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US3775231A - Multiple embossed flexible web - Google Patents

Multiple embossed flexible web
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US3775231A
US3775231AUS00187775AUS3775231DAUS3775231AUS 3775231 AUS3775231 AUS 3775231AUS 00187775 AUS00187775 AUS 00187775AUS 3775231D AUS3775231D AUS 3775231DAUS 3775231 AUS3775231 AUS 3775231A
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threads
embossing
resilient
fabric
web
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US00187775A
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G Thomas
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Kimberly Clark Corp
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Kimberly Clark Corp
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Abstract

A flexible reinforced web of creped cellulosic tissue and a nonwoven reinforcing scrim having two or more embossments repeated continuously along the length of the web and superimposed on but out of register with each other. The embossments are formed by passing the web through two or more embossing stations on the surface of a single embossing roll, and drawing the web away from the surface of the embossing roll between successive embossing stations. The flexible web may be made of creped cellulosic tissue or other substantially nonresilient material, and reinforced with resilient threads or other elements extending continuously in the longitudinal direction of the web so as to maintain a constant web length between pairs of successive embossing stations.

Description

1 Nov. 27, 1973 3,307,992 3/1967 Condon et a1. 3,424,643 l/1969 .Lewis, Jr. et a1. 3,597,299 8/1971 Thomas et a1. Primary Examiner-George F. Lesmes Assistant Examiner-Charles E. Lipsey Att0rneyC. Frederick Leydig et al.
[57] ABSTRACT A flexible reinforced web of creped cellulosic tissue and a nonwoven reinforcing scrim having two or more embossments repeated continuously along the length of the web and superimposed on but out of register with each other. The embossments are formed by passing the web through two or more embossing stations on the surface of a single embossing roll, and drawing the web away from the surface of the embossing roll between successive embossing stations. The flexible web may be made of creped cellulosic tissue or other substantially non-resilient material, and reinforced with resilient threads or other elements extending continuously in the longitudinal direction of the web so as to maintain a constant web length between pairs of successive embossing stations.
United States Patent [191 Thomas 1 MULTIPLE EMBOSSED FLEXIBLE WEB [75 Inventor: Gordon D. Thomas, Neenah, Wis.
[73] Assignee: Kimberly-Clark Corporation,
Neenah, Wis.
[22] Filed: Oct. 8, 1971 [21] Appl. No.: 187,775
Related US. Application Data [63] Continuation-impart of Ser. No. 785,508, Dec. 20,
1968, Pat. No. 3,611,919.
[52] US. 161/57, 156/179, 156/220, 156/291, 161/116, 161/129, 161/141, 161/146, 161/D1G. 3, 101/32 [51] Int. B32 b 5/ 12 [58] Field of 161/116, 57, 58, 161/59,125,128,129,141,146,148,156, 166, DIG. 3; 156/219, 220, 179; 101/23, 32, 1 01/22 [56] References Cited UNITED STATES PATENTS 5 7337 52 .58 ll llGl 60 6 11D16 '1 mm a Q a a M da S "Y0 a a-DON m "d wh o nm c h e k TGBHHF 380935 704566 999999 111111 509 6 3235 8209 .3 87622 08 07 .9 3 223 1?: 1 1 l 1 1 1 1 1 1 1 l 1 1 I 1 MULTIPLE EMBOSSED FLEXIBLE WEB CROSS REFERENCE TO RELATED APPLICATIONS This application is a continuation-in-part of application Ser. No. 785,508 filed Dec. 20, 1968, now US. Pat. No. 3,611,9l9. I
This application is also directed to subject matter related to the following applications:
Ser. No. 725,067 filed Apr. 29, 1968 now US. Pat. No. 3,546,056
Ser. No. 21,269 filed Mar. 20, 1970 Ser. No. 150,152 filed June 4, 1971, now US. Pat. No. 3,708,383.
BACKGROUND OF THE INVENTION The present invention relates to a nonwoven material particularly useful for wipe and toweling applications, and which is made of outer layers of creped cellulosic tissue reinforced by an open mesh scrim.
As disclosed in my U.S. Pat. No. 3,546,056, I have found that such material made of wet strengthened high stretch tissue and provided withpuff zones of such tissue protruding through the windows of the scrim has improved product toughness, dry and wet bulk and the like. According to that patent, puff zones may be produced in such material by incorporating a scrim with heat shrinkable threads, and subjecting the material to heat in the course of the manufacturing process. Furthermore, increased liquid absorbency and surface texture may be obtained as stated in said patent by pin ,embossing the material through the puff zones, perforating the material and causing small protruberances on one surface of the sheet. Such meterials with and without puff zones have been marketed bythe assignee'hereof and found effective as indicated in said patent for heavy duty industrial wipes, heavy duty toweling and the like.
However, there has been a need for a household towel providing generally the same features as such material, buthaving a low enough cost to be sold in the household market.
It was my primary objective, which resulted in this invention, to provide a lower cost and higher bulk towel material having generally the same features as the heavy duty towel material as specified in my prior patent; that is, substantial strength, dimensional stability, high liquid absorbency, toughness, flexibility and softness. The higher bulk was sought as a contribution not only to higherliquid absorbency, but also tosatisfy a marketing objective where the towel material was aimed for sale in the household market in roll form; namely, to provide a greater roll diameter for a given length of towel material, or number of sheets per roll.
Pin embossed scrim reinforced tissue material, subsequently heavily embossed in a singleembossing station to enhance bulk and absorbency, was tested as a household towel material but such material was not bulky enough to completely satisfy my objectives. One of the problems was that as the embossing pressureswere increased to enhance bulk, the material was overstressed and the threads were. ruptured orv nicked by the pin embossing, reducing the strength of the material. Description of. the Invention According to the present invention, higher bulk and absorbency is obtained with. lower stretch (and lower cost) creped cellulosic tissue without pin embossing, by
' is obtained by incorporating a reinforcing scrim having resilient threads which yield in the embossing nip and spring back to their original dimensions and configuration as soon as the embossing pressure is released in each successive embossing operation.
The present invention thus relates generally to embossing flexible webs and, more particularly, to a flexible web having two or more embossments repeated continuously along the length of the web.
It is a primary object of the present invention to provide an improved flexible web having two or more outof-register embossments which can be formed repetitively along the length of the web by using a single embossing roll. A releated object of the invention is to provide such a flexible web which is made of reinforced creped cellulosic tissue or other substantially nonresilient but stretchable material.
A further object of the invention is to provide an improved embossed flexible web of the type described above which can be efficiently produced at high production rates.
Still another object of the present invention is to provide an improved reinforced web of cellulosic tissue with relatively high bulk and texture which can be produced using relatively low emobssing pressures.
Other objects and advantages of the invention will become apparent from the following detailed description taken in connection with the accompanying drawings, in which:
FIG. 1 is a partially schematic end elevation of an embossing method and apparatus for producing an embossed flexible web embodying the invention;
FIG. 2 is a schematic plan view of an embossed flexible web formed by the method and apparatus illustrated in FIG. 1; and
FIG. 3 is a schematic'plan view of a reinforced paper web for use in the embossing method and apparatus illustrated in FIG. 1.
While the invention is susceptible of various modifications and alternative forms, certain specific embodiments thereof have been shown by way of example in the drawings which will be described in detail herein. It should be understood, however, that it is not intended to limit the invention to the particular forms disclosed, but, on the contrary, the intention is to cover all modifications, equivalents and alternatives falling within the spirit and scope of the invention.
Turning now to the drawings, and referring first to FIG. 1, a continuous web 10 of flexible material is drawn around an inlet roller 11 and continuously advanced under a guide roll 11a into engagement with a drivenembossing roll 12 at a first embossing station where the web is pressed firmly against the surface of the embossing roll to form a first embossment in the web. More particularly, the web 10 is drawn through the nip formed by themetal embossing roll 12 and a first rubber roll 13 so as to form a first series of repetitive embossments along the length of the web 10. As can be seen in FIG. 1, the guide roll 11a is located to feed the web 10 into the nip of the rolls l2 and 13 along a common tangent line for the two rolls. The embossments formed at this first embossing station are illustrated schematically in FIG. 2 as embossments A repeated continuously along the length of the web 10. The repetition rate of the embossments A may be varied by a number of factors, including the diameter of theembossing roll 12 and the rate of repetition, if any, of the embossing pattern on the surface of theroll 12. For example, if the pattern of the embossing surface on theroll 12 repeats itself every inches around the circumference of theroll 12, then the length of each embossment A illustrated in FIG. 2 will also be 10 inches, i.e., the embossments A will be repeated every 10 inches continuously along the length of the web 10.
In accordance with an important aspect of the present invention, the embossed web is continuously withdrawn from the first embossing station, drawn away from the surface of the embossing roll, and then passed through a second embossing station on the surface of the same embossing roll used to form the embossments at the first station. Thus, in the illustrative embodiment shown in FIG. 1, the embossed web 10 is continuously withdrawn from the nip of therolls 12 and 13 and drawn away from the surface of theembossing roll 12 over a guide roll 14a. From the guide roll 14a, the embossed web is returned to the surface of the drivenembossing roll 12 over a second guide roll 14b, and passed through a second embossing station formed by the nip of themetal embossing roll 12 and a second rubber roll 15. As can be seen in FIG. 1, the second guide roll 14b is located to feed the web 10 into the nip of therolls 12 and 15 on a common tangent line for the two rolls. As the web is passed through the nip of therolls 12 and 15, it is again pressed firmly against the surface of theroll 12 to form a second embossment in the web. These second embossments are illustrated schematically in FIG. 2 as embossments B repeated continuously along the length of the web 10, with the repetition rate being determined by the same factors discussed above in connection with the first embossments A.
It is important that the embossments formed at the second embossing station be out of register with the embossments formed at the first embossing station, so that the maximum area of the web is embossed, and to avoid overstressing any given portion of the web material. Consequently, if the embossing pattern on the surface of themetal roll 12 repeats itself around the circumference of theroll 12, the locations of the rubber rolls l3 and 15, the rate of advancement of the web 10, and the distance that the web 10 is drawn away from the surface ofroll 12 by the guide rolls 14a and 14b must be selected so that the embossments formed at the successive embossing stations are out of register with each other. In one example of the illustrative embodiment, theembossing roll 12 has a diameter of inches with an embossing pattern that repeats itself every 10 inches around the circumference of the roll; theembossing roll 12 is driven at a rate sufficient to provide a web speed of 500 feet per minute; the embossing stations are located at the angular positions shown in FIG. 1; and the centers of the guide rolls 14a and 14b are located 36 and 28 inches, respectively, from the center of the drivenembossing roll 12.
It will be understood that any desired number of additional embossing stations may be provided around the circumference of theembossing roll 12, depending upon the characteristics desired in the final embossed web. Thus, in the illustrative embodiment, a third embossing station is provided by a third rubber roll 16 bearing against the outer surface of theroll 12. As the double-embossed web 10 emerges from the nip of the second rubber roll 15 and theembossing roll 12, the web is drawn outwardly away from the surface of theembossing roll 12 and over a guide roll 17a. From the guide roll 17a the double-embossed web is returned under a second guide roll 17b to the surface of theroll 12, and then passed through the third embossing station formed by the nip of the third rubber roll 16 and themetal embossing roll 12. As in the case of guide rolls 11a and 14b described previously, the second guide roll 17b is positioned so that the web 10 is fed into the nip of the rolls l6 and 12 on a common tangent line for the two rolls.
As the web is passed through the nip of the rolls l6 and 12, it is once again pressed firmly against the surface of themetal roll 12 to form a third embossment in the web. These third embossments are illustrated schematically in FIG. 2 as embossments C repeated continuously along the length of the web 10, with the repetition rate being determined by the same factors discussed above in connection with embossment A. It is again important that the embossments C be out of register with the embossments A and B, and in the particular example described previously the centers of the guide rolls 17a and 17b are located 63 and 32 inches, respectively, from the center of theembossing roll 12. The resulting triple-embossed web emerging from the nip of therolls 16 and 12 is withdrawn from the embossing machine as at 20 for winding or further processing.
In order to maintain the rubber rollers 13, 15 and 16 at a temperature sufficiently low to prevent degradation of the rubber, the rollers are preferably water cooled. In general, it is desirable to prevent the temperature from rising above about 200 F. at any point in the rubber, which is generally in the form of a cover on the outer surface of a hollow metal drum. To facilitate cooling, the rubber cover is typically made as thin and hard as possible, consistent with good embossing perforrnance.
In accordance with another important aspect of the present invention, the web to be embossed is made of paper or other substantially non-resilient material, and is reinforced in the longitudinal or machine direction by continuous threads or other reinforcing members made of a resilient material. It has been found that the non-resilient material is permanently stressed during the embossing operation, whereas the resilient reinforcing elements tend to spring back to their original dimensions and configuration as soon as the embossing pressure is released. Consequently, a substantially constant web length is maintained between successive embossing stations. Without the resilient reinforcing elements extending continuously in the machine direction in the web, the web continuously acquires a permanent stretch at each embossing station, so that the web length between each pair of successive embossing stations gradually increases.
In accordance with one specific aspect of the present invention, the embossed web comprises a pair of flexible layers of cellulosic tissue, and an open mesh, nonwoven web of crossed threads interposed between the layers of cellulosic tissue, with at least the warp threads of the crossed-thread web being made of a resilient material. Thus, it has been found that the embossing method and apparatus provided by this invention are particularly suitable for embossing the type of web shown in FIG. 3. More Specifically, theweb 30 in FIG. 3 includes twolayers 31 and 32 of non-woven cellulosic tissue or wadding with a non-woven fabric 33 of crossedthreads 34 and 35 interposed and adhesively bonded between thelayers 31 and 32. In the preferred embodiment, eachlayer 31 and 32 is formed of two plys 31a, 31b and 32a, 32b, respectively, of creped cellulosic tissue. The cellulosic tissue preferably has a drier basis weight before creping of from about 4 to about 12 pounds per 2,880 square foot ream, with a crepe ratio before stretching and pressing of from about 1.1 to about 2.5 as it is creped off the dryer of the paper machine. The creped tissue is typically stretched and pressed after creping to reduce the original high crepe ratio to about 1.1 to 1.8 in order to produce a soft sheet such as is customarily used in the manufacture of facial tissue.
In the central layer 33 of nonwoven fabric, the till threads 35, i.e., the threads which extend in the transverse direction, are all on the same side of thewarp threads 34, i.e., the threads which extend in the longitudinal or machine direction, with the two sets of threads disposed in face-to-face relation to each other and adhesively bonded together where the threads of one set cross the threads of the other set. For the purposes of the present invention, it is preferred that the crossedthread fabric have a relatively low thread count, e.g., two to three threads per inch in both directions to provide a relatively high bulk in the final embossed product. The threads in each of the two cross-laid sets normally run parallel to each other and are uniformly spaced. The adhesive is normally applied'to both sets of threads in order to achieve the most effective bonding of the non-woven fabric 33 to theoutside layers 31 and 32 of cellulosic tissue, although adhesive may be applied to only one of the two sets of threads if desired. It will be understood that the term threads is intended to include both monofilament and multifilament structures, although multifilament structures are generally preferred in non-woven fabrics of this type.
Non-woven laminates of the type illustrates in FIG. 3 are known per se in the art, as exemplified by US. Pat. No. 3,072,511 to KJ. Harwood. When a web of such material is to be embossed by the method and apparatus of the present invention, it is important that at least thewarp threads 34 be made of a resilient material, such as 40 denier high tenacity nylon or comparable polyester or rayon, for example. Whereas the cellulosic tissue layers 31 and 32 are permanently stressed during the embossing operation, to provide the resulting embossed laminate with the desired bulk and texture, theresilient warp threads 34 are only temporarily distorted during the embossing operation, and tend to spring back to their original configuration as soon as the embossing pressure is released so that a substantial portion of the stretched tissue in the windows of the scrim protrudes out of the plane of the material. Thus, the resilient reinforcingwarp threads 34 prevent any permanent elongation of the laminated web at any given embossing station, so that a substantially constant web length is maintained between successive embossing stations.
One of the significant advantages of the present invention is that the flexible web may be embossed to any desired degree by'using a single embossing roll, and yet the embossing pressure required at each embossing station may be sufficiently low to provide a long operating life for the embossing equipment, particularly the rolls l3, l5 and 16 which are conventionally made of rubber, and which cooperate with the metal embossing roll to form the embossing stations. For example, if the same degree of embossing attainable with the threestation arrangement shown in FIG. 1 were to be achieved with a single embossing station, the embossing pressure required would be so great that the risk of failure of the rubber roll from heat build-up would render the operation unfeasible. Furthermore, supplemental operations such as pin embossing and the like are not necessary to improve the response of the flexible web to the main embossing operation, because the desired yieldability, bulk, and embossing response is improved in each subsequent embossing station, and it is simply a matter of providing the necessary number of such stations around the single embossing roll.
I claim as my invention:
1. A web of nonwoven material comprising the com- 7 bination of at least two layers of stretchable, soft cellulosic tissue and a fabric made of open-mesh threads interposed between the layers of cellulosic tissue and bonded thereto, said fabric including a first set of substantially parallel threads spaced from each other and extending in a first direction and a second set of substantially parallel threads spaced from each other and extending in a second direction so as to cross said first set of threads, any of said first and second sets of threads that extend in the longitudinal direction of said web being made of a resilient material, the composite material formed by said tissue and said fabric having been embossed under pressure repetitively by patterned embossing means to form embossments repeated continuously along the length thereof and superirnposed on each other but out of register with each other with a substantial portion of the cellulosic tissue protruding beyond said threads to increase the bulk, yieldability and surface texture of the material, the cellulosic tissue having been permanently stretched by the embossing of the composite material without overstressing the threads.
2. A web of nonwoven material as set forth in claim 1 wherein the thread count of said threads is between about two and three threads per inch.
3. An improved nonwoven towel material comprising the combination of a central layer of fabric made of openmesh crossed stretchable threads spaced from one another, at least one set of the threads being both stretchable and resilient, and a layer of stretchable, soft cellulosic tissue adhesively bonded to each of the opposite faces of said central layer of fabric, the composite material formed by said fabric layer and said cellulosic layers having been embossed under pressure repetitively by similarly patterned embossing means to form similar embossments repeated continuously along the length of the material and superimposed on but out of register with each other, the non-resilient cellulosic tissue and any non-resilient fabric threads having been permanently stretched by the embossing pressure without overstressing any given portion of the material including the threads, and the threads which are both resilient and stretchable having been temporarily distorted and allowed to spring back to substantially their original dimensions and configuration as the embossing pressure is released, so that a substantial portion of the cellulosic tissue protrudes through the windows of the open mesh fabric and beyond the opposite faces thereof to increase the bulk, yieldability and surface texture.
4. An improved nonwoven towel material comprising the combination of a central layer of fabric made of open-mesh crossed stretchable threads spaced from one another, at least one set of the threads being both stretchable and resilient, and a layer of stretchable, soft cellulosic tissue adhesively bonded to each of the opposite faces of said central layer of fabric, the composite material formed by said fabric layer and said cellulosic layers having been embossed under pressure repetitively at two or more stations spaced around a single rigid metal embossing roll wherein the material is pressed against said roll by a resilient roll to form similar embossments repeated continuously along the length of the material and superimposed on but out of register with each other, the non-resilient cellulosic tissue and any non-resilient fabric threads having been permanently stretched by the embossing pressure at each station without overstressing any given portion of the material including the threads, and the threads which are both resilient and stretchable having been temporarily distorted by the embossing pressure at each station and allowed to spring back to substantially their original dimensions and congiguration as the embossing pressure is released, to increase the material bulk, yieldability and surface texture.
5. An improved nonwoven towel material comprising the combination of a central layer of fabric made of open-mesh crossed stretchable threads spaced from one another, at least one set of the threads being both stretchable and resilient, and a layer of stretchable, soft cellulosic tissue adhesively bonded to each of the opposite faces of said central layer of fabric, the composite material having been pressure embossed repetitively through the windows of the scrim with a similar embossment pattern to form similar embossments repeated continuously along the length of the material and superimposed on but out of register with each other, the non-resilient cellulosic tissue and any nonresilient fabric threads having been permanently stretched by the embossing pressure without overstressing any given portion of the material including the threads, and the threads which are both resilient and stretchable having been temporarily distorted by the embossing pressure and allowed to spring back to substantially their original dimensions and configuration as the embossing pressure is released, to increase the material bulk, yieldability and surface texture.

Claims (5)

1. A web of nonwoven material comprising the combination of at least two layers of stretchable, soft cellulosic tissue and a fabric made of open-mesh threads interposed between the layers of cellulosic tissue and bonded thereto, said fabric including a first set of substantially parallel threads spaced from each other and extending in a first direction and a second set of substantially parallel threads spaced from each other and extending in a second direction so as to cross said first set of threads, any of said first and second sets of threads that extend in the longitudinal direction of said web being made of a resilient material, the composite material formed by said tissue and said fabric having been embossed under pressure repetitively by patterned embossing means to form embossments repeated continuously along the length thereof and superimposed on each other but out of register with each other with a substantial portion of the cellulosic tissue protruding beyond said threads to increase the bulk, yieldability and surface texture of the material, the cellulosic tissue having been permanently stretched by the embossing of the composite material without overstressing the threads.
3. An improved nonwoven towel material comprising the combination of a central layer of fabric made of open-mesh crossed stretchable threads spaced from one another, at least one set of the threads being both stretchable and resilient, and a layer of stretchable, soft cellulosic tissue adhesively bonded to each of the opposite faces of said central layer of fabric, the composite material formed by said fabric layer and said cellulosic layers having been embossed under pressure repetitively by similarly patterned embossing means to form similar embossments repeated continuously along the length of the material and superimposed on but out of register with each other, the non-resilient cellulosic tissue and any non-resilient fabric threads having been permanently stretched by the embossing pressure without overstressing any given portion of the material including the threads, and the threads which are both resilient and stretchable having been temporarily distorted and allowed to spring back to substantially their original dimensions and configuration as the embossing pressure is released, so that a substantial portion of the cellulosic tissue protrudes through the windows of the open mesh fabric and beyond the opposite faces thereof to increase the bulk, yieldability and surface texture.
4. An improved nonwoven towel material comprising the combination of a central layer of fabric made of open-mesh crossed stretchable threads spaced from one another, at least one set of the threads being both stretchable and resilient, and a layer of stretchable, soft cellulosic tissue adhesively bonded to each of the opposite faces of said central layer of fabric, the composite material formed by said fabric layer and said cellulosic layers having been embossed under pressure repetitively at two or more stations spaced around a single rigid metal embossing roll wherein the material is pressed against said roll by a resilient roll to form similar embossments repeated continuously along the length of the material and superimposed on but out of register with each other, the non-resilient cellulosic tissue and any non-resilient fabric threads having been permanently stretched by the embossing pressure at each station without overstressing any given portion of the material including the threads, and the threads which are both resilient and stretchable having been temporarily distorted by the embossing pressure at each station and allowed to spring back to substantIally their original dimensions and congiguration as the embossing pressure is released, to increase the material bulk, yieldability and surface texture.
5. An improved nonwoven towel material comprising the combination of a central layer of fabric made of open-mesh crossed stretchable threads spaced from one another, at least one set of the threads being both stretchable and resilient, and a layer of stretchable, soft cellulosic tissue adhesively bonded to each of the opposite faces of said central layer of fabric, the composite material having been pressure embossed repetitively through the windows of the scrim with a similar embossment pattern to form similar embossments repeated continuously along the length of the material and superimposed on but out of register with each other, the non-resilient cellulosic tissue and any non-resilient fabric threads having been permanently stretched by the embossing pressure without overstressing any given portion of the material including the threads, and the threads which are both resilient and stretchable having been temporarily distorted by the embossing pressure and allowed to spring back to substantially their original dimensions and configuration as the embossing pressure is released, to increase the material bulk, yieldability and surface texture.
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US8562786B2 (en)*2002-10-072013-10-22Georgia-Pacific Consumer Products LpMethod of making a fabric-creped absorbent cellulosic sheet
US8568560B2 (en)2002-10-072013-10-29Georgia-Pacific Consumer Products LpMethod of making a cellulosic absorbent sheet
US8568559B2 (en)2002-10-072013-10-29Georgia-Pacific Consumer Products LpMethod of making a cellulosic absorbent sheet
US6958103B2 (en)2002-12-232005-10-25Kimberly-Clark Worldwide, Inc.Entangled fabrics containing staple fibers
US7022201B2 (en)2002-12-232006-04-04Kimberly-Clark Worldwide, Inc.Entangled fabric wipers for oil and grease absorbency
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US8152959B2 (en)2006-05-252012-04-10The Procter & Gamble CompanyEmbossed multi-ply fibrous structure product
US20070272381A1 (en)*2006-05-252007-11-29Ahmed Kamal ElonyEmbossed multi-ply fibrous structure product
USD630441S1 (en)2007-05-022011-01-11The Procter & Gamble CompanyPaper product
US8894901B2 (en)*2007-10-012014-11-25G.R. Green Building Products Inc.Method of making a sheet of building material
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