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US5308783A - Process for the manufacture of a high density cell array of gain memory cells - Google Patents

Process for the manufacture of a high density cell array of gain memory cells
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Publication number
US5308783A
US5308783AUS07/991,776US99177692AUS5308783AUS 5308783 AUS5308783 AUS 5308783AUS 99177692 AUS99177692 AUS 99177692AUS 5308783 AUS5308783 AUS 5308783A
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layer
gate
forming
depositing
oxide
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US07/991,776
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Wolfgang H. Krautschneider
Werner M. Klingenstein
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Mosaid Technologies Inc
Qimonda AG
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Siemens AG
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Assigned to SIEMENS COMPONENTS, INC.reassignmentSIEMENS COMPONENTS, INC.ASSIGNMENT OF ASSIGNORS INTEREST.Assignors: KLINGENSTEIN, WERNER M.
Assigned to SIEMENS COMPONENTS, INC.reassignmentSIEMENS COMPONENTS, INC.ASSIGNMENT OF ASSIGNORS INTEREST.Assignors: KRAUTSCHNEIDER, WOLFGANG H.
Assigned to SIEMENS AKTIENGESELLSCHAFTreassignmentSIEMENS AKTIENGESELLSCHAFTASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS).Assignors: SIEMENS COMPONENTS, INC.
Priority to KR1019930025241Aprioritypatent/KR100308076B1/en
Priority to AT93119790Tprioritypatent/ATE184424T1/en
Priority to EP93119790Aprioritypatent/EP0602525B1/en
Priority to DE69326312Tprioritypatent/DE69326312T2/en
Priority to JP34132893Aprioritypatent/JP3495071B2/en
Publication of US5308783ApublicationCriticalpatent/US5308783A/en
Application grantedgrantedCritical
Priority to HK98102937.5Aprioritypatent/HK1003755B/en
Assigned to INFINEON TECHNOLOGIES AGreassignmentINFINEON TECHNOLOGIES AGASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS).Assignors: SIEMENS AKTIENGESELLSCHAFT
Assigned to MOSAID TECHNOLOGIES INCORPORATEDreassignmentMOSAID TECHNOLOGIES INCORPORATEDASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS).Assignors: MOSAID TECHNOLOGIES INCORPORATED
Assigned to MOSAID TECHNOLOGIES INCORPORATEDreassignmentMOSAID TECHNOLOGIES INCORPORATEDASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS).Assignors: QIMONDA AG
Assigned to QIMONDA AGreassignmentQIMONDA AGASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS).Assignors: INFINEON TECHNOLOGIES AG
Assigned to ROYAL BANK OF CANADAreassignmentROYAL BANK OF CANADAU.S. INTELLECTUAL PROPERTY SECURITY AGREEMENT (FOR NON-U.S. GRANTORS) - SHORT FORMAssignors: 658276 N.B. LTD., 658868 N.B. INC., MOSAID TECHNOLOGIES INCORPORATED
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Abstract

A multistep process is disclosed that provides an economical process for making a gain memory cell array using self-aligned techniques; that provides an integrated diode in the gate stack of the storage transistor; that provides a buried VDD line to connect the drains of the storage transistors to the power supply; and that provides a buried strap to connect the integrated diode to the source region of the storage transistor.

Description

This invention relates to a process for the manufacture of gain memory cells. More particularly, this invention relates to a process for manufacturing a high density cell array of gain memory cells.
BACKGROUND OF THE INVENTION
Gain memory cells are advantageous because they deliver high signal charge, which makes possible very short access times and a simple signal sensing scheme. They comprise a combination of two transistors, an access and a storage transistor, and a diode connecting the source and the gate of the storage transistor.
Gain memory cells, like other devices for integrated circuits, are subject to increasing miniaturization for VLSI and ULSI circuits, e.g., down to 0.5 micron design rules and smaller. In order to make high density, high speed circuits, the processing needed to manufacture these circuits must take into account the minimizing of "real estate" or chip area requirements of the devices, and also the utilization of conventional processing steps and equipment already employed extensively in the semiconductor industry, to minimize the costs of manufacture.
Thus a practical and inexpensive process for the manufacture of gain memory cells has been sought.
SUMMARY OF THE INVENTION
The process of the invention provides for manufacture of high density gain memory cell arrays that feature shallow trench isolation of devices using a planar process, a diode integrated into the gate of the storage transistor, an implanted VDD line to eliminate contact connections of the transistors to the power supply, a buried strap to connect the diode to the source region of the storage transistor and self-aligned device isolation techniques. The present process minimizes the cell area requirements of the individual gain memory cells and of the cell array and maximizes cost effectiveness of gain memory cell manufacture using self-aligned process steps and a completely planar process.
The process comprises six series of steps; firstly, defining active device regions in a semiconductor substrate, e.g., a silicon wafer, and forming a gate and gate conductor stack; secondly, forming a diode integral with the gate stack; thirdly, defining the gates and ion implanting the source and drain regions of the transistors; fourthly, implanting a VDD line to connect the transistors to the power supply; fifthly, forming a buried strap to connect the diode to the source region of the storage transistor; and finally restructuring the gate, passivating and planarizing the device. The process of the invention uses self-aligning techniques and conventional processing steps to provide an economical process.
BRIEF DESCRIPTION OF THE DRAWING
FIGS. 1 to 12 are cross sectional views illustrating the structures obtained after various processing steps are performed.
DETAILED DESCRIPTION OF THE INVENTION
The present process provides in a first sequence of steps a planar process for defining active device regions using shallow trench isolation techniques for producing design rules in the 0.5 micron range and smaller. This isolation process includes etching to form shallow trenches, filling in the trenches with nitride and oxide depositions to isolate the device regions, and planarizing the resultant layer.
Planarizing can be achieved in any of the subsequently described planarizing steps in known manner by any kind of back etching or by using chemical mechanical polishing as disclosed by Davari et al, IEDM Techn. Dig (1989) p 89. Although illustrated by the shallow trench isolation process, active device regions can also be defined using known LOCOS techniques or channel stopper technologies. This is followed by carrying out a thermal oxide growth to form the transistor gate, and depositing polysilicon thereon as the gate conductor. A silicide layer is formed optimized to minimize sheet resistance of the wordline. The gate stack is formed by the subsequent deposition of nitride and oxide layers.
In a second sequence of steps, the diode is integrated into the gate stack. Openings are made in the gate stack for the deposition of polysilicon of a dopant type, which is opposite to the dopant type of the polysilicon of the gate conductor, siliciding the polysilicon, filling the openings with oxide and carrying out a planarizing step.
In a third sequence of steps, the first structuring of the gate conductor is carried out by RIE, and a nitride spacer is deposited. The source and drain regions of the transistors are formed by ion implantation.
In a fourth sequence of steps, an implanted VDD line is put down to eliminate contacts connecting the storage transistors to the power supply. A nitride layer is deposited, openings made in this layer photolithographically, ion implanting the VDD line and siliciding.
In a fifth sequence of steps, a buried strap is made by depositing a barrier nitride layer, depositing an oxide layer thereon, and planarizing the layers; forming openings in the oxide layer for deposition of polysilicon as the buried strap material, with a final deposition of an oxide layer and planarization thereof.
In a sixth and final sequence of steps, a second isolation is carried out, the storage gate is restructured, an oxide fill is used to passivate the device, and a final planarization is carried out.
The process will be further described with reference to the Drawing.
Referring now to the exemplary embodiment shown in FIG. 1, the surface of asilicon wafer 10 is cleaned in known manner to remove contaminants and particles from the surface. To form active regions using a shallow trench isolation technique,photoresist 12 is put down over the cleaned silicon wafer and patterned. The wafer is then etched to formopenings 13 therein using standard photo and etch techniques. The photoresist is then removed,oxide 14 is deposited (e.g., plasma enhanced CVD oxide or sub atmospheric CVD oxide) and the surface is planarized by etching or chemical mechanical polishing and cleaned. The resultant surface is shown in FIG. 2. For a clearer understanding of succeeding process steps, FIGS. 3-12 do not detail the device isolation in thesilicon wafer 10.
A siliconoxide gate layer 16 is thermally grown over the processedsilicon wafer 10. For simplicity, thislayer 16 is not shown on succeeding figures.
A gate stack is next formed by sequentially depositing an n-dopedpolysilicon layer 18, forming asilicide layer 20 thereover, and depositing anitride layer 22 and anoxide layer 24 over thenitride layer 22. The resultant gate stack is shown in FIG. 3.
An integrated diode comprising a polysilicon layer of one dopant type covered by a polysilicon layer of opposite dopant type is formed in the gate stack by forming anopening 25 by etching through to thesilicide layer 20 using photolithographic techniques as shown in FIG. 4. Thereafter a p+ dopedpolysilicon layer 26 is deposited in the opening. Thispolysilicon layer 26 can be deposited as undoped silicon followed by boron-doping by either ion implantation or diffusion techniques. The dopant concentration is chosen so that I(V) characteristics of the polysilicon diode is optimized with respect to the maximum signal charge and to short signal development time. This polysilicon deposition is followed by a siliciding step to form asecond silicide layer 28. This is shown in FIG. 5.
Subsequently, anoxide layer 30 is deposited (e.g., plasma enhanced CVD oxide or sub-atmospheric CVD oxide) and then the surface of the wafer is planarized by etching or chemical mechanical polishing and cleaned. The resultant structure is shown in FIG. 6.
The gate stacks are now structured by photolithographically patterning thenitride layer 22 and etching through the gate stack comprising thenitride layer 22, thesilicide layer 20 and thepolysilicon layer 18, thegate oxide layer 16 and the diode portion comprising the filledoxide 30 over thesilicide layer 28 and thepolysilicon layer 26 using reactive ion etching techniques. Aspacer nitride layer 32 is deposited and etched to form nitride spacers along the sides of the formed gate stack and the planarized diodes. This structure is shown in FIG. 7.
Thetransistor source 34 anddrain 36 regions are next ion implanted into thesilicon wafer 10. This ion implant is optimized to form dopant levels in the source anddrain regions 34, 36 with respect to minimizing cell leakage current. The source and drain regions are thus aligned with the edges of the integrated diode regions, achieving minimum geometric size for the gain memory cells. Further, this allows processing of the diode with a non-critical structure size that is much greater than the minimum geometry size.
The VDD line is to be made next. Anitride barrier layer 38 is deposited and patterned to expose thedrain region 36 and then a layer ofsilicide 37 is deposited over thedrain region 36. This structure is shown in FIG. 8.
Additionally, the dopant concentration of thedrain region 36 can be increased by ion implantation to achieve a low sheet resistance of the VDD line. This implanted line permits contactless connection of the drains of the storage transistors to the power supply.
A buried strap is formed next to connect the diode to the source region of the storage transistor using a low resistive material. Abarrier nitride layer 42 is deposited and then athick oxide layer 44 deposited thereover, see FIG. 9, for planarization and definition of the buried strap using photolithography. Thethick oxide layer 44 is planarized andopenings 45 made therein for formation of the buried strap. This structure is shown in FIG. 10.
A layer ofpolysilicon 46 is deposited into theopenings 45 which are then filled withoxide 48. The resultant structure is then planarized and is shown in FIG. 11.
The buried strap to connect the integrated diode to the source region of the storage transistor is a basic feature of the present gain memory cell. Although a particular process using polysilicon has been described for making the buried strap, it will be apparent to those skilled in the art that other processes can be used to connect the diode to the source region of the storage transistor using a low resistance material.
A second device isolation is carried out by selectively removing oxide except for leaving some oxide over the p-n contact regions and opening recesses 50 and 52 in theoxide layer 44. This can be done in a self-aligned manner using photolithographic patterning and selectively etching the polysilicon down to the oxide which covers the p-n junction. The final self-aligned structure is shown in FIG. 12.
The cell array is completed by structuring the storage transistor gate using a second isolation technique, e.g., a shallow trench isolation process, passivating with an oxide fill and performing a final planarization.
Although the present process has been illustrated in terms of particular embodiments and sequence of process steps, various changes can be made in the steps and their sequence without departing from the essence of the invention, and are meant to be included herein. The scope of the invention is meant only to be defined by the appended claims.

Claims (6)

We claim:
1. A process for making an array of gain memory cells comprising an access transistor, a storage transistor and a diode, which comprises
a) defining active device regions in a semiconductor substrate by etching a plurality of shallow trenches in said substrate, filling said trenches with a dielectric material and planarizing the surface of said substrate;
b) forming a transistor gate stack by forming a thermal silicon oxide layer to form a transistor gate insulator and depositing a polysilicon layer thereover to form a gate conductor, forming a silicide layer thereover to minimize sheet resistance and depositing a layer of dielectric material thereover;
c) integrating a diode into the gate stack formed in step b) by forming an opening in said gate stack, depositing polysilicon of a conductivity type opposite to that of the polysilicon gate conductor in said opening, forming a silicide layer thereover, filling said opening with silicon oxide and planarizing said opening;
d) structuring the gate to form a plurality of gate stacks by etching through the gate stack layers to the surface of said substrate and depositing a spacer layer onto the sidewalls of the resultant gate stacks;
e) ion implanting source and drain regions between the gate stacks formed in step d), thereby completing a plurality of transistors;
f) forming a VDD line to connect the transistors formed in step e) to the power supply by depositing a nitride layer, forming openings in said nitride layer to expose the drain regions in said substrate, ion implanting through said openings and forming a silicide layer over the drain regions;
g) forming a buried strap to connect the integrated diodes formed in step c) to the source regions of the storage transistors formed in step b) by depositing a barrier nitride layer and a first oxide layer thereover, planarizing said layers, forming openings in said first oxide and said nitride layers, depositing a low resistivity material in said openings as the buried strap material, and filling said openings with a second oxide layer;
h) restructuring the gate stacks formed in step b) by etching the oxide over a portion of the gate stacks, depositing a silicon oxide layer, passivating the resultant gain memory devices by depositing a layer of silicon oxide thereover and planarizing the resultant array of gain memory devices.
2. A process according to claim 1 wherein defining the active device regions comprises filling the trenches with silicon nitride and silicon oxide to isolate the device regions.
3. A process according to claim 1 wherein the gate conductors are formed by reactive ion etching.
4. A process according to claim 1 wherein the dielectric material of steb b) comprises layers of silicon nitride and silicon oxide.
5. A process according to claim 1 wherein the low resistivity material deposited in step g) is polysilicon.
6. A process according to claim 5 wherein the second oxide layer is planarized.
US07/991,7761992-12-161992-12-16Process for the manufacture of a high density cell array of gain memory cellsExpired - LifetimeUS5308783A (en)

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Application NumberPriority DateFiling DateTitle
US07/991,776US5308783A (en)1992-12-161992-12-16Process for the manufacture of a high density cell array of gain memory cells
KR1019930025241AKR100308076B1 (en)1992-12-161993-11-25 How to manufacture a gain memory cell with a high density cell array
EP93119790AEP0602525B1 (en)1992-12-161993-12-08Process for the manufacture of a high density cell array of gain memory cells
AT93119790TATE184424T1 (en)1992-12-161993-12-08 PRODUCTION METHOD FOR A HIGH DENSITY MEMORY CELL ARRANGEMENT OF THE GAIN CELL TYPE
DE69326312TDE69326312T2 (en)1992-12-161993-12-08 Manufacturing method for a high density memory cell arrangement of the gain cell type
JP34132893AJP3495071B2 (en)1992-12-161993-12-10 Method of manufacturing an array of gain memory cells
HK98102937.5AHK1003755B (en)1992-12-161998-04-08Process for the manufacture of a high density cell array of gain memory cells

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US07/991,776US5308783A (en)1992-12-161992-12-16Process for the manufacture of a high density cell array of gain memory cells

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US07/991,776Expired - LifetimeUS5308783A (en)1992-12-161992-12-16Process for the manufacture of a high density cell array of gain memory cells

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US (1)US5308783A (en)
EP (1)EP0602525B1 (en)
JP (1)JP3495071B2 (en)
KR (1)KR100308076B1 (en)
AT (1)ATE184424T1 (en)
DE (1)DE69326312T2 (en)

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US5543348A (en)*1995-03-291996-08-06Kabushiki Kaisha ToshibaControlled recrystallization of buried strap in a semiconductor memory device
US5587331A (en)*1992-12-191996-12-24Goldstar Electron Co., Ltd.Method of forming a contact hole for a metal line in a semiconductor device
US5677563A (en)*1994-05-191997-10-14International Business Machines CorporationGate stack structure of a field effect transistor
US5732014A (en)*1997-02-201998-03-24Micron Technology, Inc.Merged transistor structure for gain memory cell
US5854500A (en)*1995-09-261998-12-29Siemens AktiengesellschaftDRAM cell array with dynamic gain memory cells
US5905279A (en)*1996-04-091999-05-18Kabushiki Kaisha ToshibaLow resistant trench fill for a semiconductor device
US6025220A (en)*1996-06-182000-02-15Micron Technology, Inc.Method of forming a polysilicon diode and devices incorporating such diode
US6436760B1 (en)*2001-04-192002-08-20International Business Machines CorporationMethod for reducing surface oxide in polysilicon processing
US20040042256A1 (en)*2002-08-292004-03-04Micron Technology, Inc.Single transistor vertical memory gain cell
US20040041236A1 (en)*2002-08-292004-03-04Micron Technology, Inc.Merged mos-bipolar capacitor memory cell
US20040061190A1 (en)*2002-09-302004-04-01International Business Machines CorporationMethod and structure for tungsten gate metal surface treatment while preventing oxidation
US20040108532A1 (en)*2002-12-042004-06-10Micron Technology, Inc.Embedded DRAM gain memory cell
US6804142B2 (en)2002-11-122004-10-12Micron Technology, Inc.6F2 3-transistor DRAM gain cell
US20050024936A1 (en)*2003-03-042005-02-03Micron Technology, Inc.Vertical gain cell
US6979651B1 (en)*2002-07-292005-12-27Advanced Micro Devices, Inc.Method for forming alignment features and back-side contacts with fewer lithography and etch steps
US20080097189A1 (en)*2006-09-122008-04-24General Electric CompanyCombined MR imaging and tracking
US10190390B2 (en)2012-10-152019-01-29Baker Hughes, A Ge Company, LlcPressure actuated ported sub for subterranean cement completions

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US5587331A (en)*1992-12-191996-12-24Goldstar Electron Co., Ltd.Method of forming a contact hole for a metal line in a semiconductor device
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US20040061190A1 (en)*2002-09-302004-04-01International Business Machines CorporationMethod and structure for tungsten gate metal surface treatment while preventing oxidation
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US6975531B2 (en)2002-11-122005-12-13Micron Technology, Inc.6F2 3-transistor DRAM gain cell
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US6804142B2 (en)2002-11-122004-10-12Micron Technology, Inc.6F2 3-transistor DRAM gain cell
US7151690B2 (en)2002-11-122006-12-19Micron Technology, Inc.6F2 3-Transistor DRAM gain cell
US7030436B2 (en)2002-12-042006-04-18Micron Technology, Inc.Embedded DRAM gain memory cell having MOS transistor body provided with a bi-polar transistor charge injecting means
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US20040108532A1 (en)*2002-12-042004-06-10Micron Technology, Inc.Embedded DRAM gain memory cell
US6956256B2 (en)2003-03-042005-10-18Micron Technology Inc.Vertical gain cell
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US20070158722A1 (en)*2003-03-042007-07-12Micron Technology, Inc.Vertical gain cell
US7298638B2 (en)2003-03-042007-11-20Micron Technology, Inc.Operating an electronic device having a vertical gain cell that includes vertical MOS transistors
US20050032313A1 (en)*2003-03-042005-02-10Micron Technology, Inc.Vertical gain cell
US7528440B2 (en)2003-03-042009-05-05Micron Technology, Inc.Vertical gain cell
US20050024936A1 (en)*2003-03-042005-02-03Micron Technology, Inc.Vertical gain cell
US20080097189A1 (en)*2006-09-122008-04-24General Electric CompanyCombined MR imaging and tracking
US8583213B2 (en)2006-09-122013-11-12General Electric CompanyCombined MR imaging and tracking
US10190390B2 (en)2012-10-152019-01-29Baker Hughes, A Ge Company, LlcPressure actuated ported sub for subterranean cement completions

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KR940016777A (en)1994-07-25
JP3495071B2 (en)2004-02-09
ATE184424T1 (en)1999-09-15
HK1003755A1 (en)1998-11-06
EP0602525B1 (en)1999-09-08
DE69326312D1 (en)1999-10-14
KR100308076B1 (en)2001-12-15
DE69326312T2 (en)2000-02-17
JPH06216330A (en)1994-08-05
EP0602525A1 (en)1994-06-22

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