robert Bosch GmbhSilicon-mass angular acceleration sensor
JPH0476956A (en)1990-07-191992-03-11Mitsubishi Electric CorpManufacture of semiconductor acceleration sensor
US5314572A (en)1990-08-171994-05-24Analog Devices, Inc.Method for fabricating microstructures
US5417111A (en)1990-08-171995-05-23Analog Devices, Inc.Monolithic chip containing integrated circuitry and suspended microstructure
US5345824A (en)1990-08-171994-09-13Analog Devices, Inc.Monolithic accelerometer
US5243861A (en)1990-09-071993-09-14Hitachi, Ltd.Capacitive type semiconductor accelerometer
US5284057A (en)1990-12-111994-02-08Delco Electronics CorporationMicroaccelerometer having low stress bonds and means for preventing excessive Z-axis deflection
JPH04235455A (en)1991-01-101992-08-24Mitsubishi Electric CorpCamera type image scanner
US5331853A (en)1991-02-081994-07-26Alliedsignal Inc.Micromachined rate and acceleration sensor
US5359893A (en)1991-12-191994-11-01Motorola, Inc.Multi-axes gyroscope
US5296730A (en)1992-01-161994-03-22Oki Electric Industry Co., Ltd.Semiconductor pressure sensor for sensing pressure applied thereto
US5337606A (en)1992-08-101994-08-16Motorola, Inc.Laterally sensitive accelerometer and method for making
US5561248A (en)1992-09-041996-10-01Murata Manufacturing Co., Ltd.Acceleration sensor
JPH0688837A (en)1992-09-041994-03-29Murata Mfg Co LtdAcceleration sensor
JPH06173071A (en)1992-12-071994-06-21Japan Energy Corp High speed rhodium plating method
US5495761A (en)1992-12-281996-03-05Commissariat A L'energie AtomiqueIntegrated accelerometer with a sensitive axis parallel to the substrate
JPH06227666A (en)1993-01-301994-08-16Hiroshi NishioDistribution device of pallet
US5563343A (en)1993-05-261996-10-08Cornell Research Foundation, Inc.Microelectromechanical lateral accelerometer
JPH08510837A (en)1993-05-261996-11-12コーネル・リサーチ・ファウンデーション・インコーポレイテッド Ultra-compact electromechanical lateral accelerometer
US5610335A (en)1993-05-261997-03-11Cornell Research FoundationMicroelectromechanical lateral accelerometer
US5542295A (en)1994-12-011996-08-06Analog Devices, Inc.Apparatus to minimize stiction in micromachined structures
US5511420A (en)1994-12-011996-04-30Analog Devices, Inc.Electric field attraction minimization circuit

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Office Action issued by Japanese Patent Office on Oct. 23, 2001 in connection with Priority Application No. JP-4-108020 and citing various ones of above references.
Payne et al., "Surface Micromachined Accelerometer: A Technology Update," SAE Technical Paper Series,Feb. 25, 1991, pp. 127-135.

Also Published As

Publication numberPublication date
USRE41047E1 (en)2009-12-22
USRE41213E1 (en)2010-04-13
USRE40561E1 (en)2008-11-04
EP0591554A4 (en)1994-10-05
JPH05304303A (en)1993-11-16
USRE42083E1 (en)2011-02-01
DE69305955T2 (en)1997-06-12
EP0591554A1 (en)1994-04-13
JP3367113B2 (en)2003-01-14
DE69305955D1 (en)1996-12-19
US6244112B1 (en)2001-06-12
US6171881B1 (en)2001-01-09
US20010032509A1 (en)2001-10-25
EP0591554B1 (en)1996-11-13
US6227049B1 (en)2001-05-08
WO1993022690A1 (en)1993-11-11

Similar Documents

PublicationPublication DateTitle
USRE40347E1 (en)Acceleration sensor and process for the production thereof
US6076404A (en)Micromechanical sensor including a single-crystal silicon support
US5780885A (en)Accelerometers using silicon on insulator technology
US6250165B1 (en)Semiconductor physical quantity sensor
JPH0479420B2 (en)
US5172205A (en)Piezoresistive semiconductor device suitable for use in a pressure sensor
JP3638290B2 (en) Semiconductor dynamic sensor
JP3633555B2 (en) Semiconductor dynamic quantity sensor
JPH02218172A (en)Manufacture of semiconductor acceleration sensor
JP4214572B2 (en) Manufacturing method of semiconductor dynamic quantity sensor
JP4175309B2 (en) Semiconductor dynamic quantity sensor
JPH0831608B2 (en) Method for manufacturing semiconductor pressure sensor
JP3638470B2 (en) Semiconductor acceleration sensor
JP3638469B2 (en) Semiconductor acceleration sensor
JP4783914B2 (en) Semiconductor dynamic quantity sensor and manufacturing method of semiconductor dynamic quantity sensor
JP3309827B2 (en) Method of manufacturing substrate having movable part and method of manufacturing dynamic quantity sensor
JP3580285B2 (en) Manufacturing method of semiconductor dynamic quantity sensor
JP4783915B2 (en) Semiconductor dynamic quantity sensor
JPH05335596A (en)Semiconductor acceleration sensor and manufacture thereof
JP3725059B2 (en) Semiconductor dynamic quantity sensor
JPH11220140A (en)Semiconductor dynamic-quantity sensor and manufacture thereof
JPH11345983A (en)Semiconductor dynamic quantity sensor
JP2002289876A (en)Semiconductor dynamic quantity sensor and manufacturing method therefor
JPH11220139A (en)Manufacture of semiconductor dynamic-quantity sensor

Legal Events

DateCodeTitleDescription
FPAYFee payment

Year of fee payment:8

FEPPFee payment procedure

Free format text:PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

CCCertificate of correction
FPAYFee payment

Year of fee payment:12


[8]ページ先頭

©2009-2025 Movatter.jp