Movatterモバイル変換


[0]ホーム

URL:


USRE37945E1 - Liquid crystal display device and manufacturing method thereof - Google Patents

Liquid crystal display device and manufacturing method thereof
Download PDF

Info

Publication number
USRE37945E1
USRE37945E1US09/801,179US80117901AUSRE37945EUS RE37945 E1USRE37945 E1US RE37945E1US 80117901 AUS80117901 AUS 80117901AUS RE37945 EUSRE37945 EUS RE37945E
Authority
US
United States
Prior art keywords
liquid crystal
crystal display
substrate
substrates
support members
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US09/801,179
Inventor
Tatsuo Kanezawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seiko Epson Corp
Original Assignee
Seiko Epson Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/584,599external-prioritypatent/US5717476A/en
Application filed by Seiko Epson CorpfiledCriticalSeiko Epson Corp
Priority to US09/801,179priorityCriticalpatent/USRE37945E1/en
Application grantedgrantedCritical
Publication of USRE37945E1publicationCriticalpatent/USRE37945E1/en
Anticipated expirationlegal-statusCritical
Expired - Lifetimelegal-statusCriticalCurrent

Links

Images

Classifications

Definitions

Landscapes

Abstract

In a liquid crystal display device, support columns are formed on the outside of a seal area in an edge area of opposing substrates, thus reducing substrate deformation and preventing the occurrence of air bubbles inside the liquid crystal layer, undesirable coloring of the display area, and color irregularity. Support columns9formed using a conductive ink are provided on the outside of seal material6used for sealing liquid crystal layer5contained between top substrate1and bottom substrate2.The support columns9prevent the warping of substrates1and2caused by the shrinkage of mold material8during hardening, reducing the changes in the liquid crystal layer thickness. Support columns9are print-formed simultaneously with the conductive connection area of the liquid crystal panel, and are hardened simultaneously with the seal material.

Description

BACKGROUND OF THE INVENTION
1. Field of the Invention
The invention relates to a liquid crystal display device, and more particularly to technologies for enhancing the structure of the peripheral area of the substrate of a liquid crystal display.
2. Description of the Related Art
In conventional liquid crystal display devices, the sealing of a liquid crystal layer between two substrates, and the application of voltage between the electrodes formed in pairs on the back side of the liquid crystal layer change the orientation of the liquid crystals inside the layer, making it possible to display various images. FIG. 7 depicts an example of an enlarged cross-sectional view of the substrate edge area of a conventional liquid crystal display devices, and FIG. 8 is a perspective view from above showing the overall configuration.
As shown therein, both the top andbottom substrates1,2 are constituted by clear glass plates, andtransparent electrodes3 and4 are formed in specified patterns on the opposing internal surfaces ofsubstrates1 and2.Liquid crystal layer5 is sealed betweentop substrate1 andbottom substrate2 by means ofsealant6.
Bottom substrate2 extends farther out to one side thantop substrate1, andelectrode pads4a, which are conductively connected toclear electrode4, constitute external electrodes are formed on this surface.Insertion pins7, installed such that they clampbottom substrate2, contact theseelectrode pads4a and connect to an external wiring substrate, or the like.Insertion pins7 with legs are attached tosubstrate2 by means ofelastic jaws7a and7b, such that they clamp ontobottom substrate2; and these installation areas are secured withmolding material8.
Multiple electrode pads4a are positioned at a specified minimum interval on the edge area ofbottom substrate2, and are connected totransparent electrodes4 formed on the interior surface ofbottom substrate2. On the other hand, as shown in FIG. 8,multiple electrode pads3a are also formed on the edge area ofbottom substrate2, and are connected viaconductive connection area10 totransparent electrodes3 formed on the interior surface oftop substrate1. The above device is, for example, a segment-type liquid crystal display device, andtransparent electrodes3 and4 are used as common electrodes and segment electrodes, respectively.
Such conventional devices have numerous drawbacks problems and has a disadvantage for example in the above-mentioned conventional liquid crystal display device, it is necessary to fill and coat the gap betweentop substrate1 andbottom substrate2 withresin molding material8 in order to secure the area whereelectrode pads3a and4a andinsertion pins7 with legs are conductively connected, and to prevent electrolytic corrosion ofelectrode pads4a, in the electrode lead-out area wherebottom substrate2 extends outward beyond the edge area oftop surface1. This kind of coating is also used in making a conductive connection for the pad areas of a circuit board via bonding wires, and in making a conductive connection using a conductive adhesive in the edge area of a flexible substrate and heat seal, in addition to the conductive connection that is made viainsertion pins7 with legs as described above.
The reasons for using a resin mold for coating include the following: to electrically coat the connections of the various components connected to the above-mentionedinsertion pins7 with legs, bonding wires, flexible substrates, heat seal, etc. (conductive connection area protection mold); to secure flexible substrates and the heat seal, etc. and to increase their rigidity (reinforcement mold); to prevent electrolytic corrosion caused by the potential difference between electrode pads resulting from the adhesion of a liquid such as water to two or moreadjacent electrode pads3a and4a (anti-corrosion mold); and to prevent corrosion and erosion of other structural areas of a liquid crystal panel (durability and corrosion resistance enhancement mold).
As explained above, this kind of mold is often applied to the conductive connection area whereelectrode pads3a and4a are formed. However, the type of reinforcement and durability mold described above is necessarily applied to areas other than conductive connection areas. Therefore, resin coating using a mold agent is sometimes applied to the entire perimeter of a liquid crystal panel.
When such a mold, or coating, is applied, the hardening and shrinking of the mold resin usually pulls the edges of the top and bottom substrates closer, deforming them inward. As a reaction to this phenomenon, the space between the top and bottom substrates becomes wider toward the middle of sealingmaterial6, causing negative pressure inside, and as a result, low-temperature air bubbles and shock air bubbles tend to occur inside the liquid crystal layer.
Furthermore, the stress accompanying the resin coating changes the cell thickness of the liquid crystal panel, and tends to produce coloring and color irregularity. This cell thickness change tends to be particularly large near the seal area, and it may become necessary to apply a black mask to the perimeter of the liquid crystal panel in order to avoid display quality degradation in this area. Because the formation of this mask reduces the liquid crystal display area, it increases the overall cost of manufacturing a liquid crystal display. The above-mentioned coloring and color irregularity become particularly serious problems in large-size liquid crystal panels since cell thickness may vary widely within the panel surface.
The cause of the stress that brings about the above-mentioned substrate deformation is not limited to shrinkage-induced stress, and may include such factors as mechanical contacts made during liquid crystal panel manufacturing or during the incorporation of the liquid crystal panel into various instruments, and shock or vibration applied to the various instruments into which the liquid crystal panel is incorporated.
OBJECTS OF THE INVENTION
Therefore, it is the object of the present invention to solve the above-mentioned problems and provide a new structure for a liquid crystal display device, that can prevent substrate deformation by dispersing the stress applied to the substrates.
It is another object of the present invention to improve the display quality of liquid crystal display devices by reducing dimensional errors in the liquid crystal cell structure caused by external stress.
It is a further object of the present invention to improve product yield by preventing quality degradation of liquid crystal display devices due to mold formation.
It is a still further object of the present invention to achieve a method that does not require any special design change or addition of manufacturing steps in order to prevent substrate deformation caused by mold formation.
SUMMARY OF THE INVENTION
As a means of solving the above-mentioned problems, the liquid crystal display device of the invention is provided with two substrates at least one of which is transparent, a liquid crystal contained between the substrates, a seal area formed between the substrates to surround the liquid crystal layer, and support columns for connecting the substrates on the outside of the seal area. The liquid crystal layer can be based on any display principle, and the seal area and the support columns are not limited to any particular materials. Furthermore, any number of support columns can be used, and they can be formed in any shape.
According to this means, the formation of the support columns on the outside of the seal area reduces substrate deformation that may be caused by various elements that use the seal area as the function. Therefore, it is possible to reduce the occurrence of air bubbles inside the liquid crystal layer, as well as undesirable coloring of the display area, and color irregularity.
When a mold material for covering the edge areas of the substrates is provided, the support columns resist the compression force of the mold material, thus reducing the stress applied to the substrates and providing the effect of suppressing substrate deformation. The mold materials include a type for fastening connection components, e.g., connection pins and connection wires, that are conductively connected to the external pins used for applying an electrical field to the liquid crystal layer; a type for reinforcing the flexible substrate that is conductively connected to the external pins used for applying an electrical field to said liquid crystal layer; and a type for preventing electrolytic corrosion of said external pins.
In these cases, the support columns should preferably be formed at the edges of the substrates. The support columns formed at the edges of substrates offer the greatest resistance to the stress applied to the edges of the substrates.
Furthermore, the support columns should preferably be formed using the conductive paste used for making a conductive connection among the wires inside the device. When the support columns are formed using the conductive paste, the support columns can be formed simultaneously with the conductive connection areas (in particular, the top and bottom connection areas for connecting the conductive elements formed along the substrates that sandwich the liquid crystal cells) inside the liquid crystal panel, or the support columns can be used as the conductive connection area. In this way, manufacturing costs can be reduced without any changes in the number of processes or the process contents.
Additionally, the conductive paste should preferably be a conductive ink containing carbon. When a conductive ink containing carbon is used, the support column can easily and precisely be formed using a printing method.
Furthermore, the support columns should preferably be formed using a material containing a phenol resin as the main ingredient, in which case their adhesion to the substrates is relatively weak and they process an appropriate degree of flexibility. This facilitates the cutting of the substrates which is performed during the manufacture of the liquid crystal display device, and avoids the risk of cracking the substrates when they are cut at the areas where the support columns have been formed.
Additionally, the support columns should preferably be formed using a material processing weaker adhesion strength than the material comprising the seal area. This facilitates the cutting of the substrates which is performed during the manufacture of the liquid crystal display device, and avoids the risk of cracking the substrates when they are cut at the areas where the support columns have been formed.
Furthermore, the support columns should preferably be formed using a material processing the same hardening characteristics as the material comprising the seal area. When the support columns are formed using a material that possesses the same hardening characteristics as the material comprising the seal area, the support columns can be hardened simultaneously with the seal area during the manufacture of the liquid crystal display device. Therefore, unlike in a case in which the support columns and the seal area are separately hardened, the substrate positioning accuracy used for hardening the seal area can also be used for the support columns, thus avoiding increases in the number of manufacturing steps and the process time.
Additionally, according to the manufacturing method of the liquid crystal display device, a seal area is formed between two substrates at least one of which is transparent, to surround the area that houses the liquid crystal layer, and after the support columns for connecting the substrates on the outside of the seal area are formed, the edges of said substrates are covered by a mold material. In this manufacturing method, the above-mentioned effects can be easily obtained simply by providing the support columns.
Note that the seal area and the support columns should preferably be formed using materials possessing the same hardening characteristics, and the seal area and the support columns should preferably be hardened at the same time. The seal area and the support columns can be hardened simultaneously if they are formed using materials possessing the same hardening characteristics, e.g., thermohardening or photo-curing characteristics, thus eliminating the need for a new hardening process.
Furthermore, the conductive connection areas that connect electrodes formed on the substrate with external pins should preferably be formed simultaneously with the support columns using the same material. The support columns and the conductive connection areas can be positioned and formed using a single process if they are formed using the same material, thus eliminating the need for a new manufacturing process for positioning and forming the support columns, and the above-mentioned effects can be obtained by merely changing the formation pattern of the conductive connection areas.
Other objects and attainments together with a fuller understanding of the invention will become apparent and appreciated by referring to the following description and claims taken in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
In the drawings wherein like reference symbols refer to like parts.
FIG. 1 is an enlarged partial cross-sectional view of a first embodiment of the liquid crystal display device in accordance with the present invention;
FIG. 2 is a top perspective view of the first embodiment;
FIG. 3 is an enlarged partial cross-sectional view of a second embodiment of the liquid crystal display device in accordance with the present invention;
FIGS. 4A-4D are process diagrams showing a first embodiment of a manufacturing method of the liquid crystal display device in accordance with the present invention;
FIGS. 5A-5D are process diagrams showing a second embodiment of the manufacturing method of the liquid crystal display device in accordance with the present invention;
FIG. 6 is a top view showing the assembly structure of the liquid crystal display device formed according to the second embodiment of the manufacturing method;
FIG. 7 is an enlarged partial cross-sectional view of a conventional liquid crystal display device; and
FIG. 8 is a top perspective view of a conventional liquid crystal display device.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Next, the embodiments of the invention will be explained with references to the drawings. The liquid crystal display device of the invention can be applied to various types of liquid crystal display devices, including known liquid crystal display devices such as the TN type, the STN type, and the GH type; those used for the relatively small display areas of watches and calculators; and high-capacity types used for personal computer displays and small-size TVs.
First Embodiment
FIG. 1 shows an enlarged partial cross-sectional view of the first embodiment of the liquid crystal display device related to the invention. In this embodiment, the liquid crystal display device is provided withtop substrate1 formed in the same way as the conventional example described above,bottom substrate2,transparent electrodes3 and4.Liquid crystal layer5,seal material6, andelectrode pads4a. Insertion pins7 with legs are installed onelectrode pads4a ofbottom substrate2 and are then fastened withmolding material8. Depending on the liquid crystal display method, a polarizing plate may be positioned on the outside of the top and bottom substrates.
In this embodiment,support columns9 formed using a conductive ink containing carbon particles are formed between the edges oftop substrate1 andbottom substrate2. As will be explained below, thesesupport columns9 are formed simultaneously with the assembly of the top and bottom substrates beforemold material8 is supplied.
FIG. 2 is a top perspective view of the first embodiment. As shown thereinliquid crystal layer5 is sealed betweentop substrate1 andbottom substrate2 byseal material6. Transparent electrodes4 (shown in FIG. 1) formed in a specified pattern onbottom substrate2 are conductively connected toelectrode pads4a formed on the surface of the edge area ofbottom substrate2. Transparent electrodes3 (not shown in the figure) formed in a specified pattern on the inside surface oftop substrate1 are conductively connected toelectrode pads3a formed onbottom substrate2, via top-bottom connection areas10 comprising a conductive (carbon) ink.
Electrode pads3a and4a are conductively connected to an exterior structure such as a printed circuit board viainsertion pins7 having respective legs. Note that thesupport columns9 are formed at a specified spacing between the right edge area oftop substrate1 andbottom substrate2, to provide sufficient support between the edges oftop substrate1 andbottom substrate2.
Support columns9 are formed to provide support between the edge area oftop substrate1 andbottom substrate2, as a result they should preferably be spaced evenly where necessary as in the area described above. Althoughsupport columns9 are formed only on the right edge in this embodiment, they can be formed on one or more other edges if necessary.
By virtue ofsupport columns9 being formed using a conductive ink in this embodiment, it is possible to utilize them as conductive connection areas, like top-bottom connection areas10, if the circuit configuration allows. For example, it is possible to usesupport columns9 to connectelectrodes3 formed on the inside surface oftop substrate1 toelectrode pads3a formed in the right edge area ofbottom substrate2, in place of or in addition to top-bottom connection areas10.
In the first embodiment,support columns9 are formed in locations that match the sparing ofelectrode pads3a and4a. However, as evident from the fact that somesupport columns9 are formed in areas where no electrode pads exist, the locations ofsupport columns9 are not limited to areas on top of electrode pads, andsupport columns9 can be formed in any location. However, when using a conductive material forsupport columns9, care must be taken to preventsupport columns9 from providing a conductive path among adjacent electrode pads. This can be accomplished by making the diameter ofsupport columns9 smaller than the electrode pad spacing. However, a simpler method is to formsupport columns9 on top of electrode pads as in the first embodiment.
As will be appreciated by one of, instead of formingsupport columns9 possessing circular cross-sections as in the first embodiment, it is possible to form them such that they possess elongated rectangular cross-sections along the edge of the substrate. However, when formingsupport columns9 in the electrode pad formation locations as in this embodiment, they must be formed using an insulating material, or insulators must be used between the support columns and the electrode pads to prevent shorting of the adjacent electrode pads.
Furthermore, althoughsupport columns9 should preferably be formed on the edge area oftop substrate1 as in the embodiment in order to increase their resistance to stress, they can provide a similar effect as long as they are located outside ofseal material6.
The preferred material for the support columns in this embodiment is the above-mentioned conductive ink. Conductive powder such as carbon powder is mixed in with an appropriate hardening element, and a phenol resin, for example, is used as the hardening element. Because this conductive ink is the same material as that used in the conductive connection area and can be formed in the same process, it is superior in terms of ease of manufacturing and cost reduction. Furthermore, because the phenol resin has weak adhesion strength and is relatively soft, it facilitates the cutting of the substrates during manufacturing and can prevent the substrates from cracking during the cutting operation.
In addition to the above-mentioned conductive ink, various types of conductive pastes, such as silver solder, can be used as the conductive material comprising the support columns. However, the material of the support columns related to this invention need not be conductive, and can be insulating. The material of the support columns should preferably be a type that can be positioned in a semi-fluid state and can then be hardened, in order to make the selective positioning of the support columns easy. For example, thermohardening or photo-curing resin can also be used.
In terms of required characteristics, the support columns should at least possess sufficient support strength after hardening, and need not adhere to the substrates. Actually, it is preferable that the adhesion be weak for the following reason. Because the support columns are formed on the substrate edge, the desired level of adhesion strength will not interfere with the cutting of the substrates as explained below. If the adhesion is strong, cutting the substrates across the areas where the support columns are adhered becomes difficult. Furthermore, even if cutting can be performed, it will not be possible to separate the substrates, thus posing the risk of damaging the substrate edges. Adhesion strength is related to the shrinkage rate during hardening, and the material of the support columns should preferably be weak in adhesion and low in shrinkage rate sin order to suppress substrate deformation and warpage.
Second Embodiment
FIG. 3 shows the second embodiment of the liquid crystal display device related to the invention. In the second embodiment,top substrate1,bottom substrate2,transparent electrodes3 and4,electrode pads4a,liquid crystal layer5,seal material6, andsupport columns9 are identical to those in the above embodiment, and thus their explanations are omitted.
In this embodiment,heat seal20 is adhered to the top of multiple andparallel electrode pads3a (connected totransparent electrode3; FIG. 6) and4a. Inheat seal20,wiring pads21 are formed on the bottom of a thin flexible resin sheet at the same pitch as that ofelectrode pads3a and4a, and an anisotropic conductive layer (not shown in the figure) is adhered to the surface ofwiring pads21. This anisotropic conductive layer is produced by dispersing conductive particles in a thermohardening resin, for example, and adhesion with appropriate heating and pressurization can produce conductivity in the adhesion direction only.
Electrode pads3a and4a can be conductively connected towiring pads21 by applying a specified level of pressure and heat after thewiring pads21 are formed on the surface ofheat seal20.Electrode pads3a and4a are then contacted. Then,mold material18 is used for sealing to reinforce the connection area ofheat seal20 and to coverelectrode pads3a and4a.
In the second embodiment, as in the first embodiment, the edge area oftop substrate1 has a tendency to be pulled towardbottom substrate2 by the shrinking force ofmold material18, and thereby potentially deformingtop substrate1. However, because the edge area oftop substrate1 is supported bysupport columns9, the deformation oftop substrate1 is suppressed. In the second embodiment, becausemold material18 is intended to reinforce the connection area ofheat seal20, it must preferably possess high levels of adhesion strength and hardness after hardening. In this example mold material extends betweenseal material6 andsupport columns9. However, such a material will also have a high shrinkage rate during hardening, which will apply a larger stress to the substrate edge during the hardening of the mold material, thus making the formation ofsupport columns9 even more effective in this case.
FIGS. 4A-4D show the first embodiment of the manufacturing method of the liquid crystal display device related to the invention. As shown in FIG. 4A, a pattern of transparent electrodes not shown in the figure is formed ontransparent glass substrate2, and then sealant11 is coated onto the area corresponding to the perimeter of the liquid crystal display area.Conductive ink12 is then selectively placed on the surface ofbottom substrate2 using screen printing. Thisconductive ink12 is placed in the positions of necessary conductive connection areas (for example, top-bottom connection areas10 in FIG.2), and in multiple locations alongsealant11 on the outside of the liquid crystal display area.
Next, as shown in FIG. 4B,top substrate1 is placed on top ofsealant11 andconductive ink12, andtop substrate1 andbottom substrate2 are secured by a specialized jig to maintain a specified gap (for example, several to dozens of mm). The substrates along with the specialized jig are heated to 150°-200° C. in an oven, simultaneously thermohardeningsealant11 andconductive ink12, and thus formingseal material6 andsupport columns9.
Furthermore, as shown in FIG. 4C, the top and bottom substrates are cut and separated for each liquid crystal display area, andtop substrate1 is cut as shown in FIG. 4D to form the external pin area. If the adhesion ofsupport columns9 totop substrate1 is too strong during the cutting oftop substrate1,support columns9 may protrude into the cutting line, making the cutting operation difficult, or the cutting line may weave aroundsupport columns9. The reason for this is as follows. In a low-cost coating method using printing, it is difficult to precisely control the amount ofconductive ink12; and it is even more difficult to do so given the gap between the substrates during the substrate alignment operation. Therefore, it is unrealistic to try to control the diameters ofsupport columns9 and the degree of protrusion into the planned cutting line.
However, in this embodiment, the adhesion strength ofsupport columns9, which are made of a conductive ink containing a phenol resin, is relatively weak, and is much weaker than that ofsealant11. As a result,top substrate1 can be cut without any problem even if the conductive ink protrudes past the planned substrate edge line.
Insertion pins7 with legs shown in FIG. 1 are then inserted into the liquid crystal panel thus formed,mold material8 consisting of a UV-hardening resin is coated on top of the external pin area and is hardened through light irradiation. During this operation,mold material8 may shrink as it hardens. Even so, becausesupport columns9 have been formed between the edge area oftop substrate1 andbottom substrate2, the shrinking force is absorbed bysupport columns9, thus reducing the stress applied to the substrates and preventing substrate deformation.
When a liquid crystal panel is produced without injecting liquid crystals into the gap betweentop substrate1 andbottom substrate2, the substrate gap expands by a maximum of approximately 1 mm in a conventional liquid crystal panel. In contrast, in this embodiment, expansion of the substrate gap was nearly nonexistent. When liquid crystals were actually injected in a conventional liquid crystal panel, the substrate gap is expanded by approximately 0.2-0.5 mm. In contrast, in the first embodiment, expansion of the substrate gap was at most 0.1 mm, drastically improving product yield. For example, in the case of TNT—(Twisted Nematic) type liquid crystal display devices, even changes of 0.2-0.5 mm in the substrate gap cause problems in product quality because coloring and color irregularity clearly occur when the change in the substrate gap exceeds 1 min. In the case of STN—(Super Twisted Nematic) type liquid crystal display devices, even changes of around 0.1 mm in substrate gap affect color tone. Therefore, display quality problems have occurred in TN-type liquid crystals, and in particular, fatal defects have occurred in STN-type liquid crystals in the past. However, the invention has succeeded in drastically improving display quality.
Next, the second embodiment of the manufacturing method of the liquid crystal display device related to the invention will be explained with reference to FIG. 5A-5D. In this embodiment, transparent electrodes andinternal surface structures33 and34, such as polarizing film, are formed in the interior surfaces of twotransparent substrates31 and32 as shown in FIG.5A. Assurface structures33 and34, common electrodes are formed in area a, segment electrodes are formed in the center of area b, and electrode pads are formed on both edge areas of the segment electrodes. As shown in the figure, area a and area b are alternately formed on the interior surfaces oftransparent substrates31 and32; furthermore, area a formed on the interior surface oftransparent substrate31 corresponds to area b formed on the interior surface oftransparent substrate32, and area b formed on the interior surface oftransparent substrate31 corresponds to area a formed on the interior surface oftransparent substrate32.
Next,sealant35 formed to enclose the liquid crystal containment area andphenol resin36 formed on the outside of saidsealant35 are sandwiched between the two substrates which are maintained at a specified gap by a jig, etc. From this state, the substrates are heated to hardensealant35 andphenol resin36.
When thetransparent substrates31 and32 of the continuous panel thus configured is then cut into individual limits defined by said areas a and b, a liquid crystal is thus formed that uses the area corresponding to area a as the top substrate (smaller substrate)1 and the area corresponding to area b as the bottom substrate (larger substrate)2, as shown in FIG.5B.
In this liquid crystal cell, as shown in FIG. 5C, extended areas ofbottom substrate2 exist on both sides of both edge areas oftop substrate1; andelectrode pads3a and4a similar to those in the first embodiment are formed in these extended areas.Electrode pads3a and4a are connected totransparent electrode3, i.e., the common electrode, andtransparent electrode4, i.e., the segment electrode, respectively, formed in the interior surfaces oftop substrate1 andbottom substrate2.
The liquid crystal cell thus configured forms the liquid crystal display shown in FIG. 5D when liquid crystals are introduced into the area surrounded bythermohardened seal material6 and supportcolumns19 on the outside.
In this liquid crystal display,bottom surface2 extends past both edge areas oftop substrate1, andelectrode pads3a and4a which act as external pins are formed in these extended areas.Support columns19 are formed on the outside ofseal materials6 which face these external pins on both sides. Because thesupport columns19 are made of an insulating phenol resin, they can be formed in any size or at any position regardless of the formation positions ofelectrode pads3a and4a. In this embodiment,transparent substrates31 and32 are preferably cut near the formation locations ofsupport columns19. However, the transparent substrates can be separated without any problem even ifsupport columns19 protrude into adjacent areas because of weak adhesion ofsupport columns19 to the transparent substrates.
According to this second embodiment of the manufacturing method, a printing or coating process for forming insulatingsupport columns19 must be incorporated. Sincesupport columns19 become insulating members, they offer the benefit of being able to be formed in the optimal locations and shapes for preventing deformation of the substrates of the liquid crystal display, without being limited by the relative positions of the electrode pads. The above-mentioned structure in which areas a and b are alternately repeated is preferable for mass-production of liquid crystal display devices, and is effective in achieving cost reduction.
FIG. 6 shows an example in which the above-mentioned liquid crystal display is connected via a flexible substrate (heat seal)20 tocircuit board30 on which a liquid crystal drive circuit is mounted. The edge area ofheat seal20 is placed on top ofelectrode pads3a and4a formed on the external pin area of the liquid crystal display, and is then adhered via an anisotropic conductive adhesive layer towiring pad21 formed on the bottom surface of heat seal20 (back side in the figure) by applying heat and pressure.Mold material18 fastens the tip area ofheat seal20 adhered on top ofelectrode pads3a and4a to the liquid crystal display, and is used for reinforcing the connection area.
As demonstrated by the various types of embodiments explained above, and as understandable to one skilled in the art to which the invention belongs, the invention can be used in a broad range of applications regardless of the connection structure of the external pin area of the liquid crystal display, the liquid crystal cell structure, or the area covered by the mold material.
Although the covering of the external pin area with a mold material was chiefly explained in each of the above embodiments, the invention is not limited to such cases and can be applied to various types of liquid crystal display devices, providing the superior effects of preventing changes in the substrate gap due to various types of external forces.
As explained above, the invention provides the following effects.
In accordance with an aspect of the present invention, formation of the support columns on the outside of the seal area reduces the substrate deformation that may be caused by the various elements that use the seal area as the fulcrum. Therefore, it is possible to reduce the occurrence of air bubbles inside the liquid crystal layer, as well as undesirable coloring of display area, and color irregularity caused by the changes in the substrate gap.
Additionally, the invention is effective in suppressing substrate deformation because the support columns support the shrinking force of the mold material, thus reducing the stress applied to the substrates.
Moreover in accordance with a further aspect of the present invention, the support columns formed on the edge area of the substrates provide the largest resistance to the stress applied to the edge area of the substrates.
Furthermore, in accordance with another aspect of the present invention, by using a conductive paste for forming the support columns, the support columns can be formed simultaneously with the conductive connection areas (in particular, the top and bottom connection areas for connecting the conductive elements formed along the substrates that sandwich the liquid crystal cells) inside the liquid crystal panel, or the support columns can be used as the conductive connection area, and thus manufacturing costs can be reduced without any change in the number of processes or the process contents.
In accordance with an additional aspect of the present invention, by using a conductive ink containing carbon, the support column can be easily and precisely formed using a printing method.
In accordance with still a further aspect of the present invention, by using a material containing a phenol resin as the main ingredient for forming the support columns, the adhesion of the support columns to the substrates is relatively weak and the support columns possess an appropriate degree of flexibility, thus facilitating the cutting of the substrates which is performed during the manufacture of the liquid crystal display device, and avoiding the risk of cracking the substrates when they are cut at the areas where the support columns have been formed.
In accordance with still another aspect of the present invention, the use of a material that possess weaker adhesion strength than the material comprising the seal area for forming the support columns, facilitates the cutting of the substrates which is performed during the manufacture of the liquid crystal display device and avoids the risk of cracking the substrates when they are cut at the areas where the support columns have been formed.
In accordance with still an additional aspect of the present invention, by using a material that possesses the same hardening characteristics as the material comprising the seal area for forming the support columns, the support columns can be hardened simultaneously with the seal area during the manufacture of the liquid crystal display device. Thus, unlike in a case in which the support columns and the seal area are separately hardened, the substrate positioning accuracy used for hardening of the seal area can also be used for the support columns, avoiding increases in the number of manufacturing steps and the process time.
Moreover, the above-mentioned effects can be easily obtained simply by providing the support columns.
In accordance with yet an additional aspect of the present invention, by using material possessing the same hardening characteristics, e.g., thermohardening or photo-curing characteristics, for forming both the seal area and the support columns, the need for a new hardening process is eliminated because said seal area and said support columns can be hardened at the same time.
In accordance with yet a further aspect of the present invention, by forming the support columns simultaneously with and using the same material as the conductive connection areas, the support columns and said conductive connection areas can be positioned and formed using a single process, thus eliminating the need for a new manufacturing process for positioning and forming the support columns, and the above-mentioned effects can be obtained by merely changing the formation pattern of the conductive connection areas.
While the invention has been described in conjunction with several specific embodiments, it is evident to those skilled in the art that many further alternatives, modifications and variations will be apparent in light of the foregoing description. Thus, the invention described herein is intended to embrace all such alternatives, modifications, applications and variations as may fall within the spirit and scope of the appended claims.
Reference Numerals
1: Top substrate
2: Bottom substrate
3,4: Transparent electrodes
3a,4a: Electrode pads
5: Liquid crystal layer
6: Seal material
7: Insertion pin with leg
8.18: Mold materials
9.19: Support columns
10: Conductive connection area
11: Sealant
12: Conductive
20: Heat seal

Claims (36)

What is claimed is:
1. A liquid crystal display, comprising:
opposing first and second substrates defining a gap therebetween for sandwiching a liquid crystal medium, said first substrate including a plurality of external terminals formed an edge portion thereof, the gap having a predetermined length;
a molding member disposed on said edge portion of said first substrate and contacting a corresponding edge portion of said second substrate;
a sealing member interposing said first and second substrates for encapsulating said liquid crystal medium; and
a plurality of support members disposed external to said sealing member and proximate said molding member, each said support member substantially spanning the gap between said first and second substrate for maintaining the predetermined gap length in the presence of compressive force applied to said edge portions of said first and second substrates.
2. The liquid crystal display ofclaim 1, further comprising an external connection member electrically connected to said plurality of external terminals.
3. The liquid crystal display ofclaim 2, wherein said external connection member comprises a flexible substrate.
4. The liquid crystal display ofclaim 2, wherein said external connection member comprises a plurality of external pins.
5. The liquid crystal display ofclaim 1, wherein said support members comprises a phenol resin.
6. The liquid crystal display ofclaim 1, wherein
said sealing member comprises a first material having a first adhesion strength; and
wherein each said support member comprise a second material having a second adhesion strength weaker than the first adhesion strength.
7. The liquid crystal display ofclaim 1, wherein
said sealing member comprises a first material having a first cure rate; and
wherein each said support member comprises a second material having a second cure rate substantially equal to the first cure rate.
8. The liquid crystal display ofclaim 1, wherein said molding member applies the compressive force to said edge portions of said first and second substrates.
9. The liquid crystal display ofclaim 1, further comprising a conductive connector formed between the first and second substrates to provide an electrical pathway between electrodes formed on said first and second substrates.
10. The liquid crystal display ofclaim 9, wherein said conductive connector comprises a conductive paste, and wherein said plurality of support members essentially comprise the conductive path.
11. The liquid crystal display ofclaim 9, wherein said conductive connector comprises a conductive paste including a conductive ink containing carbon.
12. A method for manufacturing a liquid crystal display device encapsulating a liquid crystal medium between opposing first and second substrates, comprising the steps of:
forming a sealing member on the first substrate for surrounding the liquid crystal medium;
forming a plurality of support members on the first substrate proximate an edge portion thereof and external to the sealing member;
arranging the second substrate on the sealing member and the plurality of support members; and
forming a molding member between the first and second substrates proximate the plurality of support members.
13. The method for manufacturing a liquid crystal display device ofclaim 12, further comprising the step of forming a conductive connector for providing an electrical connection among electrodes disposed on the first and second substrates.
14. The method for manufacturing a liquid crystal display device ofclaim 12, wherein the sealing member and the support members exhibit substantially equal cure rates and are formed substantially simultaneously.
15. The method for manufacturing a liquid crystal display device ofclaim 14, further comprising the step of forming a conductive connector for connecting electrodes formed on one of said first and second substrates with external terminals formed on the remaining one of said first and second substrates simultaneously with said plurality of support members forming step, wherein the plurality of support members and conductive connector together comprise a first conductive material.
16. A liquid crystal display, comprising:
opposing first and second substrates defining a gap therebetween for internally sandwiching a liquid crystal layer, each said first and second substrates having a perimeter edge portion, the gap having a predetermined length;
a molding member disposed on and between said edge portions of said first substrate and second substrates for protecting said edge portions;
a sealing member interposing said first and second substrates for encapsulating said liquid crystal medium; and
a plurality of support members disposed external to said sealing member and proximate said molding member, each said support member substantially spanning the gap between said first and second substrate for maintaining the predetermined gap length in the presence of compressive force applied to said edge portions of said first and second substrates by said molding member.
17. The liquid crystal display ofclaim 16, further comprising:
a plurality of external terminals formed at said edge portion of said first substrate; and
an external connection member electrically connected to said external terminals for applying an electrical field to said liquid crystal layer.
18. The liquid crystal display ofclaim 17, wherein said external connection member comprises a flexible substrate.
19. The liquid crystal display ofclaim 17, wherein said external connection member comprises a plurality of external pins.
20. The liquid crystal display ofclaim 17, wherein said molding member fastens connection components electrically connected to external connection member.
21. The liquid crystal display ofclaim 16, wherein said plurality of support members comprise a phenol resin.
22. The liquid crystal display ofclaim 16, wherein
said sealing member comprises a first material having a first adhesion strength; and
wherein each said support member comprise a second material having a second adhesion strength weaker than the first adhesion strength.
23. The liquid crystal display ofclaim 16, wherein
said sealing member comprises a first material having a first cure rate; and
wherein each said support member comprises a second material having a second cure rate substantially equal to the first cure rate.
24. The liquid crystal display ofclaim 16, further comprising a conductive connector formed between the first and second substrates to provide an electrical pathway between electrodes formed on said first and second substrates.
25. The liquid crystal display ofclaim 24, wherein said conductive connector comprises a conductive paste, and wherein said plurality of support members essentially comprise the conductive paste.
26. The liquid crystal display ofclaim 24, wherein said conductive connector comprises a conductive paste including a conductive ink containing carbon.
27. A liquid crystal display, comprising:
opposing first and second substrates defining a gap therebetween for internally sandwiching a liquid crystal layer, each said first and second substrates having a perimeter edge portion, the gap having a predetermined length;
a molding member disposed on and between said edge portions of said first substrate and second substrates;
a sealing member interposing said first and second substrates for encapsulating said liquid crystal medium;
a plurality of support members disposed external to said sealing member and proximate molding member, each said support member substantially spanning the gap between said first and second substrate for maintaining the predetermined gap length in the presence of compressive force applied to said edge portions of said first and second substrates; and
a conductive connector formed between said first and second substrate electrically connecting electrodes formed on respective interior surfaces of said first and second substrates.
28. The liquid crystal display ofclaim 27, wherein said conductive connector and said plurality of support members all essentially comprise a conductive paste.
29. The liquid crystal display ofclaim 28, further comprising a plurality external terminals formed on an edge portion of said first substrate.
30. The liquid crystal display ofclaim 29, further comprising an external connection member electrically connected to said plurality of external terminals.
31. The liquid crystal display ofclaim 30, wherein said external connection member comprises a flexible substrate.
32. The liquid crystal display ofclaim 30, wherein said external connection member comprises a plurality of external pins.
33. A liquid crystal display, comprising:
opposing first and second substrates defining a gap therebetween for sandwiching a liquid crystal medium, said first substrate including a plurality of external terminals formed an edge portion thereof, the gap having a predetermined length;
a sealing member interposing said first and second substrates encapsulating said liquid crystal medium;
a molding member disposed on said edge portion of said first substrate externally from said sealing member and over said terminals, said molding member contacting a corresponding edge portion of said second substrate; and
a plurality of support members dispersed within said molding member external to said sealing member.
34. The liquid crystal display ofclaim 33, wherein said support members are disposed sporadically within said molding member.
35. The liquid crystal display ofclaim 33, wherein said support members are uniformly dispersed within said molding member.
36. A liquid crystal display, comprising:
a first substrate including a substantially planar face and a peripheral edge, said edge comprising a plurality of external terminals extending therefrom;
a liquid crystal medium disposed on said planar face of said first substrate;
a sealing member disposed on said planar face of said first substrate circumscribing said liquid crystal medium;
a second substrate disposed on said sealing member substantially parallel to and separated a predetermined gap length from said planar face of said first substrate to encapsulate said liquid crystal medium;
a molding member disposed on said edge of said first substrate external to said sealing member and proximate said terminals, said molding member extending into contact with said second substrate; and
a plurality of support members dispersed within said molding member between said first and second substrates and spanning the predetermined gap length.
US09/801,1791995-01-132001-03-05Liquid crystal display device and manufacturing method thereofExpired - LifetimeUSRE37945E1 (en)

Priority Applications (1)

Application NumberPriority DateFiling DateTitle
US09/801,179USRE37945E1 (en)1995-01-132001-03-05Liquid crystal display device and manufacturing method thereof

Applications Claiming Priority (6)

Application NumberPriority DateFiling DateTitle
JP7-0044831995-01-13
JP4483951995-01-13
JP7-2982751995-11-16
JP29827595AJP3769317B2 (en)1995-01-131995-11-16 Liquid crystal display device and manufacturing method thereof
US08/584,599US5717476A (en)1995-01-131996-01-11Liquid crystal display device and manfacturing method therefor
US09/801,179USRE37945E1 (en)1995-01-132001-03-05Liquid crystal display device and manufacturing method thereof

Related Parent Applications (1)

Application NumberTitlePriority DateFiling Date
US08/584,599ReissueUS5717476A (en)1995-01-131996-01-11Liquid crystal display device and manfacturing method therefor

Publications (1)

Publication NumberPublication Date
USRE37945E1true USRE37945E1 (en)2002-12-31

Family

ID=26338263

Family Applications (1)

Application NumberTitlePriority DateFiling Date
US09/801,179Expired - LifetimeUSRE37945E1 (en)1995-01-132001-03-05Liquid crystal display device and manufacturing method thereof

Country Status (2)

CountryLink
US (1)USRE37945E1 (en)
JP (1)JP3769317B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
US20030094305A1 (en)*2001-10-292003-05-22Advanced Display Inc.Pressure-welded structure of flexible circuit boards
US20100276183A1 (en)*2009-04-302010-11-04Nitto Denko CorporationFlexible printed circuit board
US9052551B2 (en)1999-07-062015-06-09Semiconductor Energy Laboratory Co., Ltd.Semiconductor device and method of fabricating the same
US9941335B2 (en)*2014-09-042018-04-10Samsung Display Co., Ltd.Display device
US10976617B2 (en)2017-12-222021-04-13Sakai Display Products CorporationDisplay apparatus and method for manufacturing display apparatus

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
US5973763A (en)*1996-10-161999-10-26Seiko Epson CorporationLiquid crystal device including supporting columns
JP2006113435A (en)*2004-10-182006-04-27Citizen Watch Co LtdOptical controller and liquid crystal display device
KR101123541B1 (en)2007-07-062012-03-12엘지디스플레이 주식회사Flat-light Unit and Liquid Crystal Display Device with the same
KR100803049B1 (en)2007-08-312008-02-22(주)제이피에스 마이크로텍 Method for producing flake aluminum oxide using microwave
KR101065402B1 (en)2009-08-132011-09-16삼성모바일디스플레이주식회사 Organic light emitting display

Citations (19)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
US4466701A (en)*1981-08-251984-08-21Optrex CorporationHighly reliable electrooptical device and process for manufacturing the same
EP0267688A1 (en)1986-10-131988-05-18Semiconductor Energy Laboratory Co., Ltd.Improvements relating to liquid crystal devices
JPH01289920A (en)1988-05-171989-11-21Tokyo Electric Co Ltd electrochromic display device
JPH0225892A (en)1988-07-151990-01-29Tokyo Electric Co LtdElectrochromic display
JPH02120888A (en)1988-10-311990-05-08Tokyo Electric Co Ltd image display device
JPH02187787A (en)1989-01-131990-07-23Tokyo Electric Co LtdDisplay panel device
US5042919A (en)*1987-05-011991-08-27Canon Kabushiki KaishaExternal-circuit connecting and packaging structure
US5067796A (en)*1987-01-261991-11-26Ricoh Company, Ltd.Liquid crystal display device with cut-out portions in lead electrodes for connection to driving circuit
KR920000601A (en)1990-06-151992-01-29시키모리야 Military management device of elevator
US5100695A (en)*1988-11-301992-03-31Nippon Cmk Corp.Method of manufacturing a printed circuit board
KR920008236A (en)1990-10-311992-05-27금성계전 주식회사 Inverter controller system of a radiator and its control method
US5187604A (en)*1989-01-181993-02-16Hitachi, Ltd.Multi-layer external terminals of liquid crystal displays with thin-film transistors
EP0528603A1 (en)1991-08-161993-02-24International Business Machines CorporationMethod for manufacturing liquid crystal display apparatus
KR940004291A (en)1992-08-171994-03-14김춘웅 Ice heat storage cooling system
KR940010488A (en)1992-10-281994-05-26세끼모또 다다히로 Charge pump circuit
US5317438A (en)*1991-08-291994-05-31Ricoh Company, Ltd.Liquid crystal display device and method of producing the same having an improved connection between a flexible film substrate and a drive circuit substrate
US5406164A (en)*1993-06-101995-04-11Brother Kogyo Kabushiki KaishaMultilayer piezoelectric element
US5467210A (en)*1993-02-161995-11-14Casio Computer Co., Ltd.Arrangement of bonding IC chip to liquid crystal display device
US5556670A (en)*1992-10-151996-09-17Casio Computer Co., Ltd.Liquid crystal display panel

Patent Citations (19)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
US4466701A (en)*1981-08-251984-08-21Optrex CorporationHighly reliable electrooptical device and process for manufacturing the same
EP0267688A1 (en)1986-10-131988-05-18Semiconductor Energy Laboratory Co., Ltd.Improvements relating to liquid crystal devices
US5067796A (en)*1987-01-261991-11-26Ricoh Company, Ltd.Liquid crystal display device with cut-out portions in lead electrodes for connection to driving circuit
US5042919A (en)*1987-05-011991-08-27Canon Kabushiki KaishaExternal-circuit connecting and packaging structure
JPH01289920A (en)1988-05-171989-11-21Tokyo Electric Co Ltd electrochromic display device
JPH0225892A (en)1988-07-151990-01-29Tokyo Electric Co LtdElectrochromic display
JPH02120888A (en)1988-10-311990-05-08Tokyo Electric Co Ltd image display device
US5100695A (en)*1988-11-301992-03-31Nippon Cmk Corp.Method of manufacturing a printed circuit board
JPH02187787A (en)1989-01-131990-07-23Tokyo Electric Co LtdDisplay panel device
US5187604A (en)*1989-01-181993-02-16Hitachi, Ltd.Multi-layer external terminals of liquid crystal displays with thin-film transistors
KR920000601A (en)1990-06-151992-01-29시키모리야 Military management device of elevator
KR920008236A (en)1990-10-311992-05-27금성계전 주식회사 Inverter controller system of a radiator and its control method
EP0528603A1 (en)1991-08-161993-02-24International Business Machines CorporationMethod for manufacturing liquid crystal display apparatus
US5317438A (en)*1991-08-291994-05-31Ricoh Company, Ltd.Liquid crystal display device and method of producing the same having an improved connection between a flexible film substrate and a drive circuit substrate
KR940004291A (en)1992-08-171994-03-14김춘웅 Ice heat storage cooling system
US5556670A (en)*1992-10-151996-09-17Casio Computer Co., Ltd.Liquid crystal display panel
KR940010488A (en)1992-10-281994-05-26세끼모또 다다히로 Charge pump circuit
US5467210A (en)*1993-02-161995-11-14Casio Computer Co., Ltd.Arrangement of bonding IC chip to liquid crystal display device
US5406164A (en)*1993-06-101995-04-11Brother Kogyo Kabushiki KaishaMultilayer piezoelectric element

Cited By (9)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
US9052551B2 (en)1999-07-062015-06-09Semiconductor Energy Laboratory Co., Ltd.Semiconductor device and method of fabricating the same
US9069215B2 (en)1999-07-062015-06-30Semiconductor Energy Laboratory Co., Ltd.Semiconductor device and method of fabricating the same
US9395584B2 (en)1999-07-062016-07-19Semiconductor Energy Laboratory Co., Ltd.Semiconductor device and method of fabricating the same
US20030094305A1 (en)*2001-10-292003-05-22Advanced Display Inc.Pressure-welded structure of flexible circuit boards
US6952250B2 (en)*2001-10-292005-10-04Advanced Display Inc.Pressure-welded structure of flexible circuit boards
US20100276183A1 (en)*2009-04-302010-11-04Nitto Denko CorporationFlexible printed circuit board
US8569629B2 (en)2009-04-302013-10-29Nitto Denko CorporationFlexible printed circuit board
US9941335B2 (en)*2014-09-042018-04-10Samsung Display Co., Ltd.Display device
US10976617B2 (en)2017-12-222021-04-13Sakai Display Products CorporationDisplay apparatus and method for manufacturing display apparatus

Also Published As

Publication numberPublication date
JP3769317B2 (en)2006-04-26
JPH08248436A (en)1996-09-27

Similar Documents

PublicationPublication DateTitle
US5717476A (en)Liquid crystal display device and manfacturing method therefor
US6466294B1 (en)Liquid crystal display panel using sealing adhesive containing conductive particles
US5556670A (en)Liquid crystal display panel
US6724448B2 (en)Liquid crystal display device and manufacturing method by compression bonding
US6989879B1 (en)Liquid crystal panel and method of fabricating the same
USRE37945E1 (en)Liquid crystal display device and manufacturing method thereof
JPS62218937A (en) lcd display panel
JPH0483227A (en) Liquid crystal display element and its manufacturing method
JPH04324825A (en)Liquid crystal display element and manufacture thereof
JP2004302133A (en) Optical modulation display element and manufacturing method thereof
JP2005122078A (en)Liquid crystal display and method for manufacturing the same
JP3633178B2 (en) Liquid crystal display device and manufacturing method thereof
JPH06265924A (en)Electro-optic device and its production
JP2001005020A (en)Structure for connecting electrode terminals of liquid crystal display panel
JPH06118425A (en) Liquid crystal display element
JPH02921A (en)Liquid crystal display panel
JPH11218775A (en)Liquid crystal display device and its production
JPH08293526A (en) Electrode terminal joining method and joining structure thereof
JPH04319918A (en)Active matrix type liquid crystal panel and its manufacture
JPS6155872A (en)Soldering structure of multiterminal
JPH04280036A (en)Flat type display
JP2003295216A (en)Liquid crystal display device
JP2000193981A (en)Sealing structure of liquid crystal panel substrate and method for sealing the same
JPH06331999A (en)Electrooptical device and its production
JPH02171724A (en)Terminal connecting method for liquid crystal display element

Legal Events

DateCodeTitleDescription
FEPPFee payment procedure

Free format text:PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

Free format text:PAYER NUMBER DE-ASSIGNED (ORIGINAL EVENT CODE: RMPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

CCCertificate of correction
FPAYFee payment

Year of fee payment:8

FPAYFee payment

Year of fee payment:12


[8]ページ先頭

©2009-2025 Movatter.jp