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USRE40191E1 - Vacuum process apparatus - Google Patents

Vacuum process apparatus
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Publication number
USRE40191E1
USRE40191E1US08/962,776US96277697AUSRE40191EUS RE40191 E1USRE40191 E1US RE40191E1US 96277697 AUS96277697 AUS 96277697AUS RE40191 EUSRE40191 EUS RE40191E
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United States
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chamber
workpiece
openings
conveyors
opening
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US08/962,776
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Roman Schertler
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OC Oerlikon Balzers AG
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OC Oerlikon Balzers AG
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Priority to US09/619,391prioritypatent/USRE40192E1/en
Assigned to UNAXIS BALZERS AKTIENGESELLSCHAFTreassignmentUNAXIS BALZERS AKTIENGESELLSCHAFTCHANGE OF NAME (SEE DOCUMENT FOR DETAILS).Assignors: BALZERS AKTIENGESELLSCHAFT
Assigned to OC OERLIKON BALZERS AGreassignmentOC OERLIKON BALZERS AGCHANGE OF NAME (SEE DOCUMENT FOR DETAILS).Assignors: UNAXIS BALZERS AG
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Abstract

The invention proceeds from a vacuum process apparatus for an article which is processed or treated, resp. at two stations, whereby each station has a charging and/or removing opening for the article. A transporting device is supported for rotation and includes a supporting portion which is successively moved onto the openings of the stations. The process plant is designed in such a manner that the surface normals determined by the surfaces of the openings and the space axis defined by the axis of rotation of the transport device do not run parallel and rather enclose together an angle of 90° or 45°. By such an arrangement it is possible to design extremely compact vacuum vapor deposition apparatuses having a plurality of individual stations, whereby additionally short transporting distances are obtainable and the volumes to be conditioned can be minimized.

Description

This is a continuation of application Ser. No.08/530,778, filed Sep.19,1995 now abandoned. A continuation of this reissue application was filed Jul.19,2000, under Ser. No.09/619,391.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a vacuum process apparatus of the kind, including at least two stations for treating or handling the workpiece, and a transport device with conveyor means thereon, each for transporting at least one workpiece from station to station.
2. Description of the Prior Art
The German specification DE-A-24 54 544 and “Patent Abstracts of Japan”, Nov. 28, 1989, vol. 13, no. 532, JP-A2 1-218 627, disclose as an example such a vacuum process apparatus which includes at least two stations, each comprising an opening for an article, the openings each determining an opening area with surface normal Anperpendicular to the opening area F such as illustrated inFIG. 1 for sake of clarity. The said apparatus further includes a transport device which is supported and driven to rotate around a space axis as rotational axis and includes at least one conveyor portion for an article, whereby the conveyor portion is moved consecutively to and from the openings of the stations.
In contrary to the design of the apparatus according to the JP-1-218627, the transport device of which comprising only one conveyor portion for an article and whereat the conveyor portion is rigidly fixed on a rotatable cylinder forming the transport device, the apparatus according to the German patent no. 24 54 544 comprises four conveyor portions for articles. These conveyor portions are additionally movable with respect to the transport device. By means of a driving plunger there is realized for each conveyor portion an individual drive for moving the said conveyor portion of the transport device relative to a respective station.
Thus, according to the apparatus of the German patent no. 24 54 544, the conveyor portion may be positioned at different positions with respect to a respective station, according to the specific requirements of a process performed at the station considered, up to providing for a sealing closure of the said opening by means of the conveyor portion.
Provision of the said driving plungers which are led through the wall of the vacuum recipient has different drawbacks:
a) For every driving plunger there must be provided a dynamic gliding vacuum seal which results in a considerable additional expenditure for the apparatus in view of vacuum technical requirements for such dynamic seals.
b) The said driving plungers are individually associated to respective stations. Thus, if an apparatus or vacuum plant shall be changed by changing the number of process stations mounted thereon and especially shall be changed by raising the number of such process stations provided, the complete apparatus with its vacuum recipient must be changed according to the changing number of vacuum tight mounted driving plungers.
It is a first object of the present invention to remedy these drawbacks and to provide a vacuum process apparatus which comprises a self-comprised transport device which may flexibly be used for a great number of different apparatus configurations with respect to the number of the process stations provided.
The design of vacuum process apparatuses according to the DE-A-24 54 544 which have established themselves on the market has the further drawback that the rotational axis around which the transport device is rotatable extends parallel to the normals of the opening areas. Thereby the openings of the stations are distributed equidistantly around the rotational axis i.e. the rotational axis of the transport device, so that, as an advantage, the openings of the stations can be served solely by a pivoting movement of the transport device around the rotational axis. Nevertheless, it is disadvantageous that when designing the vacuum process apparatus, there is a restriction in constructional freedom, in that the individual stations must be located with the said normals of their opening areas extending parallel to the rotational axis of the transport device. This necessitates that the stations must be arranged in one given orientation with respect to the transport device, possibly may be provided at both sides of the plane swept over by the transport device of said DE-A-24 54 544.
It is thus a further object of the present invention to remedy this drawback and to provide a vacuum process apparatus with a transport device-to station openings-relation which allow a significantly improved constructional freedom for such apparatus.
SUMMARY OF THE INVENTION
It is thus a first object of the present invention to provide a vacuum process apparatus of the kind mentioned above which comprises a transport device which may be used flexibly for different apparatus configurations as concerns number of treating or handling stations provided thereon.
It is a further object to provide a vacuum process apparatus which gives a high degree of constructional freedom with respect to the arrangement of the said stations as concerns their orientation in space and especially the spatial arrangement of their respective openings. Thereby it shall be made possible to vastly increase the compactness of such process apparatuses, thereby optimizing assembly, disassembly, operation cycle time etc.
A further object of the invention is to provide a vacuum process apparatus for processing at least one workpiece, comprising at least two stations for treating or handling said workpiece, and having each at least one opening for the workpiece; a transport device rotatable around an axis; a drive arrangement for rotating said transport device; at least two conveyor means arranged at said transport device for at least one workpiece each; driving means at said transport device respectively coupled to said conveyor means to individually move said conveyor means relative to said transport device towards and from said openings.
by providing such a vacuum process apparatus the disadvantages of the prior art apparatus as concerns lack of flexibility with respect to arranging more or less of the said stations at the apparatus are remedied and further the self-contained transport device with conveyor means and said driving means enables to drive said conveyor means without necessity of frictional seals at the process apparatus vacuum chamber wall, through which, according to prior art, such driving means did act on the conveyor means of the known transport device.
It is still an object of the present invention to provide said apparatus with openings defining an opening area each, the normals on said areas being warped with respect to said rotational axis.
It has been recognized basically that, when providing a transporting device which is rotatable around the said axis and wherearound the openings of the said stations are arranged so that the normals on the areas defined by the respective borders of said openings are warped with respect to the said rotational axis, a highest grade of constructional flexibility is gained in order to design apparatuses more compact and/or to produce smallest possible spaces to be evacuated and/or to minimize cycle time of processing due to minimizing the conveyant distance between respective openings of the stations.
It is yet a further object to provide the said apparatus wherein said conveyor means are movable at least one of parallel to said axis and of radially to said axis. Thereby, departing from the rotational axis of the transport device, by appropriate selection of the movability of the said conveyor means, parallel and/or radial with respect to said axis, it becomes possible to reach openings of the said stations arranged with respect to the rotational axis in a great variability of different positions.
A further object of the present invention is to provide said apparatus wherein said conveyor means, once positioned adjacent one of said openings by rotating said transport device, are movable towards and from said opening in a direction given by the normal on the opening area defined by the said opening. Thereby an even simplified apparatus is realized in that it becomes possible to convey a workpiece disposed on the conveyor means considered straight ahead towards or into or through the opening of a station considered.
Yet a further object is to provide the said apparatus wherein rotation of the transport device around the rotational axis defines a cone-shaped trajectory surface with a cone opening angle with respect to the said rotational axis smaller or equal than 90°.
Although the inventive transport device can, if necessary, sweep over selectably variable conical surfaces, in that the cone angle φ is drivingly changed, it has been recognized that a substantial simplification may be reached without any substantial loss with respect to flexibility by the facts that the transport device comprises a transport arm for each of the said conveyor means which arms projecting from the said rotational axis. If the transport device structure with the said transport arms sweeps a conical trajectory surface with an opening angle with respect to the rotational axis up to 90°, by controllably changing the extent of the said transport arms with the conveyor means, station openings may be served along the said conical trajectory surface and located on different great circles of the said cone surface. Thereby, the arms advantageously comprise the said driving means.
Furthermore, the normals on the opening areas of the station openings must not necessarily extend in the direction of the generatrix lines of the conical trajectory surface. These normals can rather extend in an arbitrary direction and in this case at least the conveyor means are accordingly pivoted to finally serve respective openings.
It is, nevertheless, a further object to provide said vacuum process chamber wherein the said normals of said areas point in direction of respective generatrix lines of the trajectory cone surface. This leads to a further simplification of the apparatus, in that linear movement of the said conveyor means in direction of said transport arms will suffice to respectively serve the station openings.
Even in this case it is still possible to stagger the openings of the stations along different great circles of the conical trajectory surface. This is nevertheless not always necessary and may lead to problems in that stations staggered on different great circles and with openings along the same generatrix and thus substantially aligned in generatrix direction may cover each other, making access to the said openings by said conveyor means more difficult.
It is, thus, a further object of the invention to provide a vacuum process apparatus in which the said openings of the stations are located substantially along one single great circle of the trajectory cone surface.
It is still a further object of the present invention to provide a vacuum process apparatus in which the stations communicate by the said openings with the inside of a chamber, said transport device residing within the said chamber. On one hand, by such a design the transport device is protected and further the danger of contamination of the atmosphere prevailing within the stations is decreased because, as mentioned, the openings of the stations communicate with the chamber.
Depending from the desired process or treatment performed within the respective stations, it is a further object to provide the vacuum process apparatus which comprises gas inlet means and pumping means, at least at one of the said stations and of the said chamber.
By providing such gas inlets and pumping means selectively at the said stations and/or the said chamber, one has the freedom to perform with the apparatus different vacuum processes which are allowed or are not allowed to influence each other by atmosphere communication.
It is yet a further object of the invention to provide an apparatus whereon at least one of said conveyor means is coupled to a seal member for sealingly closing the opening of at least one of the said stations. Thereby it becomes possible to sealingly close the respective station which is advantageous if in that station a vacuum process shall be performed which necessitates a clearly defined gaseous atmosphere. The seal member may be formed by a plate-like member of the conveyor means.
Further, the said plate or disk-like member may form one door of a charging or discharging load lock for a workpiece to be charged or discharged with respect to the said chamber or the said plate may be the workpiece support feeding the workpiece through the station opening of a sputtering station whereby the seal member sealing the sputtering station against the chamber wherein the transport device is disposed.
BRIEF DESCRIPTION OF THE DRAWINGS
The invention will be better understood and objects other than those set forth above, will become apparent when consideration is given to the following detailed description thereof. Such description makes reference to the annexed drawings wherein:
FIG. 1 is a schematic illustration for explaining the relative position of opening, opening area and of the normal thereon;
FIG. 2 is a sectional view of a presently preferred embodiment of the inventive vacuum process apparatus;
FIG. 3 is an illustration of an apparatus according toFIG. 2 or4, resp. having a trajectory cone surface with a cone angle of the cone of φ=90° with respect to the cone axis, shown partly in section;
FIG. 4 is a schematic top view in the direction of the rotational axis of the apparatus according toFIG. 3;
FIG. 5 shows the transport device for disk-shaped articles at an apparatus according toFIGS. 2 to4;
FIG. 6 illustrates schematically the principle of the inventive apparatus according toFIGS. 2 to5;
FIG. 7 is a schematic illustration analogue toFIG. 6 of a further embodiment of the inventive apparatus;
FIG. 8 is an illustration in accordance withFIG. 6 or7 of a still further embodiment of the inventive apparatus; and
FIG. 9 illustrates schematically a further embodiment of the inventive apparatus.
DESCRIPTION OF THE PREFERRED EMBODIMENT
FIG. 2 is an illustration designed in section of an inventive vacuum process apparatus in a first configuration. It includes adrive motor1 on the axis A asphysical drive axis3, to which at least onetransport arm5 is mounted. The axis A5of thearm5 extends at an angle, for instance of 45° relative to the rotation axis A. If thedrive axis3 is caused to rotate by means of themotor1 such as indicated by ω, the transport arm(s)5 sweeps over a conical trajectory surface having a cone angle φ of 45°. Two stations are illustrated inFIG. 2. Afirst station7 is for instance and as illustrated designed as load lock. It includes afirst frame9 and asecond frame11 which can be moved upwards and downwards and which is flanged onto thefirst frame9. Inside of the drivingly upwards and downwards movable frame11 a sealingframe12 is provided which determines theopening13 of the station and thus its area, having a surface normal A13of said area. Thelock station7 includes acover15 which is linearly displaceable in the direction x. Quite obviously it also can be pivotable for opening and closing, around a vertical axis in FIG.2. In its closed, illustrated position it is placed sealingly onto the sealingframe12 by a lowering of theintermediate frame11 in the direction y.
Thus, thelock station7 becomes sealed against the environment U.
Thetransport arm5 carries at one end as conveyor portion a disk orplate19 on which an article to be processed rests, in the illustrated example a CD or a magneto-optical storage disk21, centered at theplate19 by acentral pin17. As shown by broken lines theplate19 at the supportingarm5 can be moved back from its seat (illustrated) at the sealingframe12 towards the rotation axis A and thus the lock may be opened at the side of the transport device. Because thetransport device3,5,19 comprised of thetransport arm5 and theconveyor plate19 of the apparatus illustrated inFIG. 2 is located in a vacuum tight chamber K theplate19 must here not necessarily contact theframe12 in a sealed manner. This situation is obviously different when the chamber K itself is not vacuum tight. Thearticle21 is conveyed by the transport arm by rotating of theshaft3 by means of themotor1 towards thesecond station27 illustrated. The driving arrangement at thetransport arm5, the specific construction thereof not forming part of the present invention, and for which various possibilities regarding its design will come to mind to the person skilled in the corresponding art, is sealed by abellows23 in a vacuum tight manner against the interior of the chamber K. By rotating of thetransport arm5, the article, namely e.g. thedisk21, is transported into the area of anopening25 of the second illustratedstation27. Theopening25 determines the surface normal A25of the opening area. From the approach position Q illustrated by broken lines, theconveyor plate19 with thedisk21 is again raised into the position illustrated by full lines by means of the mentioned, for instance pneumatic driving arrangement or mechanism at thearm5, such that the plate comes to contact, now e.g. in a sealed manner, the edge of theopening25 of thestation27 which for instance can be designed as a known etching or coating station.
FIG. 2 illustrates that on the one hand thestations7 and27 and theflange29 of themotor1 are interconnected in such a manner that they encase the closed chamber K in which the transport device with its arm(s)5 moves. The chamber K for the transport device is preferably structured vacuum tight against the environment U. Depending from the prevailing application or operation units (not illustrated) are foreseen at thestation27 and/or at the chamber K and/or at thestation7 which produce respective atmospheres in an aimed manner. Thus, i.e. lines for evacuation and/or gas inlets are foreseen to thestations7 and/or27 and/or to the chamber K. Apumping connection30 for the chamber K and agate7 are illustrated inFIG. 2 as an example.
If the apparatus is designed in such a manner that some or all station openings are sealingly closed by one of thearms5 foreseen, this leads to the possibility of presetting the respective atmospheres in the respective individual stations independently from the atmosphere in the chamber K. In certain cases, however, it will be absolutely sufficient to foresee a common atmosphere for the stations and the chamber K for the transporting device, so that only the chamber must be conditioned or evacuated, such as for example illustrated inFIG. 2, the chamber K beside theload lock station7.
FIG. 3 illustrates partly in section an apparatus in which thearms5 project perpendicularly from theaxis3 of the motor, thus defining for a cone angle φ of 90°.
A top view of the apparatus according toFIG. 3 is illustrated in FIG.4. The same structural members are identified by the same reference numerals. For instance sixtransport arms5a to5f are arranged around the axis A, analogue as illustrated in FIG.3. They serve alternatingly alock station7 for the charging and removing of e.g. thedisks21 and fivefurther processing stations27a to27e.
In order to treat disk shaped articles such as CD's or magneto-optical disks having a central hole, such as thedisk21 illustrated inFIG. 2,FIG. 5 illustrates a preferred support on theplate19. Thus, theplate19 includes at its center apin22 which has three axially extendinggrooves2322′ staggered azimutally by 120°.Springs25 are mounted in these grooves. They project towards the upright end of the pin withportions26 slightly domed outwards beyond the outer surface of the pin, such that thedisk21 can be easily slid e.g. by means of a charging roboter over these portions and a slight snapping occurs at theportions26. This depends from how much theportions26 will project over the depositeddisk21. This slight snapping-on by thedisk21, only slightly over the culmination point P of theportions26, allows also a more easy drawing-off of thedisk21 after its processing or treatment, resp. without that a drive mechanism being necessary for the retaining springs25.
The basic principle of the apparatus explained with reference toFIGS. 2 to4 is schematically illustrated in FIG.6. By means of the here e.g. three illustratedtransport arms5a to5c which rotate around the rotational axis A, the indicated exemplarily threestations27 with their openings are served. In the manner as illustrated by the limiting line29 a transport device chamber K may be formed. During its rotation ω the transport device sweeps over a conical surface having a cone angle φ and serves thestations27 of which theopenings25 determine the surface normal A25. Latter are directed in the direction of generatrix lines of the cone which is swept over. Theopenings25 of thestations27 are located on a great circle of the cone trajectory surface which is swept over, i.e. all have the same distance from the tip S of that cone surface.
InFIG. 7 a further embodiment of the apparatus is schematically illustrated. Here, stations located along the illustratedtrajectory cone surface31 swept over by the arms, are positioned on a firstgreat circle33 and further stations of which only one is illustrated are located on a secondgreat circle35. The surface normals A25of the openings extend again in direction of the generatrix lines m of thecone31. In order to serve theopenings25 ofstations27 which are located on differentgreat circles33,35 thearms5 can be drivingly elongated or shortened such as schematically shown at37, such as for instance by a pneumatic telescope drive, e.g. covered by a here not illustrated bellows, analogue to thebellows23 of FIG.2. Accordingly, it becomes possible to position stations not only on one great circle such as in the apparatus according toFIGS. 2 to4, but staggered azimutally, α, on a plurality of great circles of thecone31.
In a further embodiment of the invention according toFIG. 8 the arms can also be elongated or shortened as again shown at37 and carry aconveyor plate19a. Additionally, the angle φ of the trajectory cone is adjustable e.g. in a driven manner such that it is possible to sweep over respective cones having different cone angles φ. Accordingly, it is possible to serve stations located arbitrarily within large limits. Additionally, theconveyor plate19a is supported angularly at an angle β≦90° at therespective arm5 and, such as illustrated by p, rotatable around the arm axis A5. The setting of the cone angle φ of the elongating or shortening of the arm and of the rotating amount at p, as well, is preferably accomplished drivingly controlled such that it becomes possible to serve by such an arrangement stations with theiropenings25 which are practically positioned arbitrarily regarding their orientation and distribution in space. The preferably foreseen chamber K of the transport device is again indicated by broken lines.
According toFIG. 9 the rotational axis A lies vertically. Thearms5 are L-shaped and mounted so that theconveyor plates19 lie horizontally. This has the substantial advantage that thus articles on the plates must not be fastened or held, resp. The drive means at the arms for the movement of the plates are positioned inside ofbellows23.
By the inventive concept and a correspondingly designed vacuum process apparatus, it becomes possible to design extremely compact apparatuses having a plurality of individual process stations including load locks, whereby looking back toFIG. 2 it follows automatically that, if desired, optimally short conveyance paths may be realized or the volumes to be conditioned can be minimalized, resp.
While there are shown and described present preferred embodiments of the invention it is to be distinctly understood that the invention is not limited thereto, but may be otherwise variously embodied and practiced within the scope of the following claims.

Claims (60)

1. A vacuum process apparatus for processing at least one workpiece, comprising a chamber with:
at least two openings defining respective opening areas for one of treating and handling said at least one workpiece thereat ; and
a transport device, comprising having
a drive shaft rotatable around a rotational axis of said drive shaft;
at least two conveyors arranged at said transport device for at least one workpiece each, said transport device comprising , and a transport arm for each conveyor projecting from operatively associated with said drive shaft;
said arms being operatively coupled to said conveyors to move said conveyors independently of each other relative to said drive shaft and to have at least a radial movement component perpendicular to the drive shaft rotational axis via encapsulated, independent drives, said drives controlling closing and opening of said openings with movement of said conveyors relative to said drive shaft.
16. A vacuum chamber for processing at least one workpiece, comprising at least two openings defining respective opening areas for treating or handling said at least one workpiece thereat ; a transport device with a drive shaft for rotating said transport device around a rotational axis of said drive shaft; at least two conveyors arranged at said transport device for the workpiece thereat, said transport device further comprising , and a transport arm for each conveyor projecting from operatively associated with said drive shaft; said arms and each being operatively coupled to one of said conveyors to move said conveyors independently of each other relative to said drive shaft, said transport arms having at least a radial movement component relative to said drive shaft rotational axis via encapsulated independent drives.
36. A vacuum chamber with at least two openings therein and a workpiece transport arrangement with which at least one workpiece within the chamber is selectively brought into a position adjacent to one of said openings, whereby the transport arrangement is provided within the chamber rotatably around a rotational axis and carries at least two members for holding a workpiece each, a rotation drive is provided to rotate said workpiece transport arrangement, and at least two displacement drives are provided for displacing said at least one workpiece each with respect to said transport arrangement whereby said members are selectively brought into a position aligned with one of said openings by rotation of said transport arrangement and from such position a workpiece is displaceable towards and from said opening by one of said displacement drives, and said member and said displacement drives are operatively mounted on said transport arrangement rotation drive, said displacement drive being arranged to control closing and opening of respective ones of said at least two openings.
41. A vacuum chamber with at least two openings and a workpiece transport arrangement with which at least one workpiece within the chamber is selectively brought into a position adjacent to one of said openings, whereby the transport arrangement is provided within the chamber rotatably around a rotational axis and carries at least two members for holding a workpiece each, a rotation drive is provided to rotate said workpiece transport arrangement, and at least two displacement drives are provided for displacing said at least one workpiece each with respect to said transport arrangement whereby said members are selectively brought into a position aligned with one of said openings by rotation of said transport arrangement and from such position a workpiece is displaceable towards and from said opening by one of said displacement drives in a direction with a radial component relative to said rotational axis, and said displacement drives are operable independently of each other so as to control closing and opening of said opening.
50. A vacuum chamber with at least two openings and a workpiece transport arrangement with which at least one workpiece within the chamber is selectively brought into a position adjacent to one of said openings, whereby the transport arrangement is provided within the chamber rotatably around a rotational axis and carries at least one member for holding a workpiece, a rotation drive is provided to rotate said workpiece transport arrangement, and a sealed displacement drive is arranged between said transport arrangement and said at least one member for displacing a workpiece with respect to said transport arrangement, whereby said member is selectively brought into a position aligned with one of said openings by rotation of said transport arrangement and from such position a workpiece is displaceable towards and from said opening by said displacement drive, and said member and said displacement drive are operatively mounted relative to said transport arrangement rotation drive, said displacement drive being further arranged to control opening and closing of said opening.
US08/962,7761991-05-311997-11-03Vacuum process apparatusExpired - LifetimeUSRE40191E1 (en)

Priority Applications (2)

Application NumberPriority DateFiling DateTitle
US08/962,776USRE40191E1 (en)1991-05-311997-11-03Vacuum process apparatus
US09/619,391USRE40192E1 (en)1991-05-312000-07-19Vacuum process apparatus

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DE4117969ADE4117969C2 (en)1991-05-311991-05-31 Vacuum chamber
US07/888,111US5245736A (en)1991-05-311992-05-26Vacuum process apparatus
US53077895A1995-09-191995-09-19
US08/962,776USRE40191E1 (en)1991-05-311997-11-03Vacuum process apparatus

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US07/888,111ReissueUS5245736A (en)1991-05-311992-05-26Vacuum process apparatus
US53077895AContinuation1991-05-311995-09-19

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US07/888,111CeasedUS5245736A (en)1991-05-311992-05-26Vacuum process apparatus
US08/962,776Expired - LifetimeUSRE40191E1 (en)1991-05-311997-11-03Vacuum process apparatus
US09/619,391Expired - LifetimeUSRE40192E1 (en)1991-05-312000-07-19Vacuum process apparatus

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EP (1)EP0518109B1 (en)
JP (1)JPH0763612B2 (en)
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DE4117969C2 (en)2000-11-09
ATE162854T1 (en)1998-02-15
DE4117969A1 (en)1992-12-03
DE59209160D1 (en)1998-03-05
KR100247597B1 (en)2000-03-15
EP0518109A1 (en)1992-12-16
JPH0763612B2 (en)1995-07-12
JPH05184903A (en)1993-07-27
USRE40192E1 (en)2008-04-01
US5245736A (en)1993-09-21
KR920021203A (en)1992-12-18
EP0518109B1 (en)1998-01-28

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